Method for transferring carbon nanotube array and method for forming carbon nanotube structure

Patent metadata

Field	Value
Publication number	US-9630849-B2
Application number	US-201414521234-A
Country	US
Kind code	B2
Filing date	Oct 22, 2014
Priority date	Jun 13, 2014
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

A method for transferring a carbon nanotube array is disclosed. The carbon nanotube array has an ability to have a carbon nanotube structure drawn therefrom. The carbon nanotube array is transferred from a growing substrate to a substitute substrate, meanwhile the carbon nanotube array is still configured for drawing the carbon nanotube structure from the substitute substrate. A coating layer is formed on a top end of a carbon nanotube in the carbon nanotube array. The top end is away from the growing substrate. The substitute substrate is placed on the carbon nanotube array and contacted with the coating layer. Thereby the substitute substrate is combined with the carbon nanotube array by the coating layer. The substitute substrate is separated from the growing substrate. Thereby the carbon nanotube array is separated from the growing substrate. A method for making a carbon nanotube structure is also disclosed.

First claim

What is claimed is:

1. A method for transferring a carbon nanotube array, the method comprising:
providing a substitute substrate, a growing substrate, and a carbon nanotube array grown on the growing substrate, the carbon nanotube array comprising a plurality of carbon nanotubes oriented substantially perpendicular to a growing surface of the growing substrate, and having an ability to have a carbon nanotube structure drawn therefrom, and the carbon nanotube structure comprises the plurality of carbon nanotubes joined end to end;
transferring the carbon nanotube array from the growing substrate to the substitute substrate such that the carbon nanotube array still has the ability to have the carbon nanotube structure drawn therefrom, comprising:
forming a coating layer on a top end of a carbon nanotube in the carbon nanotube array, the top end is away from the growing substrate;
placing the substitute substrate on the carbon nanotube array and contacting the substitute substrate with the coating layer, thereby combining the substitute substrate with the carbon nanotube array by the coating layer, and the coating layer is combined with the substitute substrate only by van der Waals attractive force; and
separating the substitute substrate from the growing substrate, thereby separating the carbon nanotube array from the growing substrate.

2. The method of claim 1 , wherein the carbon nanotube structure is a carbon nanotube film or a carbon nanotube wire.

3. The method of claim 1 , wherein a bonding force (F BD ) between the coating layer and the substitute substrate satisfies F AC <F BD <F CC ; wherein F CC is van der Waals attractive forces between the plurality of carbon nanotubes in the carbon nanotube array, and F AC is a bonding force between the carbon nanotube array and the growing substrate.

4. The method of claim 1 , wherein a material of the coating layer is metal or inorganic material.

5. The method of claim 4 , wherein the metal is selected from the group consisting of iron, cobalt, nickel, palladium, titanium, copper, silver, gold, and combinations thereof, the inorganic material is selected from the group consisting of aluminum oxide, nickel oxide, titanium dioxide, copper oxide, silver oxide, cobalt oxide, and iron oxide.

6. The method of claim 1 , wherein a thickness of the coating layer is in a range form about 1 nanometer to about 20 nanometers.

7. The method of claim 1 , wherein the coating layer is formed by depositing, vacuum evaporating, or sputtering.

8. The method of claim 1 , wherein a surface of the substitute substrate has a plurality of microstructures located thereon.

9. The method of claim 1 , wherein the substitute substrate is spaced from the growing substrate by a spacing element, the spacing element has a height between the substitute substrate and the growing substrate less than or equal to the height of the carbon nanotube array.

10. The method of claim 1 , wherein during the separating the carbon nanotube array from the growing substrate, substantially all the plurality of carbon nanotubes in the carbon nanotube array are simultaneously detached from the growing substrate.

11. The method of claim 1 , wherein a moving direction of at least one of the substitute substrate and the growing substrate is substantially perpendicular to the growing surface of the growing substrate during the separating of the at least one of the substitute substrate and the growing substrate.

12. A method for forming a carbon nanotube structure, the method comprising:
providing a substitute substrate, a growing substrate, and a carbon nanotube array grown on the growing substrate, the carbon nanotube array comprising a plurality of carbon nanotubes oriented substantially perpendicular to a growing surface of the growing substrate, and having an ability to have a carbon nanotube structure drawn therefrom, and the carbon nanotube structure comprises the plurality of carbon nanotubes joined end to end;
transferring the carbon nanotube array from the growing substrate to the substitute substrate such that the carbon nanotube array still has the ability to have the carbon nanotube structure drawn therefrom, comprising:
forming a coating layer on a top end of the plurality of carbon nanotubes in the carbon nanotube array, the top end is away from the growing substrate;
placing the substitute substrate on the carbon nanotube array and contacting the substitute substrate with the coating layer, thereby combining the substitute substrate with the carbon nanotube array by the coating layer, and the coating layer is combined with the substitute substrate only by van der Waals attractive force; and
separating the substitute substrate from the growing substrate, thereby separating the carbon nanotube array from the growing substrate; and

drawing the carbon nanotube structure from the carbon nanotube array on the substitute substrate.

13. A method for forming a carbon nanotube structure, the method comprising:
providing a first substrate, a second substrate, the carbon nanotube array comprising a plurality of carbon nanotubes oriented substantially perpendicular to a growing surface of the growing substrate, and having an ability to have a carbon nanotube structure drawn therefrom, and the carbon nanotube structure comprises the plurality of carbon nanotubes joined end to end;
transferring the carbon nanotube array from the first substrate to the second substrate such that the carbon nanotube array still has the ability to have the carbon nanotube structure drawn therefrom, comprising:
forming a coating layer on a top end of the plurality of carbon nanotubes in the carbon nanotube array, the top end is away from the first substrate;
placing the second substrate on the carbon nanotube array and contacting the second substrate with the coating layer, thereby combining the second substrate with the carbon nanotube array by the coating layer, and the coating layer is combined with the substitute substrate only by van der Waals attractive force; and
separating the second substrate from the first substrate, thereby separating the carbon nanotube array from the first substrate; and

drawing the carbon nanotube structure from the carbon nanotube array on the second substrate.

14. The method of claim 1 , wherein the substitute substrate comprises a receiving surface, during the step of placing the substitute substrate on the carbon nanotube array and contacting the substitute substrate with the coating layer, a distance from the receiving surface of the substitute substrate to the growing surface of the growing substrate is less than or equal to the height of the carbon nanotube array to apply a pressing force to the carbon nanotube array.

15. The method of claim 14 , wherein during the pressing of the carbon nanotube array, the plurality of carbon nanotubes in the carbon nanotube array is still substantially perpendicular to the growing surface of the growing substrate.

16. The method of claim 1 , wherein after transferring the carbon nanotube array from the growing substrate to the substitute substrate, the carbon nanotube array is located on the substitute substrate, and the plurality of carbon nanotubes in the carbon nanotube array is substantially perpendicular with a receiving surface of the substitute substrate.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Wei Yang
• Fan Shou-Shan

Classifications

• B32B2457/20

  Displays, e.g. liquid crystal displays, plasma displays · CPC title

• B82Y10/00

  Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic · CPC title

• B32B7/00

  Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers · CPC title

• B32B7/04

  Interconnection of layers · CPC title

• B32B15/04

  comprising metal as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a bituminous or tarry layer B32B11/08; next to a water-setting substance layer B32B13/06; next to a glass layer B32B17/061; next to a cellulosic plastic layer B32B23/042)} · CPC title