Process for separating components of a reaction mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers

Patent metadata

Field	Value
Publication number	US-9631035-B2
Application number	US-201415101351-A
Country	US
Kind code	B2
Filing date	Dec 3, 2014
Priority date	Dec 4, 2013
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

The present disclosure relates to a process for separating polymeric and gaseous components of a reaction mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers in the presence of free-radical polymerization initiators into in a gaseous fraction and a liquid fraction, wherein the separation is carried out at a pressure of from 15 MPa to 50 MPa and a temperature of from 120° C. to 300° C. in a separation vessel which has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 4 to 10 and which is equipped with an inlet pipe which extends vertically from the top into the separation vessel; and the ratio of the inner diameter of the inlet pipe at its lower end and the inner diameter of the separating vessel in its cylindrical part is in the range of from 0.2 to 0.4.

First claim

What is claimed is:

1. A process for separating polymeric and gaseous components of a reaction mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, the process comprising the steps of entering the reaction mixture into a separation vessel; separating the reaction mixture into a gaseous fraction and a liquid fraction; withdrawing the gaseous fraction from the top of the separation vessel and withdrawing the liquid fraction from the bottom of the separation vessel,
wherein the separation is carried out at a pressure of from 15 MPa to 50 MPa and a temperature of from 120° C. to 300° C.; the separation vessel has a vertically arranged cylindrical shape with a ratio of length to diameter L/D of from 4 to 10 and is equipped with an inlet pipe for introducing the reaction mixture into the separation vessel; the inlet pipe extends vertically from the top into the separation vessel; and the ratio of the inner diameter of the inlet pipe at its lower end and the inner diameter of the separating vessel in its cylindrical part is in the range of from 0.2 to 0.4.

2. The process according to claim 1 , wherein the inlet pipe is centrally arranged in the separation vessel.

3. The process according to claim 1 , wherein the reaction mixture as obtained by the high-pressure polymerization is entered into the separation vessel.

4. The process according to claim 1 , wherein the inlet pipe extends for a distance into the separation vessel which is from 25% to 40% of the length of the separation vessel.

5. The process according to claim 1 , wherein the velocity of the reaction mixture at the lower end of the inlet pipe is in the range of from 0.5 m/s to 60 m/s.

6. The process according to claim 1 , wherein the vertical velocity of the rising gas in the region from the lower end of the inlet pipe to the outlet for withdrawing the gaseous fraction from the separation vessel is in the range of from 0.02 m/s to 2.0 m/s.

7. The process according to claim 1 , wherein the surfaces within the separation vessel which are in contact with the liquid fraction have an average roughness Ra of no greater than 3.2 μm.

8. The process according to claim 1 , wherein the level of the liquid fraction in the separation vessel is measured by radiometric level measurement and is controlled by a product discharge valve.

9. A process for preparing ethylene homopolymers or copolymers from ethylenically unsaturated monomers in the presence of free-radical polymerization initiators at temperatures from 100° C. to 350° C. and pressures in the range of from 110 MPa to 500 MPa in a polymerization reactor comprising a process for separating polymeric and gaseous components according to claim 1 .

10. The process according to claim 9 , wherein the polymerization is carried out in one or more tubular reactors or autoclave reactors or combinations of such reactors.

Assignees

• Basell Polyolefine Gmbh

Inventors

• Groos Georg
• Neumann Erich
• Deuerling Michael
• Littmann Dieter

Classifications

• C08F110/02

  Ethene · CPC title

• C08J11/02

  of solvents, plasticisers or unreacted monomers · CPC title

• C08F6/12 Primary

  Separation of polymers from solutions · CPC title

• C08F2/34

  Polymerisation in gaseous state · CPC title

• C08F2/02

  Polymerisation in bulk · CPC title