Anti-bacterial and anti-fingerprint coating composition, film comprising the same, method of coating the same and article coated with the same

Patent metadata

Field	Value
Publication number	US-9631118-B2
Application number	US-201414282680-A
Country	US
Kind code	B2
Filing date	May 20, 2014
Priority date	Jun 12, 2013
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

Disclosed is an anti-bacterial and anti-fingerprint coating composition for forming a multi-functional coating layer having both anti-bacterial functions and anti-fingerprint functions on surfaces of touchscreens provided in portable terminals such as cellular phones, of panels or the like, provided in display devices such as liquid crystal displays (LCDs) or plasma display panels (PDPs), by a dry deposition method.

First claim

What is claimed is:

1. A coating composition comprising a quaternary ammonium silane compound comprising:
a group represented by a formula of —[R 2 (OCH 2 CH 2 ) m OR 1 ],
wherein R 1 comprises at least one selected from the group consisting of hydrogen and a C1-C3 alkyl group, R 2 comprises at least one selected from the group consisting of a C5-C20 alkylene group, a C5-C20 alkenylene group, a C5-C20 alkynylene group, a C5-C20 arylene group, a C6-C20 aryl-alkylene group, a C5-C20 cyclic alkylene group and a C5-C20 alkylene group containing a heteroatom, and m is an integer of 1 to 12; and
a silane group represented by a formula of —[SiX p Y q ],
wherein X comprises at least one selected from the group consisting of a C1-C3 alkyl group, Y comprises at least one selected from the group consisting of a halogen atom, a methoxy group and an ethoxy group, p is 0, 1 or 2, q is 1, 2, or 3, and p+q is 3.

2. The coating composition according to claim 1 , wherein the quaternary ammonium silane compound has a molecular weight of 800 or more.

3. A coating composition comprising:
a silane compound represented by a formula of R 1′ O—(CH 2 CH 2 O) m′ —R 2′ —SiX′ p Y′ q′ ,
wherein R 1′ comprises at least one selected from the group consisting of hydrogen and a C1-C3 alkyl group, R 2′ comprises at least one selected from the group consisting of a C5-C20 alkylene group, a C5-C20 alkenylene group, a C5-C20 alkynylene group, a C5-C20 arylene group, a C6-C20 aryl-alkylene group, a C5-C20 cyclic alkylene group and a C5-C20 alkylene group containing a heteroatom, X′ comprises at least one selected from the group consisting of a C1-C3 alkyl group, Y′ comprises at least one selected from the group consisting of a halogen atom, a C1-C8 alkoxy group and a hydroxyl group, m′ is an integer of 1 to 12, p′ is 0, 1 or 2, q′ is 1, 2, or 3, and p′+q′ is 3; and
an anti-bacterial metal complex.

4. The coating composition according to claim 3 , wherein the anti-bacterial metal complex comprises a metal including Ag, Cu, Zn or Pt, metal oxide including AgO, CuO, ZnO or PtO, or a metal-containing inorganic carrier in which a porous carrier including zeolite, phosphate or silica contains a metal.

5. An anti-bacterial and anti-fingerprint film formed by coating a surface of a substrate with the coating composition according to claim 1 .

6. The anti-bacterial and anti-fingerprint film according to claim 5 , wherein the film has a contact angle to water (H 2 O), of about 65 degrees or more, and a contact angle to diiodomethane, of about 50 degrees or less.

7. A quaternary ammonium silane compound comprising:
a group represented by a formula of —[R 2 (OCH 2 CH 2 ) m OR 1 ],
wherein R 1 comprises at least one selected from the group consisting of hydrogen and a C1-C3 alkyl group, R 2 comprises at least one selected from the group consisting of a C5-C20 alkylene group, a C5-C20 alkenylene group, a C5-C20 alkynylene group, a C5-C20 arylene group, a C6-C20 aryl-alkylene group, a C5-C20 cyclic alkylene group, and a C5-C20 alkylene group containing a heteroatom, and m is an integer of 1 to 12; and
a silane group represented by a formula of —[SiX p Y q ],
wherein X comprises at least one selected from the group consisting of a C1-C3 alkyl group, Y comprises at least one selected from the group consisting of a halogen atom, a C1-C3 alkoxy group and a hydroxyl group, p is 0, 1 or 2, q is 1, 2, or 3, and p+q is 3.

