Heavy hydrocarbon removal from a natural gas stream

Patent metadata

Field	Value
Publication number	US-9631864-B2
Application number	US-201213611169-A
Country	US
Kind code	B2
Filing date	Sep 12, 2012
Priority date	Aug 3, 2012
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

A method and apparatus of removing heavy hydrocarbons from a natural gas feed stream, the method comprising using first and second hydrocarbon removal systems in series such that the first system processes the natural gas feed stream to produce a heavy hydrocarbon depleted natural gas stream and the second system processes at least a portion of the heavy hydrocarbon depleted natural gas stream from the first system to produce a natural gas stream lean in heavy hydrocarbons, wherein one of said systems is a adsorption system that comprises one or more beds of adsorbent for adsorbing and thereby removing heavy hydrocarbons from a heavy hydrocarbon containing natural gas, and the other of said systems is a gas-liquid separation system for separating a heavy hydrocarbon containing natural gas into a heavy hydrocarbon depleted natural gas vapor and a heavy hydrocarbon enriched liquid.

First claim

The invention claimed is:

1. A method of removing heavy hydrocarbons from a natural gas feed stream, wherein the heavy hydrocarbons are aliphatic hydrocarbons having six or more carbon atoms in total and/or aromatic hydrocarbons, the method comprising the steps of:
cooling the natural gas feed stream;
introducing the cooled natural gas feed stream into a gas-liquid separation system, comprising a stripping column or a phase separator, and separating the cooled natural gas feed stream into a heavy hydrocarbon depleted natural gas vapor stream and a heavy hydrocarbon enriched liquid stream;
warming the heavy hydrocarbon depleted natural gas vapor stream;
passing at least a portion of the warmed heavy hydrocarbon depleted natural gas vapor stream through one or more beds of adsorbent of an adsorption system to adsorb heavy hydrocarbons therefrom, whereby the adsorbent is selective for the heavy hydrocarbons, thereby producing a natural gas stream lean in heavy hydrocarbons; and
cooling at least a portion of the natural gas stream lean in heavy hydrocarbons to produce a cooled natural gas stream lean in heavy hydrocarbons;
wherein the heavy hydrocarbon depleted natural gas vapor stream is warmed and the at least a portion of the natural gas stream lean in heavy hydrocarbons is cooled in an economizer heat exchanger via indirect heat exchange between the heavy hydrocarbon depleted natural gas vapor stream and the at least a portion of the natural gas stream lean in heavy hydrocarbons.

2. The method of claim 1 , wherein the method is further a method of producing a liquefied natural gas stream, and further comprises liquefying at least a portion of the cooled natural gas stream lean in heavy hydrocarbons.

3. The method of claim 2 , wherein the natural gas feed stream is cooled and the at least a portion of the cooled natural gas stream lean in heavy hydrocarbons is liquefied in a liquefier, the natural gas feed stream being introduced into a warm end of the liquefier and withdrawn from an intermediate location of the liquefier, and the cooled natural gas stream lean in heavy hydrocarbons being introduced into an intermediate location of the liquefier and withdrawn from a cold end of the liquefier.

4. The method of claim 1 , wherein the gas-liquid separation system is a stripping column, the method further comprising introducing a stripping gas into the stripping column at a location below the location at which the cooled natural gas feed stream is introduced into the stripping column.

5. The method of claim 1 , wherein the gas liquid separation system is a stripping column, the method further comprising introducing a stripping gas into the stripping column at a location below the location at which the cooled natural gas feed stream is introduced into the stripping column, and wherein the stripping gas comprises one or more gases selected from the group consisting of: natural gas taken from the natural gas feed stream prior to said stream being cooled and introduced into the stripping column; a portion of the natural gas stream lean in heavy hydrocarbons that is not cooled in the economizer heat exchanger; a portion of the natural gas stream depleted in heavy hydrocarbons that has been warmed in the economiser heat exchanger; a gas obtained from re-boiling all or a portion of the heavy hydrocarbon enriched liquid stream; and a flash or boil-off gas obtained from a liquefied natural gas.

