Resin composition, and prepreg as well as laminate using the same

Patent metadata

Field	Value
Publication number	US-9629239-B2
Application number	US-201214001752-A
Country	US
Kind code	B2
Filing date	Mar 5, 2012
Priority date	Mar 7, 2011
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A resin composition is provided which can be suitably used in a printed wiring board having high glass transition temperature, high copper foil peel strength, heat resistance in moisture absorption, flame resistance, resistance to soldering heat, low water absorption and high heat dissipation characteristics, and a prepreg using the resin composition, and a laminate as well as a metal foil-clad laminate using the prepreg. There is used a resin composition including an epoxy resin (A), a curing agent (B), a first filler (C), a second filler (D) and a wetting dispersant (E), wherein the first filler (C) is borate particles coated with hexagonal boron nitride.

First claim

The invention claimed is:

1. A resin composition comprising:
an epoxy resin (A) represented by the following general formula (I),

wherein a plurality of R are each independently present and represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or a phenyl group; and n is an average value and represents 1<n≦20;
a curing agent (B) comprising a cyanate ester compound represented by the following general formula (II),

wherein R represents a hydrogen atom or a methyl group, and n represents an integer of 1 to 50;
a first filler (C);
a second filler (D); and
a wetting dispersant (E) comprising a copolymer containing at least one functional group comprising an acid group, wherein a content of the wetting dispersant (E) is 0.1 to 20 parts by mass based on 100 parts by mass of a total of the components (A) to (D);
wherein a content of the epoxy resin (A) is 10 to 90 parts by mass based on 100 parts by mass of a total of the epoxy resin (A) and the curing agent (B);
wherein a content of the curing agent (B) is 10 to 90 parts by mass based on 100 parts by mass of a total of the epoxy resin (A) and the curing agent (B);
wherein the first filler (C) is borate particles coated with hexagonal boron nitride, and the second filler (D) is at least one selected from the group consisting of alumina, aluminum nitride, boehmite, and silica, and a content of the first filler (C) is 50 to 350 parts by mass based on 100 parts by mass of a total of the epoxy resin (A) and the curing agent (B), and
further wherein a content of the second filler (D) is 50 to 700 parts by mass based on 100 parts by mass of a total of the epoxy resin (A) and the curing agent (B).

2. The resin composition according to claim 1 , wherein the borate particles are magnesium or calcium borate particles.

3. The resin composition according to claim 1 , wherein an average particle size (D 50 ) of the second filler (D) is 0.1 to 10 μm.

4. The resin composition according to claim 1 , further comprising a silane coupling agent.

5. The resin composition according to claim 1 , wherein the wetting dispersant (E) is a polymer wetting dispersant having an acid value of 20 to 200 mgKOH/g.

6. A prepreg formed by impregnating a base material (F) with the resin composition according to claim 1 .

7. A laminate formed by laminate-molding the prepreg according to claim 6 .

8. A metal foil-clad laminate formed by laminate-molding the prepreg according to claim 6 and a metal foil.

9. A prepreg formed by applying the resin composition according to claim 1 onto a base material (F).

10. A laminate formed by laminate-molding the prepreg according to claim 9 .

11. A metal foil-clad laminate formed by laminate-molding the prepreg according to claim 9 and a metal foil.

Assignees

• OHTSUKA Hajime
• Ueyama Daisuke
• Sogame Masanobu
• Mitsubishi Gas Chemical Co

Inventors

• OHTSUKA Hajime
• Ueyama Daisuke
• Sogame Masanobu

Classifications

• B32B2262/101

  Glass fibres · CPC title

• B32B2264/102

  Oxide or hydroxide · CPC title

• B32B2264/104

  Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles · CPC title

• C08K3/013

  Fillers, pigments or reinforcing additives · CPC title

• C08K2003/387

  Borates · CPC title