Electrochemical device for syngas and liquid fuels production

Patent metadata

Field	Value
Publication number	US-9631284-B2
Application number	US-201414213879-A
Country	US
Kind code	B2
Filing date	Mar 14, 2014
Priority date	Mar 15, 2013
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

The invention relates to methods for creating high value liquid fuels such as gasoline, diesel, jet and alcohols using carbon dioxide and water as the starting raw materials and a system for using the same. These methods combine a novel solid oxide electrolytic cell (SOEC) for the efficient and clean conversion of carbon dioxide and water to hydrogen and carbon monoxide, uniquely integrated with a gas-to-liquid fuels producing method.

First claim

What is claimed:

1. A method for producing liquid fuels, comprising:
providing a feed stream comprising carbon dioxide and water;
heating the feed stream to produce a heated feed stream;
compressing an air stream to produce a pressurized air stream;
heating the pressurized air stream to produce a heated air stream;
reacting the heated feed stream and the heated air stream in a solid oxide electrolytic cell in the electrolysis mode to form a syngas and an oxygen-containing stream, wherein the electrolytic cell comprises a cathode and an anode and a power supply;
treating the syngas stream to produce a treated syngas stream; and
converting the syngas to produce the liquid fuels in a gas to liquid subsystem.

2. The method of claim 1 , wherein the cathode is at a temperature between about 750° C. to about 850° C., and the anode is at a temperature between about 750° C. to about 850° C.

3. The method of claim 1 , wherein the cathode is at a pressure between about 1.0 bar to about 20.0 bar, and the anode is at a pressure between about 1.0 bar to about 20.0 bar.

4. The method of claim 1 , wherein the cathode is at pressure between about 1.0 bar to about 2.0 bar, and an anode at a pressure between about 1.0 bar to about 2.0 bar.

5. The method of claim 1 , further comprising preheating the air stream to produce a preheated air stream, wherein the oxygen-containing stream preheats the air stream utilizing a heat-exchanger.

6. The method of claim 1 , wherein the preparing step further comprises removing a hydrogen sulfide from the feed stream to produce a scrubbed feed stream.

7. The method of claim 6 , wherein the hydrogen sulfide is removed from the feed stream by a liquid oxidation method to form the scrubbed feed stream.

8. The method of claim 1 , wherein the preparing further comprises:
removing hydrogen sulfide by scrubbing the feed stream utilizing a liquid oxidation method to form a scrubbed feed stream;
polishing the scrubbed feed stream utilizing a zinc oxide bed to produce a polished feed stream; and
mixing hydrogen and steam with the polished feed stream to produce an enriched feed stream.

9. The method of claim 1 , wherein the treating step comprises:
separating condensable components from the syngas, wherein the condensable components comprise water, to produce dry syngas;
compressing the dry syngas to produce a pressurized syngas;
heating the pressurized syngas to produce a heated syngas; and
splitting the heated syngas to produce a syngas side-stream and a main syngas stream.

10. A method for producing liquid fuels, comprising:
providing a feed stream comprising carbon dioxide and water;
removing hydrogen sulfide by scrubbing the feed stream utilizing a liquid oxidation method to form a scrubbed feed stream;
polishing the scrubbed feed stream utilizing a zinc oxide bed to produce a polished feed stream;
heating the polished feed stream to produce a heated feed stream, wherein the heated feed stream has a temperature between about 800° C. to about 850° C.;
compressing an air stream to a pressure between about 1.0 bar to about 2.0 bar to produce a pressurized air stream;
heating the pressurized air stream to produce a heated air stream, wherein the heated air stream has a temperature of about 750° C. to about 850° C.;
reacting the heated feed stream and the heated air stream in a solid oxide electrolytic cell to form a syngas and an oxygen-containing stream;
separating condensable components from the syngas to produce a dry syngas, wherein the condensable components comprise water, and wherein condensing comprises cooling the syngas to a temperature of less than about 50° C.;
compressing the dry syngas to produce a pressurized syngas, wherein the pressurized syngas has a pressure of at least about 35 bar;
heating the dry syngas to produce a heated syngas, wherein the heated syngas has a temperature of at least about 800° C.;
splitting the dry syngas to produce a syngas side-stream and a main syngas stream, wherein the syngas side-stream comprises less than about 5 mass % of the dry syngas stream and the main syngas stream comprises the remainder of the heated syngas;
providing the syngas side-stream utilizing a water-gas shift reactor to produce a shifted syngas stream with a hydrogen content higher than a hydrogen content of the syngas side-stream;
separating at least a portion of the hydrogen content from the shifted syngas stream to produce a hydrogen recycle stream;
feeding the hydrogen recycle stream to the feed stream heating step; and
converting the main syngas stream to the liquid fuels.

11. The method of claim 10 , wherein the liquid fuel is selected from the group consisting of diesel, jet, gasoline, light fuel gas, and mixtures thereof.

12. The method of claim 10 , wherein the converting step utilizes Fisher-Tropsch processing to produce the liquid fuels.

13. The method of claim 12 , wherein the Fisher-Tropsch processing further comprises:
producing a steam stream; and
combining the steam stream with the polished feed stream to produce an enriched feed stream.

14. The method of claim 11 , further comprising combusting the light fuel gas to produce a first combustion gas in a burner.

15. The method of claim 11 , further comprising:
combusting the light fuel gas stream to produce a first combustion gas;
a first feeding step, wherein the first combustion gas is fed to a first heat-exchanger to heat the polished feed to produce a second combustion gas and the heated feed stream;
a second feeding step, wherein the second combustion gas is fed a second heat-exchanger to heat the pressurized air stream to produce a third combustion gas and the heated air stream;
a scrubbed feed stream heating step, wherein the third combustion gas is fed to a third heat-exchanger to heat the scrubbed feed stream using the third combustion gas to produce a fourth combustion gas and a preheated scrubbed feed stream; and
a third feeding step, wherein the fourth combustion gas is fed to a fourth heat-exchanger to heat the dry syngas to produce a fifth combustion gas and the heated syngas.

16. The method of claim 1 , further comprising:
an electric power generating step that produces a waste gas comprising carbon dioxide and electrical power;
feeding a portion of the electrical power to the solid oxide electrolytic cell (SOEC) power supply;
a carbon dioxide capture step that treats the waste gas to produce a purified carbon dioxide stream, wherein the purified carbon dioxide stream is greater than 99.9 vol % pure in carbon dioxide; and
feeding the purified carbon dioxide stream to the preparing step.

17. The method of claim 16 , wherein the carbon dioxide capture step is achieved by a method that is selected from the group consisting of absorption, cryogenic processing, membrane separation, adsorption, oxy-combustion, and combinations thereof.

18. The method of claim 16 , wherein the carbon dioxide capture step is by absorption utilizing a liquid amine.

19. The method of claim 18 , wherein the liquid amine is either Selexol or Rectisol.

20. The method of claim 10 , wherein the solid oxide electrolytic cell in the electrolysis mode.

Assignees

• Colorado School Of Mines
• Alliance Sustainable Energy

Inventors

• Braun Robert J
• Becker William L
• Penev Michael

Classifications

• C01B2203/0495

  the impurity being water · CPC title

• Y02E60/366

  Cross-Sectional Technologies · mapped topic

• B01D2257/504

  Carbon dioxide · CPC title

• Y02E50/32

  Cross-Sectional Technologies · mapped topic

• C01B2203/043

  Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration · CPC title