Method and system for producing methanol using partial oxidation

Patent metadata

Field	Value
Publication number	US-9637432-B2
Application number	US-201514963344-A
Country	US
Kind code	B2
Filing date	Dec 9, 2015
Priority date	Dec 17, 2014
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A method and system for producing methanol that employs steam methane reforming (SMR) and/or autothermal (ATR) synthesis gas production system, together with a partial oxidation system, is disclosed. The dual mode system and method for producing the synthesis gas in a methanol production process optimizes the efficiency and productivity of the methanol plant by using the partial oxidation based reforming system as an independent source of synthesis gas. The disclosed methods and systems are configurable either as a retrofit to existing methanol production facilities or as an integrated package into newly constructed methanol production facilities.

First claim

What is claimed is:

1. A method for producing a product composition comprising methanol, comprising the steps of
(i) producing a first stream of synthesis gas having a module greater than 2.0, in a steam methane reformer (SMR) or in a steam methane reformer followed by an autothermal reformer, by reforming a first hydrocarbon feed stream and steam in the presence of a catalyst;
(ii) producing a second stream of synthesis gas having a module less than that of the first stream of synthesis gas, by partial oxidation or autothermal reforming of a second hydrocarbon feed stream;
(iii) combining the first stream of synthesis gas and the second stream of synthesis gas to form a combined synthesis gas stream; and
(iv) synthesizing the combined synthesis gas product stream in a methanol synthesis reactor into a product composition comprising methanol;
and further comprising the step of recycling a portion of the excess hydrogen and methane slip formed during synthesis of the product composition comprising methanol to the steam methane reformer.

2. The method of claim 1 wherein the second stream of synthesis gas is produced by autothermal reforming of the second hydrocarbon feed stream.

3. The method of claim 1 wherein the second stream of synthesis gas is produced by partial oxidation of the second hydrocarbon feed stream.

4. The method of claim 3 wherein the second stream of synthesis gas is produced by partial oxidation of the second hydrocarbon feed stream with a high velocity stream of hot oxygen.

5. The method of claim 1 wherein the second stream of synthesis gas has a module of between about 1.4 and 2.0.

6. The method of claim 1 wherein the second stream of synthesis gas has a methane slip of less than about 4.5 percent by volume.

7. The method of claim 1 wherein the module of the combined synthesis gas stream is between about 2.0 to 2.8.

8. The method of claim 1 wherein said second stream of synthesis gas is produced by reaction of said second hydrocarbon feed stream with oxygen that is comprised in an oxidant having an oxygen content of at least 80 vol. %.

9. The method of claim 1 further comprising the step of cooling one or both of the first stream of synthesis gas or the second stream of synthesis gas to a temperature of about 400° C. or less.

10. The method of claim 1 wherein a combined hydrocarbon feed stream is treated to lower the content therein of sulfur compounds, and a portion of the resulting treated hydrocarbon feed stream comprises said first hydrocarbon feed stream and another portion of the resulting treated hydrocarbon feed stream comprises said second hydrocarbon feed stream.

11. A method for enhancing the methanol output from an existing facility that produces a product composition comprising methanol, wherein the existing facility produces a first stream of synthesis gas from a pre-existing steam methane reformer (SMR) or a combined steam methane reformer followed by an autothermal reformer, by reforming a first hydrocarbon feed stream and steam in the presence of a catalyst, the method comprising the steps of:
(i) producing a second stream of synthesis gas, with a lower module than the first stream of synthesis gas, by partial oxidation or autothermal reforming of a second hydrocarbon feed stream;
(ii) combining the first stream of synthesis gas and the second stream of synthesis gas to form a combined synthesis gas stream with a module that is less than the module of the first synthesis gas stream; and
(iv) synthesizing the combined synthesis gas product stream in a methanol synthesis reactor into a product composition comprising methanol;
and further comprising the step of recycling a portion of the excess hydrogen and methane slip formed during synthesis of the product composition comprising methanol to the steam methane reformer.

12. The method of claim 11 wherein the second stream of synthesis gas has a module of between about 1.4 and 2.0.

13. The method of claim 11 wherein the second stream of synthesis gas has a methane slip of less than about 4.5 percent by volume.

14. The method of claim 11 wherein the module of the combined synthesis gas stream is between about 2.0 to 2.8.

15. The method of claim 11 wherein said second stream of synthesis gas is produced by reaction of said second hydrocarbon feed stream with oxygen that is comprised in an oxidant having an oxygen content of at least 80 vol. %.

Assignees

• Chakravarti Shrikar
• Shah Minish
• Drnevich Raymond F
• Praxair Technology Inc

Inventors

• Chakravarti Shrikar
• Shah Minish
• Drnevich Raymond F

Classifications

• C07C29/1518 Primary

  one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis · CPC title

• C01B2203/142

  At least two reforming, decomposition or partial oxidation steps in series · CPC title

• C01B2203/025

  containing a partial oxidation step · CPC title

• C01B2203/0485

  the impurity being a sulfur compound · CPC title

• C01B3/36

  using oxygen; using mixtures containing oxygen as gasifying agents · CPC title