High performance reversible electrochemical cell for H2O electrolysis or conversion of CO2 and H2O to fuel

Patent metadata

Field	Value
Publication number	US-9631286-B2
Application number	US-201314391555-A
Country	US
Kind code	B2
Filing date	Apr 11, 2013
Priority date	Apr 13, 2012
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

The present invention relates to a reversible electrochemical cell, such as an electrolysis cell for water splitting or for conversion of carbon dioxide and water into fuel. The present invention relates also to an electrochemical cell that when operated in reverse performs as a fuel cell. The electrochemical cell comprises gas 5 diffusion electrodes and a porous layer made of materials and having a structure adapted to allow for a temperature range of operation between 100-374° C. and in a pressure range between 3-200 bars.

First claim

What is claimed is:

1. An electrochemical cell comprising:
at least two porous gas diffusion electrodes, wherein at least one of said at least two porous gas diffusion electrodes comprises doped strontium titanate;
a ceramic porous layer, wherein said porous layer is located in between said at least two porous gas diffusion electrodes and wherein said ceramic porous layer comprises an aqueous electrolyte in said ceramic porous layer, wherein said ceramic porous layer has pore diameters between 2 and 50 nm; and
wherein said ceramic porous layer has a perovskite structure having the formula of AB Y B′ 1−y O 3−δ wherein:
A is Ca, Sr, or Ba, or a combination thereof;
B is Ti, Zr, Hf, or Ce, or a combination thereof; and
B′ is Y, Sc, or Ga, or a combination thereof; and
0≦y≦1; or

wherein said ceramic porous layer is an alkaline earth metal titanate; or
wherein said ceramic porous layer is a metal carbide; or
wherein said porous layer is a metal nitride;
whereby said electrochemical cell withstands a temperature range between 100-374° C. and a pressure range between 3-200 bars, allowing for said electrochemical cell to operate within that temperature and pressure range.

2. The electrochemical cell according to claim 1 , wherein said porous layer has pore diameters that are greater than 50 nm.

3. The electrochemical cell according to claim 1 , wherein said aqueous electrolyte is an aqueous solution of MOH, M 2 CO 3 , MHCO 3 , M 2 SO 4 , MX 2 PO 4 , M 2 XPO 4 , MXO 4 , MXO 3 , or MX, wherein M is H, Li, Na, K, Rb or Cs, and X is Cl, Br or I.

4. The electrochemical cell according to claim 1 , wherein said at least one of said at least two porous gas diffusion electrodes comprises Nickel, a Nickel alloy or Ni—Co.

5. The electrochemical cell according to claim 1 , wherein said at least one of said at least two porous gas diffusion electrodes comprises a ceramic material.

6. The electrochemical cell according to claim 1 , wherein said at least one of said at least two porous gas diffusion electrodes comprises perovskites with the formula ABO 3 , wherein A is a combination of an alkali metal, an alkaline earth element, a lanthanide or Y, and B is a combination of a transition metal, lanthanide, Ga or Mg.

7. The electrochemical cell according to claim 1 , wherein said at least one of said at least two porous gas diffusion electrodes comprises spinels with the formula A 3 O 4 , wherein A is a combination of transition metals, Mg, Ga or Al.

8. The electrochemical cell according to claim 1 , wherein said at least one of said at least two porous gas diffusion electrodes comprises a transition metal or Zr, Hf, Ce, Y, or Sc or alkaline earth or lanthanide or Si, Ga, or Al.

9. The electrochemical cell according to claim 1 , wherein at least one of said at least two porous gas diffusion electrodes is loaded with a catalyst.

10. A method of using an electrochemical cell according to claim 1 comprising:
providing the electrochemical cell according to claim 1 and producing hydrogen and oxygen from water with said electrochemical cell.

11. A method of using an electrochemical cell according to claim 1 comprising:
providing the electrochemical cell according to claim 1 and producing a synthetic fuel from carbon dioxide and water with said electrochemical cell.

12. The electrochemical cell according to claim 1 , wherein at least one of said at least two porous gas diffusion electrodes comprises a metal foam.

13. A method of producing an electrochemical cell according to claim 1 , said method comprising:
assembling a porous layer for supporting a liquid electrolyte located in between at least two electrodes;
pressing said assembly;
sintering said assembly in a reducing atmosphere; and
loading an electrocatalyst.

Assignees

• Univ Danmarks Tekniske

Inventors

• Allebrod Frank
• Chatzichristodoulou Christodoulos
• Mollerup Pia Lolk
• Mogensen Mogens Bjerg

Classifications

• H01M8/2465

  Details of groupings of fuel cells · CPC title

• C25B3/00

  Electrolytic production of organic compounds · CPC title

• H01M8/08

  Fuel cells with aqueous electrolytes · CPC title

• H01M8/0293

  Matrices for immobilising electrolyte solutions · CPC title

• H01M4/8652

  as mixture · CPC title