Method for manufacturing lithium-containing composite oxide

Patent metadata

Field	Value
Publication number	US-9627686-B2
Application number	US-201514595355-A
Country	US
Kind code	B2
Filing date	Jan 13, 2015
Priority date	Mar 18, 2011
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

To simply manufacture a lithium-containing oxide at lower manufacturing cost. A method for manufacturing a lithium-containing composite oxide expressed by a general formula LiMPO 4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)). A solution containing Li and P is formed and then is dripped in a solution containing M (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) to form a mixed solution. By a hydrothermal method using the mixed solution, a single crystal particle of a lithium-containing composite oxide expressed by the general formula LiMPO 4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) is manufactured.

First claim

What is claimed is:

1. A lithium-containing composite oxide comprising a single crystal particle,
wherein the lithium-containing composite oxide has an olivine structure,
wherein the single crystal particle has a flat shape having a first side in an a-axis direction, a second side in a b-axis direction, and a third side in a c-axis direction,
wherein a length of the second side is shorter than each of lengths of the first and third sides, and
wherein the length of the second side is longer than or equal to 5 nm and shorter than or equal to 50 nm.

2. The lithium-containing composite oxide according to claim 1 , wherein the length of the second side is longer than or equal to 5 nm and shorter than or equal to 20 nm.

3. The lithium-containing composite oxide according to claim 1 , wherein a ratio of the length of the first side to the length of the third side is greater than or equal to 0.5 and less than or equal to 1.5.

4. The lithium-containing composite oxide according to claim 3 , wherein the ratio of the length of the first side to the length of the third side is greater than or equal to 0.8 and less than or equal to 1.2.

5. The lithium-containing composite oxide according to claim 1 , wherein the lithium-containing composite oxide is selected from the group consisting of LiFePO 4 , LiNiPO 4 , LiCoPO 4 , LiMnPO 4 , LiFe a Ni b PO 4 , LiFe a Co b PO 4 , LiFe a Mn b PO 4 , LiNi a Co b PO 4 , LiNi a Mn b PO 4 (a+b≦1, 0<a<1, 0<b<1), LiFe c Ni d Co e PO 4 , LiFe c Ni d Mn e PO 4 , LiNi c Co d Mn e PO 4 (c+d+e≦1, 0<c<1, 0<d<1, 0<e<1), LiFe f Ni g Co h Mn i PO 4 (f+g+h+i≦1, 0<f<1, 0<g<1, 0<h<1, 0<i<1).

6. A positive electrode comprising:
a positive electrode current collector; and
a positive electrode active material layer on the positive electrode current collector,
wherein the positive electrode active material layer comprises lithium-containing composite oxides each comprising a single crystal particle,
wherein the lithium-containing composite oxides have olivine structures,
wherein the single crystal particle has a flat shape having a first side in an a-axis direction, a second side in a b-axis direction, and a third side in a c-axis direction,
wherein a length of the second side is shorter than each of lengths of the first and third sides, and
wherein the length of the second side is longer than or equal to 5 nm and shorter than or equal to 50 nm.

7. The positive electrode according to claim 6 , wherein the length of the second side is longer than or equal to 5 nm and shorter than or equal to 20 nm.

8. The positive electrode according to claim 6 , wherein a ratio of the length of the first side to the length of the third side is greater than or equal to 0.5 and less than or equal to 1.5.

9. The positive electrode according to claim 8 , wherein the ratio of the length of the first side to the length of the third side is greater than or equal to 0.8 and less than or equal to 1.2.

10. The positive electrode according to claim 6 , wherein the lithium-containing composite oxides are selected from the group consisting of LiFePO 4 , LiNiPO 4 , LiCoPO 4 , LiMnPO 4 , LiFe a Ni b PO 4 , LiFe a Co b PO 4 , LiFe a Mn b PO 4 , LiNi a Co b PO 4 , LiNi a Mn b PO 4 (a+b≦1, 0<a<1, 0<b<1), LiFe c Ni d Co e PO 4 , LiFe c Ni d Mn e PO 4 , LiNi c Co d Mn e PO 4 (c+d+e≦1, 0<c<1, 0<d<1, 0<e<1), LiFe f Ni g Co h Mn i PO 4 (f+g+h+i≦1, 0<f<1, 0<g<1, 0<h<1, 0<i<1).

11. The positive electrode according to claim 6 , wherein the positive electrode active material layer further comprises a carbon layer covering the lithium-containing composite oxides with a thickness of greater than or equal to 1 nm and less than or equal to 10 nm.

12. The positive electrode according to claim 6 , wherein a thickness of the positive electrode active material layer is in a range of 20 μm to 100 μm.

13. A lithium-ion secondary battery comprising:
a negative electrode comprising a negative electrode current collector and a negative electrode active material layer;
a positive electrode comprising a positive electrode current collector and a positive electrode active material layer; and
a separator between the negative electrode and the positive electrode,
wherein the positive electrode active material layer comprises lithium-containing composite oxides each comprising a single crystal particle,
wherein the lithium-containing composite oxides have olivine structures,
wherein the single crystal particle has a flat shape having a first side in an a-axis direction, a second side in a b-axis direction, and a third side in a c-axis direction,
wherein a length of the second side is shorter than each of lengths of the first and third sides, and
wherein the length of the second side is longer than or equal to 5 nm and shorter than or equal to 50 nm.

14. The lithium-ion secondary battery according to claim 13 , wherein the length of the second side is longer than or equal to 5 nm and shorter than or equal to 20 nm.

15. The lithium-ion secondary battery according to claim 13 , wherein a ratio of the length of the first side to the length of the third side is greater than or equal to 0.5 and less than or equal to 1.5.

16. The lithium-ion secondary battery according to claim 15 , wherein the ratio of the length of the first side to the length of the third side is greater than or equal to 0.8 and less than or equal to 1.2.

17. The lithium-ion secondary battery according to claim 13 , wherein the lithium-containing composite oxides are selected from the group consisting of LiFePO 4 , LiNiPO 4 , LiCoPO 4 , LiMnPO 4 , LiFe a Ni b PO 4 , LiFe a Co b PO 4 , LiFe a Mn b PO 4 , LiNi a Co b PO 4 , LiNi a Mn b PO 4 (a+b≦1, 0<a<1, 0<b<1), LiFe c Ni d Co e PO 4 , LiFe c Ni d Mn e PO 4 , LiNi c Co d Mn e PO 4 (c+d+e≦1, 0<c<1, 0<d<1, 0<e<1), LiFe f Ni g Co h Mn i PO 4 (f+g+h+i≦1, 0<f<1, 0<g<1, 0<h<1, 0<i<1).

18. The lithium-ion secondary battery according to claim 13 , wherein the positive electrode active material layer further comprises a carbon layer covering the lithium-containing composite oxides with a thickness of greater than or equal to 1 nm and less than or equal to 10 nm.

19. The lithium-ion secondary battery according to claim 13 , wherein a thickness of the positive electrode active material layer is in a range of 20 μm to 100 μm.

Assignees

• Semiconductor Energy Lab

Inventors

• Futamura Tomoya

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/5825 Primary

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• C01B25/45

  containing plural metal, or metal and ammonium · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title