Toner having silica fine particles

Patent metadata

Field	Value
Publication number	US-9625841-B2
Application number	US-201615217379-A
Country	US
Kind code	B2
Filing date	Jul 22, 2016
Priority date	Dec 27, 2011
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A magnetic toner contains magnetic toner particles containing a binder resin, a release agent, and a magnetic body, and inorganic fine particles present on the surface of the magnetic toner particles, wherein a ratio of coverage of the magnetic toner particles' surface by the inorganic fine particles is in a prescribed range for the magnetic toner, the inorganic fine particles contain prescribed metal oxide fine particles, with at least 85 mass % of the metal oxide fine particles being silica fine particles, the coefficient of variation on the coverage ratio A is in a prescribed range, the binder resin contains a styrene resin, in a GPC measurement of a THF-soluble matter in the magnetic toner, a peak molecular weight (Mp) of a main peak is in a prescribed range, and a prescribed fatty acid ester compound is incorporated as a release agent.

First claim

The invention claimed is:

1. A toner comprising
toner particles containing a binder resin comprising styrene resin, and release agent comprising at least one fatty acid ester compound having a melting point of 60° C. to 90° C. selected from the group consisting of a tetrafunctional fatty acid ester compound, a pentafunctional fatty acid ester compound and a hexafunctional fatty acid ester compound; and
inorganic fine particles present on the surface of the toner particles, the inorganic fine particles comprising metal oxide fine particles, said metal oxide fine particles containing silica fine particles, and optionally containing titania fine particles and alumina fine particles, a content of the silica fine particles being at least 85 mass % with respect to a total mass of the silica, titania and alumina fine particles, wherein
when a coverage ratio A (%) is a coverage ratio of the toner particles' surface by the inorganic fine particles and a coverage ratio B (%) is a coverage ratio of the toner particles' surface by the inorganic fine particles that are fixed on the toner particles' surface, the toner has a coverage ratio A of 45.0% to 70.0% and a coefficient of variation on the coverage ratio A of not more than 10.0%,
B/A is 0.50 to 0.85, and
a peak molecular weight (Mp) of a main peak is from 4000 to 8000 in a measurement using gel permeation chromatography of a tetrahydrofuran-soluble matter in the toner.

2. The toner according to claim 1 , wherein the fatty acid ester compound comprises an ester of a C 18-22 fatty acid and an alcohol having 4 to 6 hydroxyl groups.

3. The toner according to claim 1 , wherein an average circularity of the toner is 0.935 to 0.955.

4. The toner according to claim 3 , wherein an average circularity of the toner is 0.938 to 0.950.

5. The toner according to claim 2 , wherein an average circularity of the toner is 0.935 to 0.955.

6. The toner according to claim 5 , wherein an average circularity of the toner is 0.938 to 0.950.

7. The toner according to claim 1 , wherein a glass-transition temperature (Tg) of the toner is 40° C. to 70° C.

8. The toner according to claim 6 , wherein a glass-transition temperature (Tg) of the toner is 40° C. to 70° C.

9. The toner according to claim 1 , wherein the release agent is 0.1 to 20 mass parts per 100 mass parts of the binder resin.

10. The toner according to claim 8 , wherein the release agent is 0.1 to 20 mass parts per 100 mass parts of the binder resin.

11. The toner according to claim 1 , wherein the sum of proportion of the tetrafunctional fatty acid ester compound, the pentafunctional fatty acid ester compound and the hexafunctional fatty acid ester compound is 20 to 80 mass % based on the mass of the release agent.

12. The toner according to claim 10 , wherein the sum of proportion of the tetrafunctional fatty acid ester compound, the pentafunctional fatty acid ester compound and the hexafunctional fatty acid ester compound is 20 to 80 mass % based on the mass of the release agent.

13. The toner according to claim 2 , wherein the alcohol is pentaerythritol or dipentaerythritol.

14. The toner according to claim 12 , wherein the alcohol is pentaerythritol or dipentaerythritol.

15. The toner according to claim 1 , wherein the inorganic fine particles are 1.5 to 3.0 mass parts per 100 mass parts of the toner particles.

16. The toner according to claim 14 , wherein the inorganic fine particles are 1.5 to 3.0 mass parts per 100 mass parts of the toner particles.

Assignees

• Canon Kk

Inventors

• Hiroko Shuichi
• Magome Michihisa
• Hasegawa Yusuke
• Suzumura Yoshitaka

Classifications

• G03G9/08711

  with esters of acrylic or methacrylic acid · CPC title

• G03G9/08782

  Waxes · CPC title

• G03G9/0833

  Oxides · CPC title

• G03G9/0839 Primary

  Treatment of the magnetic components; Combination of the magnetic components with non-magnetic materials (G03G9/0834 takes precedence) · CPC title

• G03G9/0806

  whereby chemical synthesis of at least one of the toner components takes place · CPC title