Urea fertilizer compositions comprising rice hulls and methods of use
US-2017327433-A1 · Nov 16, 2017 · US
US9630887B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9630887-B2 |
| Application number | US-201514793461-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 7, 2015 |
| Priority date | Sep 12, 2008 |
| Publication date | Apr 25, 2017 |
| Grant date | Apr 25, 2017 |
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The present invention relates to novel urea-formaldehyde polymers coated with an active ingredient, a method of making the same, and their use.
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The invention claimed is: 1. A urea-formaldehyde polymer comprising an active agent consisting of a urease inhibitor, wherein the concentration of the active ingredient is greater than about 35 wt % based on the weight of the active ingredient containing urea-formaldehyde polymer. 2. The urea-formaldehyde polymer of claim 1 , wherein the urea-formaldehyde polymer and the urease inhibitor are commingled. 3. The urea-formaldehyde polymer of claim 1 , wherein the urea-formaldehyde polymer and the urease inhibitor are admixed. 4. The urea-formaldehyde polymer of claim 1 , wherein the urease inhibitor is NBPT. 5. The urea-formaldehyde polymer of claim 1 , wherein the urea-formaldehyde polymer further comprises one or more fungicides or insecticides in addition to the urease inhibitor. 6. The urea-formaldehyde polymer of claim 1 , wherein the urea-formaldehyde polymer has a water content of between about 1 and 80 weight percent, based on the weight of the urea-formaldehyde polymer. 7. The urea-formaldehyde polymer of claim 1 , wherein the urea-formaldehyde polymer has a water content of between about 10 and 35 weight percent, based on the weight of the urea-formaldehyde polymer. 8. The urea-formaldehyde polymer of claim 1 , wherein the urea-formaldehyde polymer has a water content of between about 10 and 20 weight percent, based on the weight of the urea-formaldehyde polymer. 9. The urea-formaldehyde polymer of claim 1 , further comprising residual solvent, wherein the solvent is selected from the group consisting of ethers, alcohols, hydrocarbons, halogenated hydrocarbons and aromatic hydrocarbons. 10. The urea-formaldehyde polymer of claim 9 , wherein the residual solvent is selected from ethers, alcohols, and hydrocarbons. 11. The urea-formaldehyde polymer of claim 10 , wherein the residual solvent is tetrahydrofuran. 12. The urea-formaldehyde polymer of claim 1 , comprising substantially no residual solvent. 13. The urea-formaldehyde polymer of claim 1 , wherein the polymer does not contain any residual NMP. 14. A process for preparing the urea-formaldehyde polymer of claim 1 , the method comprising mixing a urea-formaldehyde polymer with a urease inhibitor in a solvent selected from the group consisting of ethers, alcohols, hydrocarbons, halogenated hydrocarbons and aromatic hydrocarbons. 15. The process of claim 14 , wherein the solvent is tetrahydrofuran. 16. The process of claim 14 , wherein the mixing is conducted under conditions of elevated temperature and sub-atomic pressure. 17. A urea-formaldehyde polymer prepared according to the process of claim 14 so as to comprise a urease inhibitor.
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