Organic electroluminescent element, display device and illuminating device

Patent metadata

Field	Value
Publication number	US-9634275-B2
Application number	US-201313895801-A
Country	US
Kind code	B2
Filing date	May 16, 2013
Priority date	Mar 23, 2006
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

Disclosed is an organic electroluminescent element having high luminous efficiency and long life. Also disclosed are a display device and an illuminating device respectively using such an organic electroluminescent element. Specifically disclosed is an organic electroluminescent element comprising an electrode and at least one or more organic layers on a substrate. This organic electroluminescent element is characterized in that at least one of the organic layers is a light-emitting layer containing a phosphorescent compound and a host compound, the phosphorescent compound has a HOMO of −5.15 to −3.50 eV and a LUMO of from −1.25 to +1.00 eV, and the host compound has a 0-0 band of the phosphorescence spectrum at not more than 460 nm and a glass transition temperature of not less than 60° C.

First claim

What is claimed is:

1. An organic electroluminescent element comprising a substrate having thereon an electrode and at least one organic layer,
wherein at least one of the organic layers is a light-emitting layer containing a phosphorescent compound and a host compound, and
the phosphorescent compound is represented by Formula (A),

wherein R 1 represents a substituent; Z represents a group of non-metal elements necessary to form a five- to seven-membered ring; n1 is an integer of 0 to 5; B 2 represents a nitrogen atom, B 1 and B 3 -B 5 each represents a carbon atom, a nitrogen atom, an oxygen atom or a sulfur atom, at least one of B 1 and B 3 -B 5 represents a nitrogen atom; M 1 is a metal of 8-10 group in the periodic table; X 1 and X 2 each represent a carbon atom, a nitrogen atom or an oxygen atom; L 1 is a group of elements forming ligands having coordination number 2 with X 1 and X 2 ; m1 is an integer of 1 to 3; m2 is an integer of 0 to 2; and m1+m2 is 2 or 3, and the phosphorescent compound has a HOMO of from −5.15 to −3.50 eV and a LUMO of from −1.25 to +1.00 eV,

and
the host compound has a 0-0 band of 460 nm or less in a phosphorescence spectrum and the host compound is represented by Formula (1),

wherein R 1a represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; R 1 and R 2 each represent a hydrogen atom or a substituent; at least one of R 1 represents a dibenzofuryl group; n1 is an integer of 1-4, and n2 is an integer of 0-4; and
wherein the host compound has a glass transition temperature of 130° C. or more.

2. The organic electroluminescent element of claim 1 , wherein the phosphorescent compound has the HOMO of from −4.80 to −3.50 eV and the LUMO of from −0.80 to +1.00 eV.

3. The organic electroluminescent element of claim 1 , wherein m2 is 0 in the phosphorescent compound represented by Formula (A).

4. The organic electroluminescent element of claim 1 , wherein Formula (A) is further represented by Formula (B),

wherein R 1 , R 2 and R 3 each represent a substituent; Z represents a group of non-metal elements necessary to form a five- to seven-membered ring; n1 is an integer of 0 to 5; M 1 is a metal of 8-10 group in the periodic series; X 1 and X 2 each are a carbon atom, a nitrogen atom or an oxygen atom; L 1 is a group of elements forming ligands having coordination number 2 with X 1 and X 2 ; m1 is an integer of 1 to 3; m2 is an integer of 0 to 2; and m1+m2 is 2 or 3.

5. The organic electroluminescent element of claim 1 , wherein the host compound is represented by Formula (2),

wherein R 1 and R 2 each represent a hydrogen atom or a substituent; at least one of R 1 represents a dibenzofuryl group; n1 is an integer of 1-4, and n2 is an integer of 0-4; R 3 represents a substituent; L 1 represents a divalent linking group; and m1 is an integer of 0-5.

6. The organic electroluminescent element of claim 1 , wherein a glass transition point of the host compound is 160° C. or more.

7. The organic electroluminescent element of claim 1 , further comprising an electron inhibition layer.

8. The organic electroluminescent element of claim 1 , emitting white light.

9. A display device comprising the organic electroluminescent element of claim 1 .

10. An illuminating device comprising the organic electroluminescent element of claim 1 .

Assignees

• Konica Minolta Inc

Inventors

• Otsu Shinya
• Kita Hiroshi
• Katoh Eisaku

Classifications

• C09K2211/1092

  containing sulfur as the only heteroatom · CPC title

• C09K11/06 Primary

  containing organic luminescent materials · CPC title

• C09K2211/1044

  containing two nitrogen atoms as heteroatoms · CPC title

• C09K2211/1037

  with sulfur · CPC title

• H05B33/14

  characterised by the chemical or physical composition or the arrangement of the electroluminescent material {, or by the simultaneous addition of the electroluminescent material in or onto the light source} · CPC title