Low temperature vapor phase digestion of graphite

Patent metadata

Field	Value
Publication number	US-9623371-B1
Application number	US-201514867644-A
Country	US
Kind code	B1
Filing date	Sep 28, 2015
Priority date	Sep 28, 2015
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A method for digestion and gasification of graphite for removal from an underlying surface is described. The method can be utilized to remove graphite remnants of a formation process from the formed metal piece in a cleaning process. The method can be particularly beneficial in cleaning castings formed with graphite molding materials. The method can utilize vaporous nitric acid (HNO 3 ) or vaporous HNO 3 with air/oxygen to digest the graphite at conditions that can avoid damage to the underlying surface.

First claim

What is claimed is:

1. A method for digestion of graphite comprising feeding a gaseous stream to contact a structure, the structure comprising graphite on a surface of the structure, the gaseous stream comprising vaporous nitric acid, the nitric acid of the gaseous stream contacting the graphite, wherein upon the contact, reaction between the graphite and the nitric acid and/or between the graphite and one or more decomposition products of the nitric acid takes place resulting in digestion and gasification of the graphite and removal of essentially all of the graphite from the surface.

2. The method of claim 1 , wherein the reaction takes place at a temperature of about 600° C. or less.

3. The method of claim 1 , wherein the reaction takes place at a temperature of from about 300° C. to about 500° C.

4. The method of claim 1 , wherein the gaseous stream comprises water vapor.

5. The method of claim 1 , wherein the gaseous stream includes the nitric acid in a concentration of about 16 moles per liter or less.

6. The method of claim 1 , wherein one or more additional streams containing vaporous nitric acid are fed to contact the structure at different time points during the reaction.

7. The method of claim 1 , wherein an off-gas stream from the reaction is recycled and combined with the gaseous stream.

8. The method of claim 1 , wherein the method is carried out in a batch-wise, semi-batch, or continuous flow process.

9. The method of claim 1 , wherein the gaseous stream is fed such that the nitric acid contacts the graphite at a concentration of from about 3 grams of nitric acid to about 15 grams of nitric acid per gram of graphite.

10. The method of claim 1 , further comprising contacting the graphite with oxygen.

11. The method of claim 10 , wherein air or oxygen is fed to contact the graphite in conjunction with the gaseous stream.

12. The method of claim 1 , wherein the surface comprises a metal.

13. The method of claim 12 , wherein the metal comprises aluminum, tin, lead, steel, nickel, cobalt, an iron-based superalloy, a stainless steel alloy, a titanium alloy, or a titanium aluminide alloy.

14. The method of claim 1 , wherein the structure is a cast metal piece.

15. The method of claim 14 , the cast metal piece having been formed in a graphite mold or a mold comprising a graphite face.

16. The method of claim 1 , wherein the structure comprises a metal wire.

17. The method of claim 16 , wherein the structure is a wire coil.

18. The method of claim 1 , further comprising scrubbing a stream comprising the off-gas products of the reaction.

19. The method of claim 1 , further comprising capturing carbon dioxide formed in the reaction.

Assignees

• Savannah River Nuclear Solutions Llc

Inventors

• Pierce Robert A

Classifications

• B01D53/04

  with stationary adsorbents {(B01D53/025 takes precedence)} · CPC title

• B01D2255/20761

  Copper · CPC title

• B01D2253/102

  Carbon · CPC title

• G21C19/38

  Chemical means only · CPC title

• B01D2255/2073

  Manganese · CPC title