Pressure-sensitive adhesive material particularly for encasing an electronic arrangement

Patent metadata

Field	Value
Publication number	US-9631127-B2
Application number	US-201314422203-A
Country	US
Kind code	B2
Filing date	Jul 4, 2013
Priority date	Aug 24, 2012
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

Pressure-sensitive adhesive material for encasing an electronic arrangement to prevent permeate, which material comprises at least 70 percent by weight of a mixture of at least one fluorine-containing thermoplastic elastomer and at least one fluorine-containing liquid elastomer, wherein the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer is between 5:95 to 55:45.

First claim

The invention claimed is:

1. A pressure-sensitive adhesive for encapsulating an electronic arrangement with respect to permeants, comprising to an extent of at least 70 wt. % based on the overall composition of the pressure-sensitive adhesive, a mixture of at least one fluorine-containing thermoplastic elastomer and at least one fluorine-containing liquid elastomer, the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer being between 5:95 to 55:45.

2. The pressure-sensitive adhesive (PSA) of claim 1 , wherein the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer is between 15:75 and 50:50.

3. The pressure-sensitive adhesive of claim 1 , wherein the fluorine-containing thermoplastic elastomer or elastomers are selected, individually or in any combination, from the group consisting of
a fluorine-containing elastomer having at least one soft segment, consisting of a terpolymer of vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene or vinylidene fluoride/chlorotrifluoroethylene/tetrafluoroethylene, and at least one hard segment, consisting of a copolymer of tetrafluoroethylene/ethylene or chlorotrifluoroethylene/ethylene or polyvinylidene fluoride,
a fluorine-containing elastomer having at least one soft segment composed of a copolymer of tetrafluoroethylene/propylene and at least one hard segment composed of a copolymer of tetrafluoroethylene/ethylene, and
a fluorine-containing elastomer having at least one soft segment composed of an amorphous rubberlike copolymer of tetrafluoroethylene/perfluoroalkyl vinyl ether and at least one hard segment composed of a copolymer of tetrafluoroethylene/perfluoroalkyl vinyl ether in which the amount of perfluoroalkyl vinyl ether is less than in the soft segment.

4. The pressure-sensitive adhesive of claim 1 , wherein the thermoplastic fluorine-containing elastomer is compatible with the fluorine-containing liquid elastomer.

5. The pressure-sensitive adhesive of claim 3 , wherein the monomer composition of the soft segment of the thermoplastic elastomer or the monomer composition of the fluorine-containing copolymer or terpolymer is selected to be similar to the monomer composition of the liquid elastomer.

6. The pressure-sensitive adhesive of claim 3 , wherein the PSA comprises the combination of a fluorine-containing liquid elastomer composed of vinylidene fluoride, hexafluoropropylene, and tetrafluoroethylene and of a fluorine-containing thermoplastic elastomer which comprises a soft segment composed of the same terpolymer as the liquid elastomer, or the combination of a fluorine-containing liquid elastomer which is a tetrafluoroethylene/propylene copolymer or a tetrafluoroethylene/perfluoropropyl vinyl ether copolymer, and of a fluorine-containing thermoplastic elastomer having a soft segment composed of the same copolymer as the liquid elastomer.

7. The pressure-sensitive adhesive of claim 3 , wherein fluorine-containing liquid elastomers used are elastomers based on vinylidene fluoride/hexafluoropropylene, on vinylidene fluoride/hexafluoropropylene/tetrafluoroethylene, on tetrafluoroethylene/propylene, on hexafluoropropylene/ethylene, fluorosilicone elastomers and/or fluorine-substituted phosphazene elastomers.

8. The pressure-sensitive adhesive of claim 1 , wherein the liquid elastomer has a number-average molecular weight M n of 500 to 20 000.

9. The pressure-sensitive adhesive of claim 1 , wherein the pressure-sensitive adhesive is crosslinked.

10. The pressure-sensitive adhesive of claim 1 , wherein the pressure-sensitive adhesive comprises one or more additives selected from the group consisting of plasticizers, primary antioxidants, secondary antioxidants, process stabilizers, light stabilizers, processing assistants, endblock reinforcer resins and elastomeric polymers.

11. The pressure-sensitive adhesive of claim 1 , wherein the pressure-sensitive adhesive comprises one or more fillers.

12. The pressure-sensitive adhesive of claim 1 , wherein the pressure-sensitive adhesive is transparent in the visible light of the spectrum.

13. The pressure-sensitive adhesive of claim 1 , wherein the pressure-sensitive adhesive exhibits a haze of less than 5.0%.

14. An adhesive for encapsulating an electronic arrangement with respect to permeants, which comprises a mixture of at least one fluorine-containing thermoplastic elastomer and at least one fluorine-containing liquid elastomer and also at least one tackifier resin, the adhesive comprising this mixture to an extent of at least 70 wt. %, based on the overall composition of the adhesive.

15. The adhesive of claim 14 , wherein the mass ratio of the fluorine-containing liquid elastomer to the fluorine-containing thermoplastic elastomer is between 5:95 to 55:45.

16. The adhesive of claim 1 , wherein the adhesive comprises at least one resin which has a DACP of more than 30° C. and an MMAP of more than 50° C.

17. The pressure-sensitive adhesive of claim 1 , wherein the pressure-sensitive adhesive comprises at least one resin which has a DACP of less than 20° C. and an MMAP of less than 0° C.

Assignees

• Tesa Se

Inventors

• KEITE-TELGENBüSCHER KLAUS
• Ellinger Jan

Classifications

• C09J127/16 Primary

  Homopolymers or copolymers of vinylidene fluoride · CPC title

• C09J127/12 Primary

  containing fluorine atoms · CPC title

• H10K59/873

  Encapsulations · CPC title

• C08K11/00

  Use of ingredients of unknown constitution, e.g. undefined reaction products · CPC title

• H01L2924/00

  Electricity · mapped topic