6. The method of claim 1 , wherein the adsorption system is a temperature swing adsorption system, and the method further comprises regenerating the one or more beds of the temperature swing adsorption system by passing a gas, selected from a portion of the natural gas stream lean in heavy hydrocarbons or a flash or boil off gas obtained from a liquefied natural gas, through the one or more beds, the temperature of the one or more beds during regeneration being higher than the temperature of the one or more beds during adsorption of heavy hydrocarbons from the heavy hydrocarbon depleted natural gas vapor stream or portion thereof.

7. The method of claim 6 , wherein the method further comprises cooling and separating into liquid and vapor phases the gas obtained from the one or more beds of the temperature swing adsorption system during regeneration of said one or more beds, and recycling the vapor phase into the natural gas feed stream prior to the introduction thereof into the gas-liquid separation system.

8. The method of claim 6 , wherein the gas liquid separation system is a stripping column, and the method further comprises cooling and separating into liquid and vapor phases the gas obtained from the one or more beds of the temperature swing adsorption system during regeneration of said one or more beds, and introducing the vapor phase as a stripping gas into the stripping column at a location below the location at which the cooled natural gas feed stream is introduced into the stripping column.

9. The method of claim 1 , wherein the natural gas feed stream is lean in aliphatic hydrocarbons having from 3 to 5 carbon atoms in total, and/or is lean in aliphatic hydrocarbons having from 2 to 5 carbon atoms in total.

10. An apparatus for removing heavy hydrocarbons from a natural gas feed stream and producing a liquefied natural gas stream, wherein the heavy hydrocarbons are aliphatic hydrocarbons having six or more carbon atoms in total and/or aromatic hydrocarbons, the apparatus comprising:
a gas-liquid separation system, comprising a stripping column or a phase separator, for receiving and separating the natural gas feed stream into a heavy hydrocarbon depleted natural gas vapor stream and a heavy hydrocarbon enriched liquid stream;
an adsorption system, in fluid flow communication with the gas-liquid separation system, for receiving at least a portion of the heavy hydrocarbon depleted natural gas vapor stream, and comprising one or more beds of adsorbent for adsorbing heavy hydrocarbons from said at least a portion of the heavy hydrocarbon depleted natural gas vapor stream, whereby the adsorbent is selective for the heavy hydrocarbons, to thereby produce a natural gas stream lean in heavy hydrocarbons;
an economizer heat exchanger for warming the heavy hydrocarbon depleted natural gas vapor stream, prior to said stream or portion thereof being passed through the one or more beds of the adsorption system, and cooling at least a portion of the natural gas stream lean in heavy hydrocarbons via indirect heat exchange between the heavy hydrocarbon depleted natural gas vapor stream and the at least a portion of the natural gas stream lean in heavy hydrocarbons; and
a liquefier connected in fluid flow communication with the gas-liquid separation system and the second heavy hydrocarbon removal system, for receiving and cooling the natural gas feed stream prior to said stream being introduced into the gas-liquid separation system, and for receiving and liquefying at least a portion of the natural gas stream lean in heavy hydrocarbons to produce the liquefied natural gas stream, the natural gas feed stream being introduced into a warm end of the liquefier and withdrawn from an intermediate location of the liquefier, and the at least a portion of the natural gas stream lean in heavy hydrocarbons being introduced into an intermediate location of the liquefier and withdrawn from a cold end of the liquefier.

Assignees

• Chen Fei
• Luo Xukun
• Ott Christopher Michael
• Roberts Mark Julian
• Krishnamurthy Gowri
• Air Prod & Chem

Inventors

• Chen Fei
• Luo Xukun
• Ott Christopher Michael
• Roberts Mark Julian
• Krishnamurthy Gowri

Classifications

• C10L3/10

  Working-up natural gas or synthetic natural gas · CPC title

• C10L2290/545

  Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title

• F25J1/0022 Primary

  Hydrocarbons, e.g. natural gas · CPC title

• C10L3/101

  Removal of contaminants · CPC title

• F25J2210/06

  Splitting of the feed stream, e.g. for treating or cooling in different ways · CPC title