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US-12180196-B2 · Dec 31, 2024 · US
US9627630B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9627630-B2 |
| Application number | US-201514595611-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 13, 2015 |
| Priority date | Dec 13, 2006 |
| Publication date | Apr 18, 2017 |
| Grant date | Apr 18, 2017 |
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Disclosed is an organic electroluminescent device having long life, while exhibiting high luminous efficiency. Also disclosed are an illuminating device and a display, each using such an organic electroluminescent device. In the organic electroluminescent device, a compound represented by the general formula (A) which is suitable as a host material for a phosphorescent metal complex is used at least in one sublayer of a light-emitting layer.
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The invention claimed is: 1. An organic electroluminescent element comprising a substrate having thereon at least an anode and a cathode, and a light emitting layer between the aforesaid anode and the aforesaid cathode, wherein at least one light emitting layer incorporates a compound represented by Formula (A): wherein A1 and A2 each represent a hydrogen atom or a nitrogen-atom containing substituent selected from the group consisting of a carbazolyl group, a carbolinyl group represented by Formula (a), and a diarylamino group, provided that at least one of A1 and A2 represents the carbazolyl group; X and Y each represent O; L1 and L2 each represent a divalent linking group; L3 represents a m-phenylene group; n represents an integer of 1 or 2; n1 and n2 each represent an integer of 1 or 2; and n3 and n4 each represent 0 or 1; wherein X 1 -X 8 each represent a nitrogen atom or —C(Ra)═; and at least one of the aforesaid X 1 -X 8 represents a nitrogen atom; and Ra and Rb each represent a hydrogen atom or a substituent. 2. The organic electroluminescent element of claim 1 , wherein both A1 and A2 in Formula (A) represent the carbazolyl group. 3. The organic electroluminescent element of claim 1 , wherein the aforesaid light emitting layer incorporates a phosphorescence emitting metal complex. 4. The organic electroluminescent element of claim 3 , wherein the aforesaid phosphorescence emitting metal complex is an Ir complex. 5. The organic electroluminescent element of claim 3 , wherein the aforesaid phosphorescence emitting metal complex is represented by Formula (B): wherein R 1 represents a substituent; Z represents a group of non-metal atoms necessary for forming a 5-7 membered ring; n 1 represents an integer of 0-5; B 1 -B 5 each represents a carbon atom, a nitrogen atom, an oxygen atom, or a sulfur atom and at least one represents a nitrogen atom; M 1 represents a metal of Groups 8-10 in the element periodic table; X 1 and X 2 each represents a carbon atom, a nitrogen atom, or an oxygen atom; L 1 represents a group of atoms which form a bidentate ligand with X 1 and X 2 ; m1 represents 1, 2, or 3; and m2 represents 0, 1, or 2, provided that a sum of m1 and m2 is 2 or 3. 6. The organic electroluminescent element of claim 5 , wherein m2 of the phosphorescence emitting metal complex represented by the aforesaid Formula (B) is 0. 7. The organic electroluminescent element of claim 5 , wherein a nitrogen-containing heterocyclic ring formed by phosphorescence emitting metal complexes B 1 -B 5 in the aforesaid Formula (B) is an imidazole ring. 8. The organic electroluminescent element of claim 1 , emitting a white light. 9. A display device provided with the organic electroluminescent element of claim 1 . 10. An illuminating device provided with the organic electroluminescent element of claim 1 .
containing organic luminescent materials · CPC title
with sulfur · CPC title
containing oxygen as the only heteroatom · CPC title
Ortho-condensed systems · CPC title
containing three or more hetero rings · CPC title
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