Apparatus and method for continuously producing carbon nanotubes

Patent metadata

Field	Value
Publication number	US-9630160-B2
Application number	US-201414152853-A
Country	US
Kind code	B2
Filing date	Jan 10, 2014
Priority date	Apr 4, 2011
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

Disclosed are an apparatus and method for continuously producing carbon nanotubes. More specifically, disclosed are an apparatus for continuously producing carbon nanotubes including i) a reactor to synthesize carbon nanotubes, ii) a separator to separate a mixed gas from the carbon nanotubes transferred from the reactor, iii) a filter to remove all or part of one or more component gases from the separated mixed gas, and iv) a recirculation pipe to recirculate the filtered mixed gas to the reactor for carbon nanotubes.
Advantageously, the apparatus and method for continuously producing carbon nanotubes enable rapid processing, exhibit superior productivity and excellent conversion rate of a carbon source, significantly reduce production costs, reduce energy consumption due to decrease in reactor size relative to capacity, and generate little or no waste gas and are thus environmentally friendly.

First claim

The invention claimed is:

1. A method for continuously producing carbon nanotubes comprising:
i) reacting a reaction gas containing a carbon source, a reducing gas and an inert gas with a catalyst in a reactor to synthesize carbon nanotubes;
ii) separating a mixed gas from the synthesized carbon nanotubes to produce a separated mixed gas;
iii) filtering the separated mixed gas to remove 20 to 40% of the reducing gas to produce a filtered separated mixed gas;
iv) recirculating the filtered separated mixed gas to the reaction i),
wherein the reactor is a rotary kiln reactor,
wherein an unreacted carbon source contained in the mixed gas is controlled to be 5 to 20% of carbon source supplied to the reactor and
wherein the method further comprises adding carbon source corresponding to an amount consumed during the reaction i) to the filtered separated mixed gas of the recirculation.

2. The method according to claim 1 , wherein the amount of the reducing gas removed during the filtration iii) is equivalent to the amount of the reducing gas produced in the reaction.

3. The method according to claim 1 , wherein a molar ratio of the carbon source to the reducing gas in the reaction is 1:0.5 to 1:10.

4. The method according to claim 1 , wherein the filtration iii) is carried out using a hydrogen PSA unit.

5. The method according to claim 1 , wherein the filtration is carried out using a metal membrane gas separation unit.

6. A method for continuously producing carbon nanotubes comprising:
i) reacting a reaction gas containing a carbon source, a reducing gas and an inert gas with a catalyst in a reactor to synthesize carbon nanotubes;
ii) separating a mixed gas from the synthesized carbon nanotubes to produce a separated mixed gas;
iii) filtering the separated mixed gas to remove 19 to 34% of the reducing gas to produce a filtered separated mixed gas;
iv) recirculating a filtered separated mixed gas to the reaction i),
wherein the reactor is a fluidized bed reactor,
wherein a fluidized bed is formed in the reactor, the catalyst contacts the reaction gas in the fluidized bed to cause reaction,
wherein the carbon nanotubes are grown on an activated metal of the catalyst, as the reaction progresses, and are then discharged from the reactor when a bulk density of the product is 0.01 to 0.1 g/cm3,
wherein a fluidization velocity of the fluidized bed formed in the fluidized bed reactor is 0.1 to 25 cm/s,
wherein an unreacted carbon source contained in the mixed gas is controlled to be 5 to 20% of carbon source supplied to the reactor, and
wherein the method further comprises adding carbon source corresponding to an amount consumed during the reaction i) to the filtered separated mixed gas of the recirculation.

Assignees

• Lg Chemical Ltd

Inventors

• Chang Kwang-Hyun
• Kim Jin-Do
• Yoon Kwang-Woo

Classifications

• B01J8/0055 Primary

  using cyclones · CPC title

• B01J8/006

  by filtration · CPC title

• B01J8/025

  in a cylindrical shaped bed · CPC title

• B01J2208/00548

  Flow · CPC title

• B01J2208/00274

  involving reactant vapours · CPC title