Non-caking rock dust for use in underground coal mines

Patent metadata

Field	Value
Publication number	US-9631492-B2
Application number	US-201414281610-A
Country	US
Kind code	B2
Filing date	May 19, 2014
Priority date	Jul 2, 2013
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

A heterogeneous composition for use as rock dust is disclosed. The heterogeneous composition includes a fine, wet ground inorganic particulate material treated with at least one fatty acid, a salt thereof, or an ester thereof, and a coarse, untreated, dry ground inorganic particulate material. Also disclosed is a heterogeneous composition including coal dust and mine rock dust including a fine, wet ground inorganic particulate material treated with at least one fatty acid, a salt thereof, or an ester thereof, and a coarse, untreated, dry ground inorganic particulate material. The amount of mine rock dust may be sufficient to render the coal dust explosively inert. The fine, treated, wet ground inorganic particulate material may be calcium carbonate. The coarse, untreated inorganic particulate material may be calcium carbonate. The fatty acid may be stearic acid.

First claim

What is claimed is:

1. A method for abating explosions in a mine containing coal dust, the method comprising:
providing in the mine containing coal dust a heterogeneous,
non-caking mine rock dust comprising
a fine, wet ground inorganic particulate material coated with at least one fatty acid, a salt thereof, or an ester thereof; and
a coarse, untreated, dry ground inorganic particulate material,
wherein particle packing of the fine, wet ground inorganic particulate material into voids between the coarse, untreated, dry ground inorganic particulate material reduces moisture wicking into the heterogeneous, non-caking mine rock dust, and
wherein the ratio by weight of fine, wet ground inorganic particulate material to coarse, untreated, dry ground inorganic particulate material ranges from about 5:95 to about 30:70, and
wherein, when in contact with water, the mine rock dust remains dispersable to render coal dust explosively inert.

2. The method of claim 1 , wherein the fine, wet ground inorganic particulate material is ground calcium carbonate.

3. The method of claim 1 , wherein the coarse, untreated, dry ground inorganic particulate material is calcium carbonate.

4. The method of claim 1 , wherein the coarse, untreated, dry ground inorganic particulate material comprises at least one of gypsum, diatomaceous earth, perlite, hydrous or calcined kaolin, attapulgite, bentonite, and montmorillonite.

5. The method of claim 1 , wherein the fine, wet ground inorganic particulate material has a d 50 ranging from about 0.5 to 75 microns.

6. The method of claim 1 , wherein the coarse, untreated, dry ground inorganic particulate material has a d 50 ranging from about 3 to about 75 microns.

7. The method of claim 1 , wherein the at least one fatty acid, salt thereof, or ester thereof comprises one or more fatty acids, salts thereof, or esters thereof with a chain length of C16 or greater.

8. The method of claim 1 , wherein the fatty acid comprises stearic acid.

9. The method of claim 1 , wherein the fatty acid, salt thereof, or ester thereof is present in an amount not greater than about 2.5% by weight of the fine, treated wet ground inorganic particulate material.

10. The method of claim 1 , wherein the fine, wet ground inorganic particulate material is substantially free of dispersant.

11. The method of claim 1 , wherein the fine, wet ground inorganic particulate material has a Hegman of about 5.5 or less.

12. The method of claim 1 , wherein the fine, wet ground inorganic particulate material has a brightness of 95 or less.

13. The method of claim 1 , wherein the fine, wet ground inorganic particulate material has a BET surface area of at least about 0.3 square meters/gram.

14. The method of claim 1 , wherein the mine rock dust has a contact angle ranging from 10 to 150 degrees.

15. A heterogeneous composition comprising:
coal dust; and
non-caking mine rock dust comprising
a fine, wet ground inorganic particulate material coated with at least one fatty acid, a salt thereof, or an ester thereof; and
a coarse, untreated, dry ground inorganic particulate material,
wherein particle packing of the fine, wet ground inorganic particulate material into voids between the coarse, untreated, dry ground inorganic particulate material reduces moisture wicking into the non-caking mine rock dust,
wherein the ratio by weight of fine, wet ground inorganic particulate material to coarse, untreated, dry ground inorganic particulate material ranges from about 5:95 to about 30:70, and
wherein the heterogenous composition is in contact with water, and

wherein the amount of dispersible non-caking mine rock dust is sufficient to render the coal dust explosively inert.

16. The heterogeneous composition of claim 15 , wherein the fine, wet ground inorganic particulate material has a d 50 ranging from about 0.5 to 75 microns.

17. The heterogeneous composition of claim 15 , wherein the coarse, untreated, dry ground inorganic particulate material has a d 50 ranging from about 3 to about 75 microns.

18. The heterogeneous composition of claim 15 , wherein the at least one fatty acid, salt thereof, or ester thereof comprises one or more fatty acids, salts thereof, or esters thereof with a chain length of C16 or greater.

19. The heterogeneous composition of claim 15 , wherein the heterogeneous composition has a contact angle ranging from 25 to 125 degrees.

Assignees

• Imerys Pigments Inc
• Imerys Usa Inc

Inventors

• Anstine David
• Shurling Jr Dickey

Classifications

• C09K3/18

  for application to surfaces to minimize adherence of ice, mist or water thereto (rendering particulate materials free flowing, in general, e.g. making them hydrophobic B01J2/30); Thawing or antifreeze materials for application to surfaces (used in liquids for heat-transfer, heat-exchange or heat-storage or for the production of heat or cold other than by combustion, e.g. radiator liquids, C09K5/00) · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01F11/185

  After-treatment, e.g. grinding, purification, conversion of crystal morphology · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title