Using fossil fuels to increase biomass-based fuel benefits

Patent metadata

Field	Value
Publication number	US-9624440-B2
Application number	US-201314060965-A
Country	US
Kind code	B2
Filing date	Oct 23, 2013
Priority date	Mar 8, 2010
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

In the production of fuel such as ethanol from carbonaceous feed material such as biomass, a stream comprising hydrogen and carbon monoxide is added to the raw gas stream derived from the feed material, and the resulting combined stream is converted into fuel and a gaseous byproduct such as by a Fischer-Tropsch reaction. The gaseous byproduct may be utilized in the formation of the aforementioned stream comprising hydrogen and carbon monoxide.

First claim

What is claimed is:

1. A method comprising
(A) providing a gaseous product stream which is formed from fossil-fuel-based hydrocarbon feed and which comprises hydrogen and carbon monoxide at a mole ratio of H2:CO of at least 2.0:1;
(B) forming a syngas stream that is derived from carbonaceous feed material and subjecting this syngas stream to partial oxidation; and
(C) adding the gaseous product stream provided in step (A) to the partially oxidized syngas stream derived from carbonaceous feed material and containing hydrogen and CO, in a sufficient amount to form a mixed syngas stream having a H2:CO mole ratio higher than that of said partially oxidized syngas stream derived from carbonaceous feed material.

2. A method according to claim 1 , wherein up to 100% of a byproduct stream obtained from the conversion of said mixed syngas stream to form product fuel is reacted in said formation of said gaseous product stream that is provided in step (A), wherein said byproduct stream comprises one or more of hydrogen, CO, water vapor, methane and hydrocarbon containing at least 2 carbon atoms and 0 to 2 oxygen atoms.

3. A method comprising
(A) providing fossil-fuel-based hydrocarbon feed;
(B) forming from said fossil-fuel-based hydrocarbon feed a gaseous product stream comprising hydrogen and carbon monoxide at a mole ratio of H2:CO of at least 2.0:1;
(C) forming a syngas stream that is derived from carbonaceous feed material and subjecting this syngas stream to partial oxidation; and
(D) adding the gaseous product stream formed in step (B) to the partially oxidized syngas stream derived from carbonaceous feed material, in a sufficient amount to form a mixed syngas stream having a H2:CO mole ratio higher than that of said partially oxidized syngas stream derived from carbonaceous feed material.

4. A method according to claim 3 , also including the step of
(D) reacting up to 100% of a byproduct stream obtained from the conversion of said mixed syngas stream to form product fuel in said formation of said gaseous product stream in step (B), wherein said byproduct stream comprises one or more of hydrogen, CO, water vapor, methane and hydrocarbon containing at least 2 carbon atoms and 0 to 2 oxygen atoms.

5. A method comprising
(A) deriving a syngas stream from carbonaceous feed material, wherein the syngas stream contains hydrogen and CO and subjecting the syngas stream to partial oxidation; and
(B) adding to the syngas stream derived in step (A) a gaseous product stream comprising hydrogen and carbon monoxide, wherein the mole ratio of H2:CO of said gaseous product stream is at least 2.0:1, and wherein said gaseous product stream is formed from fossil-fuel-based hydrocarbon feed,
wherein adding said gaseous product stream to said partially oxidized syngas stream forms a mixed syngas stream having a H2:CO mole ratio higher than that of said partially oxidized syngas stream derived from carbonaceous feed material.

6. A method according to claim 5 , wherein up to 100% of a byproduct stream obtained from the conversion of said mixed syngas stream to form product fuel is reacted in said formation of said gaseous product stream that is added in step (B), wherein said byproduct stream comprises one or more of hydrogen, CO, water vapor, methane and hydrocarbon containing at least 2 carbon atoms and 0 to 2 oxygen atoms.

Assignees

• Chakravarti Shrikar
• Drnevich Raymond Francis
• Bonaquist Dante Patrick
• Panuccio Gregory
• Praxair Technology Inc

Inventors

• Chakravarti Shrikar
• Drnevich Raymond Francis
• Bonaquist Dante Patrick
• Panuccio Gregory

Classifications

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• C10J2300/0909

  Drying · CPC title

• C10G2/30 Primary

  from carbon monoxide with hydrogen · CPC title

• C10J3/18

  using electricity · CPC title

• C10G2/32

  with the use of catalysts · CPC title