Catalytic system for catalytic partial oxidation processes with a short contact time

Patent metadata

Field	Value
Publication number	US-9630168-B2
Application number	US-201113701593-A
Country	US
Kind code	B2
Filing date	May 31, 2011
Priority date	Jun 3, 2010
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

The present invention relates to a catalytic system comprising at least two catalytic zones of which at least one zone exclusively contains one or more noble metals selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium and Platinum and at least another zone contains Nickel, said catalytic system characterized in that at least one zone exclusively containing noble metals selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium and Platinum is always distinct but in contact with at least one zone containing Nickel. One or more metals selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium and Platinum are possibly added to the catalytic zone or zones comprising Nickel.

First claim

The invention claimed is:

1. A catalytic system, comprising:
a first catalytic zone comprising at least one noble metal selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium, and Platinum; and
a second catalytic zone comprising Nickel and at least one metal selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium, and Platinum,
wherein the first catalytic zone is distinct but in contact with the second catalytic zone comprising Nickel and at least one metal selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium, and Platinum, and
said first catalytic zone does not contain Nickel.

2. The catalytic system of claim 1 , wherein the second catalytic zone comprises Palladium or Platinum.

3. The catalytic system of claim 1 , wherein the first catalytic zone comprises Rhodium and the second catalytic zone comprises Nickel and Rhodium.

4. The catalytic system of claim 2 , wherein the first catalytic zone, the second catalytic zone, or both comprise Rhodium.

5. The catalytic system of claim 1 , wherein the first and second catalytic zones are arranged to form a catalytic bed.

6. The catalytic system of claim 1 , wherein the noble metal amount ranges from 0.2% to 10% weight, with respect to the total catalyst weight.

7. The catalytic system of claim 6 , wherein the noble metal amount ranges from 0.5% to 2% weight, with respect to the total catalyst weight.

8. The catalytic system of claim 1 , wherein the Nickel amount ranges from 0.5% to 20% weight, with respect to the total catalyst weight.

9. The catalytic system of claim 8 , wherein the Nickel amount ranges from 2% to 10% weight, with respect to the total catalyst weight.

10. The catalytic system of claim 5 , wherein each of said first catalytic zone and said second catalytic zone is in the form of metallic pellets, wherein each of said at least one noble metal and said Nickel is supported on spheres of α-alumina.

11. The catalytic system of claim 1 , wherein the noble metal amount ranges from 0.2% to 10% weight, with respect to the total catalyst weight, and the Nickel amount ranges from 0.5% to 20% weight, with respect to the total catalyst weight.

12. The catalytic system of claim 1 , wherein the noble metal amount ranges from 0.5% to 2% weight, with respect to the total catalyst weight, and the Nickel amount ranges from 2% to 10% weight, with respect to the total catalyst weight.

13. The catalytic system of claim 3 , wherein the Rhodium amount ranges from 0.2% to 10% weight, with respect to the total catalyst weight, and the Nickel amount ranges from 0.5% to 20% weight, with respect to the total catalyst weight.

14. The catalytic system of claim 3 , wherein the Rhodium amount ranges from 0.5% to 2% weight, with respect to the total catalyst weight, and the Nickel amount ranges from 2% to 10% weight, with respect to the total catalyst weight.

15. The catalytic system of claim 10 , wherein the noble metal amount ranges from 0.2% to 10% weight, with respect to the total catalyst weight, and the Nickel amount ranges from 0.5% to 20% weight, with respect to the total catalyst weight.

16. The catalytic system of claim 10 , wherein the noble metal amount ranges from 0.5% to 2% weight, with respect to the total catalyst weight, and the Nickel amount ranges from 2% to 10% weight, with respect to the total catalyst weight.

17. The catalytic system of claim 15 , wherein the first catalytic zone comprises Rhodium and the second catalytic zone comprises Nickel and Rhodium.

18. The catalytic system of claim 16 , wherein the first catalytic zone comprises Rhodium and the second catalytic zone comprises Nickel and Rhodium.

Assignees

• Basini Luca Eugenio
• Guarinoni Alessandra
• Carluccio Luciano Cosimo
• Eni Spa

Inventors

• Basini Luca Eugenio
• Guarinoni Alessandra
• Carluccio Luciano Cosimo

Classifications

• C01B2203/1247

  Higher hydrocarbons · CPC title

• C01B2203/107

  Platinum catalysts · CPC title

• C01B2203/1064

  Platinum group metal catalysts · CPC title

• C01B2203/0261

  containing a catalytic partial oxidation step [CPO] · CPC title

• C01B2203/0238

  the reforming step being a carbon dioxide reforming step · CPC title