8. The quaternary ammonium silane compound according to claim 7 , wherein the quaternary ammonium silane compound has the following Formula 1 below:

wherein m is an integer of 1 to 12, n is an integer of 1 or more, p is 0, 1, or 2, and q is 1, 2 or 3.

9. The quaternary ammonium silane compound according to claim 7 , wherein the quaternary ammonium silane compound has a molecular weight of about 800 or more.

10. A coating method comprising:
loading an object to be coated in a vacuum chamber;
forming a primer layer on the object using silicon dioxide (SiO 2 ); and
depositing the coating composition according to claim 1 on a surface of the primer layer.

11. The coating method according to claim 10 , further comprising removing foreign matter present on the object, before formation of the primer layer on the object.

12. An article surface-coated with an anti-bacterial and anti-fingerprint film comprising the anti-bacterial and anti-fingerprint coating composition according to claim 1 .

13. The article according to claim 12 , wherein the article is a display, a touch panel or an information terminal.

14. A coating composition for a substrate, comprising:
a quaternary ammonium silane that imparts anti-finger printing properties and anti-bacteria properties to the coated substrate, wherein the quaternary ammonium silane comprises:
a group represented by a formula of —[R 2 (OCH 2 CH 2 ) m OR 1 ],

wherein R 1 comprises at least one selected from the group consisting of hydrogen and a C1-C3 alkyl group, R 2 comprises at least one selected from the group consisting of a C5-C20 alkylene group, a C5-C20 alkenylene group, a C5-C20 alkynylene group, a C5-C20 arylene group, a C6-C20 aryl-alkylene group, a C5-C20 cyclic alkylene group and a C5-C20 alkylene group containing a heteroatom, and m is an integer of 1 to 12, and
a silane group represented by a formula of —[SiX p Y q ],

wherein X comprises at least one selected from the group consisting of a C1-C3 alkyl group, Y comprises at least one selected from the group consisting of a halogen atom, a methoxy group and an ethoxy group, p is 0, 1 or 2, g is 1, 2, or 3, and p+q is 3.

15. An anti-bacterial and anti-fingerprint film formed by coating a surface of a substrate with the coating composition according to claim 2 .

16. An anti-bacterial and anti-fingerprint film formed by coating a surface of a substrate with the coating composition according to claim 3 .

17. A coating method comprising:
loading an object to be coated in a vacuum chamber;
forming a primer layer on the object using silicon dioxide (SiO 2 ); and
depositing the coating composition according to claim 2 on a surface of the primer layer.

18. A coating method comprising:
loading an object to be coated in a vacuum chamber;
forming a primer layer on the object using silicon dioxide (SiO 2 ); and
depositing the coating composition according to claim 3 on a surface of the primer layer.

19. An article surface-coated with an anti-bacterial and anti-fingerprint film comprising the anti-bacterial and anti-fingerprint coating composition according to claim 2 .

20. An article surface-coated with an anti-bacterial and anti-fingerprint film comprising the anti-bacterial and anti-fingerprint coating composition according to claim 3 .

Assignees

• Samsung Electronics Co Ltd

Inventors

• Park Byung Ha
• Park Soo Jin
• Chung Jun Sung
• Hwang In Oh

Classifications

• Y10T428/31663

  As siloxane, silicone or silane · CPC title

• A01N25/10

  Macromolecular compounds · CPC title

• C08L101/10

  containing hydrolysable silane groups · CPC title

• C09D5/14

  Paints containing biocides, e.g. fungicides, insecticides or pesticides (C09D5/16 takes precedence) · CPC title

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title