Method for recovering an electropositive metal from a metal carbonate

Patent metadata

Field	Value
Publication number	US-9624590-B2
Application number	US-201314412792-A
Country	US
Kind code	B2
Filing date	Jun 25, 2013
Priority date	Jul 5, 2012
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A method recovers an electropositive metal from a metal carbonate. In the method, hydrogen and halogen are combusted to form hydrogen halide. The solid metal carbonate is converted into metal chloride by a gaseous hydrogen halide. In an electrolysis, the metal chloride is decomposed into metal and halogen. The halogen produced in the electrolysis is led out of the electrolysis for combusting. Preferably, the hydrogen halide is produced by combusting the hydrogen and the halogen and the metal carbonate is converted into metal chloride in a fluidized bed reactor. Preferably, lithium is used as the metal.

First claim

The invention claimed is:

1. A process for recovering an electropositive metal from a solid metal carbonate, comprising:
in a carbonate-halide reaction process, reacting a portion of the solid metal carbonate with a gaseous hydrogen halide to produce a portion of dry metal halide;
performing an electrolysis of the portion of dry metal halide to yield the electropositive metal and a halogen;
reacting the electropositive metal, in an unreacted, unstable electropositive state, with carbon dioxide to produce a further portion of the solid metal carbonate; and
using the halogen to prepare further gaseous hydrogen halide for reaction with the further portion of the solid metal carbonate in the carbonate-halide reaction process to produce a further portion of dry metal halide.

2. The process as claimed in claim 1 , wherein the solid metal carbonate is an alkali metal carbonate.

3. The process as claimed in claim 2 , wherein the alkali metal carbonate is lithium carbonate.

4. The process as claimed in claim 1 , wherein the solid metal carbonate is an alkaline earth metal carbonate.

5. The process as claimed in claim 4 , wherein the alkaline earth metal carbonate is magnesium or calcium carbonate.

6. The process as claimed in claim 1 , further comprising forming the further gaseous hydrogen halide by combusting hydrogen and the halogen.

7. The process as claimed in claim 6 , wherein the halogen is chlorine,
the combusting of the hydrogen and the chlorine generates heat, and
the heat generated while combusting the hydrogen and the chlorine heats the carbonate-halide reaction process.

8. The process as claimed in claim 7 , wherein the carbonate-halide reaction is carried out at a temperature of at least 100° C.

9. The process as claimed in claim 8 , wherein
the further gaseous hydrogen halide is formed from hydrogen and chlorine, and
the hydrogen used to form the further gaseous hydrogen halide is produced by water electrolysis.

10. The process as claimed in claim 9 , wherein excess power from renewable energy is used for the electrolysis of the metal halide and the water electrolysis.

11. The process as claimed in claim 1 , wherein
the carbonate-halide reaction process is carried out at a temperature of at least 100° C.

12. The process as claimed in claim 1 , wherein the halogen is chlorine.

13. The process as claimed in claim 1 , wherein
the further gaseous hydrogen halide is formed from hydrogen and the halogen, and
the hydrogen used to form the further gaseous hydrogen halide is produced by water electrolysis.

14. The process as claimed in claim 13 , wherein excess power from renewable energy is used for at least one of the electrolysis of the metal halide and the water electrolysis.

15. The process as claimed in claim 1 , comprising reacting the electropositive metal, in the unreacted, electropositive state, with carbon dioxide to produce (a) the further portion of the solid metal carbonate and (b) acetylene.

Assignees

• Siemens Ag

Inventors

• Baldauf Manfred
• Schmid Guenter
• Taroata Dan

Classifications

• C25B1/26

  Chlorine; Compounds thereof (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• B01J8/24

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• C25C1/00 Primary

  Electrolytic production, recovery or refining of metals by electrolysis of solutions (C25C5/00 takes precedence) · CPC title

• C25C3/00

  Electrolytic production, recovery or refining of metals by electrolysis of melts (C25C5/00 takes precedence) · CPC title

• C25C3/02

  of alkali or alkaline earth metals · CPC title