Superabsorbent polymer

Patent metadata

Field	Value
Publication number	US-9624328-B2
Application number	US-201414440246-A
Country	US
Kind code	B2
Filing date	Apr 28, 2014
Priority date	Apr 30, 2013
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

The present invention relates to a superabsorbent polymer which has excellent initial absorbency and keeps water from flowing out under pressure even after passage of time. The superabsorbent polymer of the present invention is characterized by simultaneously optimizing centrifuge retention capacity (CRC), absorbency under pressure (AUP), liquid permeability (SFC), and gel strength within a predetermined range. The present invention can provide improved physical properties of a final diaper product and apply an ultra-thin technology to the diaper product.

First claim

The invention claimed is:

1. A superabsorbent polymer, of which centrifuge retention capacity (CRC) for a physiological saline solution is 28 g/g or more, absorbency under pressure (AUP) of 0.7 psi for the physiological saline solution is 22 g/g or more, liquid permeability (SFC) is 25×10 −7 cm 3 *sec/g or more, and gel strength is 7500 to 10,800 Pa, wherein the superabsorbent polymer includes a powdery base polymer comprising a crosslinked polymer prepared by polymerizing water-soluble ethylene-based unsaturated monomers having acidic groups which are at least partially neutralized; and a surface crosslinking layer comprising a surface crosslinked polymer prepared by further crosslinking the crosslinked polymer of the powdery base polymer which is formed on the powdery base polymer.

2. The superabsorbent polymer of claim 1 , wherein the base polymer is crosslinked in the presence of one or more internal crosslinking agents selected from the group consisting of a di(meth)acrylate of a polyol having 2 to 20 carbon atoms and a poly(meth)acrylate of a polyol having 2 to 20 carbon atoms; and the surface crosslinking layer is further crosslinked in the presence of one or more surface crosslinking agents selected from the group consisting of a substance satisfying δ p <12 (J/cm 3 ) 1/2 , a substance satisfying 4<δ H <6 (J/cm 3 ) 1/2 , and a substance satisfying δ tot >31(J/cm 3 ) 1/2 , δ p , δ H , and δ tot being defined as Hansen solubility parameters.

3. The superabsorbent polymer of claim 2 , wherein the water-soluble ethylene-based unsaturated monomer is one or more selected from the group consisting of an anionic monomer or salts thereof, a nonionic hydrophilic monomer, and an amino group-containing unsaturated monomer or a quaternary compound thereof, and
in which the anionic monomer is acrylic acid, methacrylic acid, maleic anhydride, fumaric acid, crotonic acid, itaconic acid, 2-acryloylethane sulfonic acid, 2-methacryloylethane sulfonic acid, 2-(meth)acryloylpropane sulfonic acid, or 2-(meth)acrylamide-2-methyl propane sulfonic acid; the nonionic hydrophilic monomer is (meth)acrylamide, N-substituted (meth)acrylate, -2-hydroxyethyl(meth)acrylate, 2-hydroxypropyl(meth)acrylate, methoxy polyethylene glycol (meth)acrylate, or polyethylene glycol (meth)acrylate; and the amino group-containing unsaturated monomer is (N,N)-dimethylaminoethyl(meth)acrylate or (N,N)-dimethylaminopropyl (meth)acrylate.

4. The superabsorbent polymer of claim 2 , wherein the internal crosslinking agent is one or more selected from the group consisting of polyethylene glycol diacrylate, glycerin diacrylate, glycerin triacrylate, and trimethylol triacrylate.

5. The superabsorbent polymer of claim 2 , wherein the substance satisfying δ p <12 (J/cm 3 ) 1/2 is one or more selected from the group consisting of ethylene glycol, 1,4-butanediol, 1,6-hexandiol, propylene glycol, 1,2-hexandiol, 1,3-hexandiol, 2-methyl-1,3-propanediol, 2,5-hexandiol, 2-methyl-1,3-pentanediol, 2-methyl-2,4-pentanediol, tripropylene glycol, and glycerol.

6. The superabsorbent polymer of claim 2 , wherein the substance satisfying 4<δ H <6 (J/cm 3 ) 1/2 is one or more selected from the group consisting of ethylene carbonate and propylene carbonate.

7. The superabsorbent polymer of claim 2 , wherein the substance satisfying δ tot >31 (J/cm 3 ) 1/2 is one or more selected from the group consisting of ethylene glycol, 1,3-propanediol, and glycerol.

8. The superabsorbent polymer of claim 1 , wherein the water-soluble ethylene-based unsaturated monomer is one or more selected from the group consisting of an anionic monomer or salts thereof, a nonionic hydrophilic monomer, and an amino group-containing unsaturated monomer or a quaternary compound thereof, and
in which the anionic monomer is acrylic acid, methacrylic acid, maleic anhydride, fumaric acid, crotonic acid, itaconic acid, 2-acryloylethane sulfonic acid, 2-methacryloylethane sulfonic acid, 2-(meth)acryloylpropane sulfonic acid, or 2-(meth)acrylamide-2-methyl propane sulfonic acid; the nonionic hydrophilic monomer is (meth)acrylamide, N-substituted (meth)acrylate, 2-hydroxyethyl(meth)acrylate, 2 hydroxypropyl(meth)acrylate, methoxy polyethylene glycol (meth)acrylate, or polyethylene glycol (meth)acrylate; and the amino group-containing unsaturated monomer is (N,N)-dimethylaminoethyl(meth)acrylate or (N,N)-dimethylaminopropyl (meth)acrylate.

9. A method for preparing the superabsorbent polymer of claim 1 , including:
the step of performing thermal polymerization or photopolymerization of a monomer composition containing a water-soluble ethylene-based unsaturated monomer, a polymerization initiator, and an internal crosslinking agent to form a water-containing gel polymer;
the step of drying the water-containing gel polymer;
the step of pulverizing the dried polymer; and
the step of adding a surface crosslinking agent to the pulverized polymer to perform a surface crosslinking reaction,
wherein the internal crosslinking agent includes one or more selected from the group consisting of a di(meth)acrylate of a polyol having 2 to 20 carbon atoms and a poly(meth)acrylate of a polyol having 2 to 20 carbon atoms;
the surface crosslinking agent includes one or more selected from the group consisting of a substance satisfying δ p <12 (J/cm 3 ) 1/2 , a substance satisfying 4<δ H <6 (J/cm 3 ) 1/2 , and a substance satisfying δ tot >31 (J/cm 3 ) 1/2 , δ p , δ H , and δ tot being defined as Hansen solubility parameters; and
the step of the surface crosslinking reaction is performed under conditions of a maximum reaction temperature of 190 or higher and a total reaction time of 30 minutes or longer, and of maintaining the reaction temperature at 180° C. or higher for about 25 minutes or longer.

10. The superabsorbent polymer of claim 1 , wherein the liquid permeability (SFC) ranges from 25×10- 7 to 37×10- 7 cm 3 *sec/g.

Assignees

• Lg Chemical Ltd

Inventors

• Won Tae Young
• Nam Dae Woo
• Han Chang Sun

Classifications

• C08F222/102

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• C08J3/245

  Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• C08J2300/14

  Water soluble or water swellable polymers, e.g. aqueous gels · CPC title