Flame retardant modified cellulosic nanomaterials (FR-CNs) prepared using phosphorus-containing monomers

Patent metadata

Field	Value
Publication number	US-9624312-B2
Application number	US-201414226103-A
Country	US
Kind code	B2
Filing date	Mar 26, 2014
Priority date	Mar 26, 2014
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

In accordance with some embodiments of the present invention, a composite material is prepared by blending a flame retardant modified cellulosic nanomaterial (FR-CN) filler into a polymer, wherein the FR-CN filler comprises a cellulosic nanomaterial (e.g., cellulose nanocrystals (CNCs) and/or cellulose nanofibrils (CNFs)) having a surface functionalized to incorporate a phosphorus-containing moiety. In some embodiments, the FR-CN filler is prepared by reacting hydroxyl groups on the surface of the cellulosic nanomaterial and a halogenated phosphorous-containing monomer (e.g., diphenyl phosphoryl chloride). In some embodiments, the surface of the cellulosic nanomaterial is further functionalized to incorporate an orthogonal functionality selected to enhance the compatibility of the FR-CN filler with the polymer by reacting hydroxyl groups on the surface of the cellulosic nanomaterial and a monomer (e.g., epichlorohydrin when the polymer is an epoxy-based polymer).

First claim

What is claimed is:

1. A composite material, comprising:
a polymer;
a flame retardant modified cellulosic nanomaterial blended into the polymer, wherein the flame retardant modified cellulosic nanomaterial comprises a cellulosic nanomaterial having a surface functionalized to incorporate a phosphorus-containing moiety, wherein the surface of the cellulosic nanomaterial is functionalized to incorporate the phosphorus-containing moiety by reacting a halogenated phosphorus-containing monomer and hydroxyl groups on the surface of the cellulosic nanomaterial, wherein the cellulosic nanomaterial is selected from a group consisting of cellulose nanocrystals (CNCs), cellulose nanofibrils (CNFs), and combinations thereof, wherein the halogenated phosphorus-containing monomer is selected from a group consisting of diphenyl phosphoryl chloride, diphenylphosphinic chloride, and combinations thereof,
wherein the surface of the cellulosic nanomaterial is further functionalized to incorporate an orthogonal functionality selected to enhance the compatibility of the flame retardant modified cellulosic nanomaterial with the polymer, wherein the orthogonal functionality is separately appended to the surface of the cellulosic nanomaterial relative to the phosphorus-containing moiety, wherein the surface of the cellulosic nanomaterial is functionalized to incorporate the orthogonal functionality by reacting a compatibilizing monomer and remaining hydroxyl groups on the surface of the cellulosic nanomaterial that remain after reacting the halogenated phosphorus-containing monomer and hydroxyl groups on the surface of the cellulosic nanomaterial,
wherein the polymer is an epoxy-based polymer, and wherein the compatibilizing monomer is epichlorohydrin.

2. The composite material as recited in claim 1 , wherein the halogenated phosphorus-containing monomer is diphenyl phosphoryl chloride.

3. The composite material as recited in claim 1 , wherein the halogenated phosphorus-containing monomer is diphenylphosphinic chloride.

4. An article of manufacture containing the composite material as recited in claim 1 , wherein the article of manufacture is one of an electronic circuit board, a connector, or a plastic enclosure panel.

Assignees

• IBM

Inventors

• Boday Dylan J
• Kuczynski Joseph
• Wertz Jason T

Classifications

• C08L1/26

  Cellulose ethers · CPC title

• C08L1/04

  Oxycellulose; Hydrocellulose {, e.g. microcrystalline cellulose} · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• C08L1/00

  Compositions of cellulose, modified cellulose or cellulose derivatives · CPC title

• C08B11/187

  with olefinic unsaturated groups · CPC title