Adhesive film for polarizing plate, polarizing plate including the same and optical display including the same

Patent metadata

Field	Value
Publication number	US-9624403-B2
Application number	US-201514923297-A
Country	US
Kind code	B2
Filing date	Oct 26, 2015
Priority date	Oct 24, 2014
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

An adhesive film for polarizing plates has a K value of about 0.2 to about 0.5, as calculated by Equation 1. A polarizing plate includes the adhesive film for polarizing plates. An optical display includes the polarizing plate. The adhesive films for polarizing plates according to embodiments of the invention suppress light leakage due to dimensional changes in the polarizing plates at high temperature and/or high humidity.

K=ΔG′×ΔR 0   Equation 1

First claim

What is claimed is:

1. An acrylic adhesive film for polarizing plates, the acrylic adhesive film having a K value of about 0.2 to about 0.5, as calculated by Equation 1:
K=ΔG′×ΔR 0   Equation 1

wherein ΔG′ is defined by Equation 2, and ΔR 0 is defined by Equation 3;
Δ G′=G 1− G 2  Equation 2

wherein G1 is a storage modulus in MPa at 23° C. and G2 is a storage modulus in MPa at 85° C., as measured from a 500 μm thick stacked adhesive film for polarizing plates by temperature sweep testing under a strain of 5%, a normal force of 100 N and an angular frequency of 1 rad/sec while elevating temperature from 0° C. to 100° C. at a rate of 10° C./min using an advanced rheometry expansion system;
Δ R 0 =R 01 −R 02   Equation 3

wherein R 01 is retardation in nm at 85° C. at a wavelength of 590 nm, and R 02 is retardation in nm at 23° C. at a wavelength of 590 nm, as measured from a 1 mm thick adhesive film for polarizing plates upon application of a stress of 125 mN/15 mm while elevating temperature from 0° C. to 100° C. at a rate of 10° C./min.

2. The adhesive film for polarizing plates according to claim 1 , wherein the G1 of the adhesive film is about 0.45 MPa to about 1 MPa.

3. The adhesive film for polarizing plates according to claim 1 , wherein the G2 of the adhesive film is about 0.01 MPa to about 0.3 MPa.

4. The adhesive film for polarizing plates according to claim 1 , wherein the adhesive film is formed of an adhesive composition for polarizing plates comprising (A) a crosslinkable (meth)acrylic copolymer containing a crosslinkable functional group, (B) a non-crosslinkable (meth)acrylic copolymer having positive birefringence, and (C) a curing agent.

5. The adhesive film for polarizing plates according to claim 4 , wherein the (A) crosslinkable (meth)acrylic copolymer is a copolymer of a monomer mixture comprising a crosslinkable functional group-containing monomer, and the crosslinkable functional group-containing monomer is present in an amount of about 1 wt % to about 20 wt % in the monomer mixture.

6. The adhesive film for polarizing plates according to claim 4 , wherein the (B) non-crosslinkable (meth)acrylic copolymer is a copolymer of a monomer mixture comprising a crosslinkable functional group-containing monomer, and the crosslinkable functional group-containing monomer is present in an amount of less than about 1 wt % in the monomer mixture.

7. The adhesive film for polarizing plates according to claim 4 , wherein each of the (A) crosslinkable (meth)acrylic copolymer and the (B) non-crosslinkable (meth)acrylic copolymer has a weight average molecular weight of less than about 1,000,000 g/mol.

8. The adhesive film for polarizing plates according to claim 4 , wherein the (B) non-crosslinkable (meth)acrylic copolymer has a weight average molecular weight of about 300,000 g/mol to less than about 1,000,000 g/mol.

9. The adhesive film for polarizing plates according to claim 4 , wherein the (A) crosslinkable (meth)acrylic copolymer is a copolymer of a monomer mixture comprising: at least one of a hydroxyl group-containing (meth)acrylic monomer or a carboxylic acid group-containing (meth)acrylic monomer; and an alkyl group-containing (meth)acrylic monomer.

10. The adhesive film for polarizing plates according to claim 4 , wherein the (B) non-crosslinkable (meth)acrylic copolymer is a copolymer of a monomer mixture comprising an aromatic group-containing (meth)acrylic monomer, an alkyl group-containing (meth)acrylic monomer, and a (meth)acrylic monomer represented by Formula 2:

wherein A is a C 1 to C 20 aliphatic hydrocarbon group; B is —O— or —S—; R 1 is hydrogen or a methyl group; R 2 is a C 1 to C 20 aliphatic hydrocarbon group; and n is an integer of 1 to 5.

11. The adhesive film for polarizing plates according to claim 10 , wherein the (meth)acrylic monomer represented by Formula 2 comprises 2-(2-ethoxyethoxy)ethyl (meth)acrylate.

12. The adhesive film for polarizing plates according to claim 4 , wherein the (A) crosslinkable (meth)acrylic copolymer is present in an amount of about 60 parts by weight to about 95 parts by weight, and the (B) non-crosslinkable (meth)acrylic copolymer is present in an amount of about 5 parts by weight to about 40 parts by weight, each based on 100 parts by weight of the (A) crosslinkable (meth)acrylic copolymer and the (B) non-crosslinkable (meth)acrylic copolymer.

13. The adhesive film for polarizing plates according to claim 4 , wherein the adhesive composition for polarizing plates further comprises a silane coupling agent.

14. A polarizing plate comprising the adhesive film for polarizing plates according to claim 1 .

15. An optical display comprising the polarizing plate according to claim 14 .

Assignees

• Samsung Sdi Co Ltd

Inventors

• Kim Won
• Kim Yi Eun
• Suh Yoo Jin
• Jeong Chul
• Cho Ha Yun
• Han In Cheon

Classifications

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B27/325

  comprising polycycloolefins · CPC title

• G02B5/305

  including organic materials, e.g. polymeric layers · CPC title

• B32B27/286

  comprising polysulphones; polysulfides · CPC title

• B32B27/306

  comprising vinyl acetate or vinyl alcohol (co)polymers · CPC title