Segmented metallic nanostructures, homogeneous metallic nanostructures and methods for producing same

Patent metadata

Field	Value
Publication number	US-9624598-B2
Application number	US-201314011864-A
Country	US
Kind code	B2
Filing date	Aug 28, 2013
Priority date	Sep 6, 2012
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

The present invention includes a method of producing a segmented 1D nanostructure. The method includes providing a vessel containing a template wherein on one side of the template is a first metal reagent solution and on the other side of the template is a reducing agent solution, wherein the template comprises at least one pore; allowing a first segment of a 1D nanostructure to grow within a pore of the template until a desired length is reached; replacing the first metal reagent solution with a second metal reagent solution; allowing a second segment of a 1D nanostructure to grow from the first segment until a desired length is reached, wherein a segmented 1D nanostructure is produced.

First claim

The invention claimed is:

1. A method of producing a segmented 1D nanostructure, the method comprising:
providing a vessel containing a template wherein on one side of the template is a first metal reagent solution and on the other side of the template is a reducing agent solution, wherein the template comprises at least one pore;
allowing a first segment of a 1D nanostructure to grow within a pore of the template until a desired length is reached;
replacing the first metal reagent solution with a second metal reagent solution;
allowing a second segment of a 1D nanostructure to grow from the first segment until a desired length is reached,
wherein a segmented 1D nanostructure is produced.

2. The method according to claim 1 further comprising growing at least one additional segment from the 1D nanostructure.

3. The method of claim 1 wherein the length of a segment is increased by increasing the growth time.

4. The method of claim 1 wherein before allowing the second segment to grow, the concentration of the reducing agent is increased by about two fold to about fifty fold.

5. The method of claim 4 wherein region of alloying on the nanostructure is less than about 100 nm.

6. The method of claim 1 wherein nucleation of the first segment of the nanostructure occurs at an interface of a pore of the template and the reducing agent solution.

7. The method of claim 1 wherein the metals of the first metal reagent solution and the second metal reagent solution are different from one another and wherein the metals are selected from the group consisting of transition metals, actinide metal and lanthanide metals.

8. The method of claim 7 wherein the metals are selected from the group consisting of Ru, Rh, Pd, Ag, Os, Ir, Pt and Au.

9. The method of claim 1 wherein the reducing agent of the reducing agent solution comprises at least one of metal borohydrides, sodium cyanoborohydride, citric acid, citrate anion, ascorbic acid, ascorbate anion, formic acid, formate anion, oxalic acid, oxalate anion, lithium aluminum hydride, diborane, alpine borane, hydrogen gas, hydrazine, and 2-mercaptoethanol.

10. The method of claim 1 , wherein the 1D nanostructure is a nanowire, a nanotube, or an array comprising a plurality of nanowires.

Assignees

• Univ New York State Res Found

Inventors

• Wong Stanislaus
• Koenigsmann Christopher

Classifications

• B22F1/0547

  Nanofibres or nanotubes · CPC title

• C30B29/52

  Alloys · CPC title

• Y10T428/12493

  Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] · CPC title

• C30B29/60

  characterised by shape · CPC title

• C30B29/02

  Elements · CPC title