Method for making a porous silica aerogel composite membrane

Patent metadata

Field	Value
Publication number	US-9636633-B2
Application number	US-201615383278-A
Country	US
Kind code	B2
Filing date	Dec 19, 2016
Priority date	Oct 15, 2013
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

The present invention provides a method for making a porous silica aerogel composite membrane. The porous silicon oxide aerogel composite membrane includes a porous aluminum oxide membrane having a plurality of macro pores with an average diameter larger than 50 nm and a porous silica aerogel membrane formed on at least one side of the porous aluminum oxide membrane and the macro pores of surface layers of the porous aluminum oxide membrane where the porous silica aerogel membrane has a plurality of meso pores with an average diameter of 2˜50 nm and is derived from methyltrimethoxysilane precursor by a sol-gel synthetic method.

First claim

What is claimed is:

1. A method for making a porous silicon oxide aerogel composite membrane, comprising:
providing a porous aluminum oxide membrane having a plurality of macro pores with an average diameter larger than 50 nm wherein the porous aluminum oxide membrane has a first side and a second side;
providing a silica sol prepared by a methyltrimethoxysiliane precursor;
performing a gelation procedure, dipping at least one side of the porous aluminum oxide membrane, that is, the first side, the second side or the first and the second sides, into the silica sol to form a membrane coated with gel on its surface;
performing an aging procedure, dipping the membrane coated with gel on its surface into ethanol for a predetermined period of aging time to form a composite membrane;
performing a solvent exchange procedure, dipping the composite membrane after the aging procedure into n-hexane for a predetermined period of solvent exchange time; and
performing a drying procedure, drying the composite membrane after the solvent exchange procedure so as to obtain the porous aluminum oxide membrane having porous silicon oxide aerogel as the porous silicon oxide aerogel composite membrane.

2. The method according to claim 1 , wherein in the gelation procedure only one side of the porous aluminum oxide membrane is dipped into the silica sol to form the coated membrane having one side coated with gel.

3. The method according to claim 1 , wherein the silica sol is prepared by hydrolysis reaction of the methyltrimethoxysiliane precursor added with ethanol and hydrochloric acid and then condensation reaction through adding ethanol and ammonia water to stir until becoming homogenizing.

4. The method according to claim 3 , wherein ammonia water is 17 wt % in a reaction mixture and an amount of the added ethanol during condensation reaction to the methyltrimethoxysiliane precursor is a molar ratio of 1.

5. The method according to claim 3 , wherein the predetermined period of aging time is 48 hrs and the predetermined period of solvent exchange time is 24 hrs.

6. The method according to claim 1 , wherein the porous silicon oxide aerogel has an average diameter of 8˜9 nm.

7. The method according to claim 1 , wherein the porous silicon oxide aerogel has a thickness of 40˜50 nm.

Assignees

• Univ Chung Yuan Christian

Inventors

• Lin Yi-Feng
• Ko Chia-Chieh
• Tung Kuo-Lun
• Chen Chien-Hua
• Chang Kai-Shiun

Classifications

• B01D2053/221

  Devices · CPC title

• B01D71/027

  Silicium oxide · CPC title

• B01J20/28035

  with more than one layer, e.g. laminates, separated sheets · CPC title

• B01J20/103

  comprising silica · CPC title

• B01D53/228 Primary

  characterised by specific membranes · CPC title