Plant and process for performance of heterogeneously catalyzed gas phase reactions

Patent metadata

Field	Value
Publication number	US-9636651-B2
Application number	US-201514737025-A
Country	US
Kind code	B2
Filing date	Jun 11, 2015
Priority date	Jun 12, 2014
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

The present invention relates to a plant for performance of heterogeneously catalyzed gas phase reactions. The plant entails a reactor, at least one line leading into the reactor for introduction of reactants into the reactor, at least one first feed for providing at least one first reactant A, which leads into the line, at least one second feed for providing at least one second reactant B, which leads into the line, at least one third feed for providing a cycle gas G, which leads into the line, a temperature control unit which is disposed in the line upstream of the reactor and is for controlling the temperature of the first reactant A and/or second reactant B and/or cycle gas G prior to entry into the reactor and at least one outlet for products, by-products and/or unreacted reactants from the gas phase reaction.

First claim

The invention claimed is:

1. A plant comprising
a reactor,
at least one line leading into the reactor, configured for introduction of reactants into the reactor,
at least one first feed, configured for providing at least one first reactant A, which leads into the line,
at least one second feed, configured for providing at least one second reactant B, which leads into the line,
at least one third feed, configured for providing a cycle gas G, which leads into the line,
a temperature control unit which is disposed in the line upstream of the reactor and is configured for controlling a temperature of the first reactant A or second reactant B or cycle gas G prior to entry into the reactor, wherein the temperature control unit is a heat exchanger operable as a preheater or as a cooler,
at least one outlet, configured for products, by-products or unreacted reactants from a gas phase reaction,
a fourth feed for feeding of process steam D to the temperature control unit, wherein the fourth feed comprises a valve V 1 ,
a fifth feed for feeding of cold condensate K to the temperature control unit, wherein the fifth feed comprises a valve V 2 , and
a second outlet for condensate K or hot condensate HK leading out of the temperature control unit.

2. The plant of claim 1 , wherein the reactor is a shell and tube reactor having reaction tubes filled essentially completely with a catalytically active material.

3. The plant of claim 1 , wherein the temperature control unit is a heat exchanger operable as a preheater.

4. The plant of claim 1 , wherein the temperature control unit is a heat exchanger operable as a cooler.

5. The plant according to claim 1 , wherein
in the course of performance of heterogeneously catalyzed gas phase reactions, the temperature control unit serves to preheat the gas mixture which is fed to the reactor, and
in maintenance operation the same temperature control unit is operated as a heat exchanger in the opposite direction and serves to cool the gas fed to the reactor.

6. A process for performing a heterogeneously catalyzed gas phase reaction in the plant of claim 1 , the process comprising:
mixing the first reactant A, the second reactant B and the cycle gas G to give a reaction mixture R in the line,
b) adjusting a temperature of the reaction mixture R in the temperature control unit, to obtain a temperature-adjusted reaction mixture R,
c) feeding the temperature-adjusted reaction mixture R to the reactor,
d) performing at least one heterogeneously catalyzed gas phase reaction at least between the first reactant A and the second reactant B, to obtain at least one reaction product P, and
e) removing a mixture of the at least one reaction product P and the at least one cycle gas G via the outlet.

7. The process of claim 6 , wherein the temperature control unit operated in a) as a heat exchanger that preheats the reaction mixture R.

8. The process of claim 7 , wherein the temperature control unit is fed with hot process steam D as a heat transfer medium.

9. The process of claim 6 , wherein the reaction mixture R is preheated in the temperature control unit in a) to a temperature of 60% to 100% of the reaction temperature in the reactor.

10. The process of claim 6 , comprising performing i)-vii) at time intervals:
i) stopping a feed of the first reactant A and a feed of the second reactant B to the line,
ii) feeding the cycle gas G to the line,
iii) stopping the mixing a),
iv) adjusting the temperature of the cycle gas G in the temperature control unit,
v) feeding the temperature-adjusted cycle gas G to the reactor,
vi) stopping the at least one heterogeneously catalyzed gas phase reaction d), and
vii) removing the cycle gas G via the outlet.

11. The process of claim 10 , wherein the temperature control unit is operated in a) as a heat exchanger that cools the cycle gas G.

12. The process of claim 10 , wherein the temperature control unit is supplied with cold condensate K as a heat transfer medium.

Assignees

• Basf Se

Inventors

• Hammon Ulrich
• Walter Thomas

Classifications

• B01J8/065 Primary

  Feeding reactive fluids · CPC title

• C07C47/22

  Acryaldehyde; Methacryaldehyde · CPC title

• B01J2208/00893

  Feeding means for the reactants · CPC title

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C07C51/16 Primary

  by oxidation (C07C51/145 takes precedence) · CPC title