Oxygen-absorbing resin composition

Patent metadata

Field	Value
Publication number	US-9630764-B2
Application number	US-201314412809-A
Country	US
Kind code	B2
Filing date	Jul 9, 2013
Priority date	Jul 10, 2012
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

An oxygen-absorbing resin composition copolymerized polyolefin compound including a copolymerized polyolefin compound and a transition metal catalyst, wherein the copolymerized polyolefin compound is a copolymerized polyolefin compound including at least one of constitutional unit (a) selected from the group consisting of the constitutional units represented by the general formula (1), and at least one of the constitutional unit (b) having an indane ring, selected from the group consisting of the constitutional units represented by the general formulas (2) and (3).

First claim

The invention claimed is:

1. An oxygen-absorbing resin composition comprising a copolymerized compound and a transition metal catalyst,
wherein the copolymerized compound is a copolymerized compound comprising:
at least one of constitutional unit (a) selected from the group consisting of the constitutional units represented by the following general formula (1):

wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrogen atom or a first monovalent substituent, the first monovalent substituent is at least one selected from the group consisting of a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxy group, a carboxyl group, an ester group, an amide group, a nitro group, an alkoxy group, an aryloxy group, an acyl group, an amino group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclic thio group and an imide group, and these groups may further have a substituent; and
at least one of constitutional unit (b) having an indane ring, selected from the group consisting of the constitutional units represented by the following general formulas (2) and (3):

wherein R 5 , R 6 and R 7 each independently represent a hydrogen atom or a second monovalent substituent, R 8 , R 9 , R 10 and R 11 each independently represent a third monovalent substituent, the second monovalent substituent and the third monovalent substituent are each independently at least one selected from the group consisting of a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxy group, a carboxyl group, an ester group, an amide group, a nitro group, an alkoxy group, an aryloxy group, an acyl group, an amino group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclic thio group and an imide group, the groups may further have a substituent, and when the number of R 8 s, R 9 s, R 10 s or R 11 s being present is two or more, the two or more R 8 s, R 9 s, R 10 s or R 11 s may be the same as each other or different from each other; m represents an integer of 0 to 3, n represents an integer of 0 to 5, q represents an integer of 0 to 4 and q represent an integer of 0 to 4, and at least one hydrogen atom is bonded to a benzylic position of the indane ring; X represents a divalent group selected from the group consisting of —(C═O)O—, —(C═O)NH—, —O(C═O)—, —NH(C═O)— and —(CHR)s-, and s represents an integer of 0 to 12; Y is —(CHR)t-, and t represents an integer of 0 to 12; and R represents a monovalent chemical species selected from the group consisting of a hydrogen atom, a methyl group and an ethyl group.

2. The oxygen-absorbing resin composition according to claim 1 , wherein the transition metal catalyst comprises at least one transition metal selected from the group consisting of manganese, iron, cobalt, nickel and copper.

3. The oxygen-absorbing resin composition according to claim 1 , wherein the transition metal catalyst is included in an amount of 0.001 to 10 parts by mass in terms of the transition metal amount, based on 100 parts by mass of the copolymerized compound.

4. The oxygen-absorbing resin composition according to claim 1 , wherein a content ratio of a content of the constitutional unit (a) to a content of the constitutional unit (b) is 1/99 to 99/1 in terms of the molar ratio.

5. The oxygen-absorbing resin composition according to claim 1 ,
wherein the constitutional unit (a) is at least one selected from the group consisting of the constitutional units represented by the following general formulas (4) and (5):

and the constitutional unit (b) is the constitutional unit represented by the following general formula (6):

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Iwamoto Shinpei
• Okada Satoshi
• Ikeda Shinichi

Classifications

• B65D81/266 Primary

  for absorbing gases, e.g. oxygen absorbers or desiccants (B65D51/244, B65D51/30 take precedence) · CPC title

• C08F8/00

  Chemical modification by after-treatment (graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C) · CPC title

• C08K5/09 Primary

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08F8/14

  Esterification · CPC title

• C08L23/08 Primary

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title