Use of polymers as additives in a polymer matrix

Patent metadata

Field	Value
Publication number	US-9631086-B2
Application number	US-201414783409-A
Country	US
Kind code	B2
Filing date	Apr 8, 2014
Priority date	Apr 8, 2013
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

The present invention relates to the use of polymers of the following formula (I):

wherein:
A 1i represents a radical alkylene divalent comprising from 2 to 20 carbon atoms; A 2i represents a radical alkylene divalent comprising from 2 to 20 carbon atoms; X 1i is chosen from the group consisting of: —S—, —CH 2 — and a bond; Y represents H, a phenyl group or an alkyl group comprising from 1 to 10 carbon atoms; i represents an integer varying from 1 to n; n represents an integer comprised from 2 to 1,000;

provided that the total number of carbon atoms of the radicals A 2i , X 1i et A 1i is greater than or equal to 8;
as additives in a polymeric matrix chosen from the group consisting of matrices of polyester, poly(vinyl chloride), polyurethane, polyamide, poly(alkyl acrylate), poly(alkyl methacrylate), polystyrene and polyolefin,
said polymer of formula (I) being different from poly(ricinoleic acid).

First claim

What is claimed is:

1. A method of improving impact resistance and/or modulating nano-structuration of a polymeric matrix comprising adding a polymer of the following formula (I) to the polymeric matrix:

wherein:
A 1i represents a linear or branched divalent alkylene radical, comprising from 2 to 20 carbon atoms, said radical optionally comprising one or several unsaturations, and being optionally substituted with at least one —OAlk substituent, Alk representing an alkyl group comprising from 1 to 10 carbon atoms;
A 2i represents a linear or branched divalent alkylene radical comprising from 2 to 20 carbon atoms, said radical optionally comprising one or several unsaturations, and being optionally substituted with at least one —OAlk substituent, Alk representing an alkyl group comprising from 1 to 10 carbon atoms;
X 1i is selected from the group consisting of: —S—, —CH 2 — and a bond;
Y represents H, a phenyl group or an alkyl group comprising from 1 to 10 carbon atoms;
i represents an integer varying from 1 to n;
n represents an integer comprised from 2 to 1,000;

provided that the total number of carbon atoms of the radicals A 2i , X 1i and A 1i is greater than or equal to 8;
as additives in a polymeric matrix selected from the group consisting of matrices of polyester, poly(vinyl chloride), polyurethane, polyamide, poly(alkyl acrylate), poly(alkyl methacrylate), polystyrene and polyolefin,
said polymer of formula (I) being different from poly(ricinoleic acid) fitting the following formula:

wherein n is as defined earlier;
wherein impact resistance and/or nano-structuration of the polymeric matrix is improved.

2. The method according to claim 1 , of polymers of formula (I-1):

wherein:
X 1i , A 1i , Y and n are as defined in claim 1 ;
R represents H or a linear or branched divalent alkyl radical, comprising from 1 to 20 carbon atoms, preferably from 2 to 10, preferentially from 4 to 9, said alkyl radical being optionally substituted with at least one OAlk group, Alk representing an alkyl group comprising from 1 to 10 carbon atoms;
R′ represents H or an OAlk group, Alk representing an alkyl group comprising from 1 to 10 carbon atoms;
r i represents an integer comprised from 0 to 5.

3. The method according to claim 1 , wherein at least one group A 1i comprises at least one unsaturation.

4. The method according to claim 1 , wherein at least one group X 1i represents S.

5. The method according to claim 1 , of additives selected from the group consisting of polymers fitting one of the following formulae:

wherein n is as defined in claim 1 .

6. The method according to claim 1 , wherein the additive is the compound, poly(methyl ricinoleate), of the following formula:

n being as defined in claim 1 .

7. The method according to claim 1 , wherein the polymeric matrix is a poly(lactic acid) matrix.

8. A composition comprising:
a polymeric matrix selected from the group consisting of matrices of polyester, poly(vinyl chloride), polyurethane, polyamide, poly(alkyl acrylate), poly(alkyl methacrylate), polystyrene and polyolefin;
5% to 20% by mass of a compound of formula (I), based on the total mass of the composition:

wherein:
A 1i represents a linear or branched divalent alkylene radical, comprising from 2 to 20 carbon atoms, said radical optionally comprising one or several unsaturations, and being optionally substituted with at least one —OAlk substituent, Alk representing an alkyl group comprising from 1 to 10 carbon atoms;
A 2i represents a linear or branched divalent alkylene radical, comprising from 2 to 20 carbon atoms, said radical optionally comprising one or several unsaturations, and being optionally substituted with at least one —OAlk substituent, Alk representing an alkyl group comprising from 1 to 10 carbon atoms;
X 1i is selected from the group consisting of: —S—, —CH 2 — and a bond;
Y represents H, a phenyl group or an alkyl group comprising from 1 to 10 carbon atoms;
i represents an integer varying from 1 to n;
n represents an integer comprised from 2 to 1,000;

 provided that the total number of carbon atoms of the radicals A 2i , X 1i and A 1i is greater than or equal to 8,
 except for poly(ricinoleic acid); and
optionally at least one other polymer selected from the group consisting of poly(butadiene), poly(isoprene), poly(ε-caprolactone) and poly(tetrahydrofurane).

9. A method for preparing a composition according to claim 8 , comprising a step for mixing at least one polymer of formula (I) according to claim 8 , and a polymeric matrix according to claim 8 , said mixing step being carried out at a temperature comprised from 180° C. to 190° C., for at least 15 minutes.

10. The method according to claim 9 , wherein the mixing step is carried out at 180° C. for 5 minutes.

Assignees

• Univ Bordeaux
• Inst Des Corps Gras Etudes Et Rech Techniques-Iterg
• Centre Nat De La Rech Scient (C N R S)
• Inst Polytechnique Bordeaux
• Inst Des Corps Gras Etudes Et Rech Technigues—Iterg

Inventors

• Cramail Henri
• Lebarbe Thomas
• Gadenne Benoit
• Alfos Carine

Classifications

• C08L67/04 Primary

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08L25/06

  Polystyrene · CPC title

• C08L33/06

  of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title