Photocatalyst, manufacturing method therefor, and photocatalyst apparatus

Patent metadata

Field	Value
Publication number	US-9636660-B2
Application number	US-201214400641-A
Country	US
Kind code	B2
Filing date	Dec 27, 2012
Priority date	May 25, 2012
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

Provided is a photocatalyst including: a porous metal oxide film; and metal particles formed on a surface of the porous metal oxide film.

First claim

The invention claimed is:

1. A photocatalyst comprising:
a porous metal oxide film consisting of a metal oxide; and
metal particles formed on a surface of the porous metal oxide film,
wherein the photocatalyst capable of activation by visible light of a wavelength from 380 nm to 700 nm,
wherein the photocatalyst has a specific surface area from 50 m 2 /g to 500 m 2 /g,
wherein the metal particles are present in an amount of 0.0001 mg to 0.01 mg per 1 cm 2 of the porous metal oxide film,
wherein the metal particles form a discontinuous coating layer having island shapes on the surface of the porous metal oxide film, and the island shapes have an average diameter from 3 nm to 8 nm; and wherein the metal particles comprise at least one selected from the group consisting of tungsten, chromium, vanadium, molybdenum, copper, iron, cobalt, manganese, nickel, silver, cerium, cadmium, zinc, magnesium, calcium, strontium, barium, and combinations thereof.

2. The photocatalyst according to claim 1 , wherein the discontinuous coating layer has a thickness from 0.1 nm to 10 nm.

3. The photocatalyst according to claim 1 , wherein the metal oxide in the metal oxide film comprises at least one selected from the group consisting of titanium oxide, tungsten oxide, zinc oxide, niobium oxide, and combinations thereof.

4. The photocatalyst according to claim 1 , wherein the porous metal oxide film has a porosity from 5% to 50%.

5. The photocatalyst according to claim 1 , wherein the metal particles are present in an amount of 0.01 wt % to 10 wt % based on 100 wt % of the photocatalyst.

6. A photocatalytic apparatus comprising the photocatalyst according to claim 1 .

7. The photocatalyst according to claim 1 , wherein the metal oxide in the metal oxide film is titanium oxide or tungsten oxide.

8. The photocatalyst according to claim 1 , wherein the photocatalyst has an absorbance of the visible light of the wavelength from 380 nm to 700 nm from 2% to 20%.

Assignees

• Lg Hausys Ltd

Inventors

• Lee Dong Il
• Jung Seong Moon
• Seo Joo-Hwan
• Lee Ju-Hyung

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J23/50

  Silver · CPC title

• C01G23/047

  Titanium dioxide · CPC title

• B01J37/341

  making use of electric or magnetic fields, wave energy or particle radiation (use of flames, plasma or lasers B01J37/349) · CPC title

• B01J23/02 Primary

  of the alkali- or alkaline earth metals or beryllium · CPC title