Solid oxide fuel cell with reinforced electrolyte membrane

Patent metadata

Field	Value
Publication number	US-9620803-B2
Application number	US-201514645373-A
Country	US
Kind code	B2
Filing date	Mar 11, 2015
Priority date	Sep 25, 2008
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A solid oxide fuel cell has a reinforced membrane-electrode assembly. The solid oxide fuel cell includes a first electrode layer, a second electrode layer, and an electrolyte membrane disposed between the first and second electrode layers. The solid oxide fuel cell further includes a gas-permeable structure adjacent to one or both of the electrode layers, for mechanical stabilization.

First claim

What is claimed is:

1. A method comprising:
depositing an electrolyte membrane onto a surface of a support substrate;
depositing a first electrode layer over the electrolyte membrane;
bonding an upper substrate over the electrolyte membrane and the first electrode layer on the support substrate, the upper substrate having etched therein a set of flow channels and a supply pathway;
injecting a gel through the supply pathway and into the flow channels of the upper substrate; and
providing reinforcing support for the electrolyte membrane by drying the gel so that the dried gel forms a gas-permeable structure that supports the electrolyte membrane.

2. The method of claim 1 , wherein the electrolyte membrane is a solid oxide electrolyte membrane.

3. The method of claim 1 , further comprising the act of etching the set of flow channels and the supply pathway in the upper substrate.

4. The method of claim 1 , further comprising:
removing material from a backside of the support substrate opposite said surface so as to etch a set of backside flow channels in the support substrate.

5. The method of claim 4 , further comprising:
removing material from the backside of the support substrate so as to release the electrolyte membrane.

6. The method of claim 5 , wherein the electrolyte membrane is a solid oxide electrolyte membrane, and further comprising the act of:
depositing a back electrode layer onto said backside of the support substrate so that the electrolyte membrane is disposed between said first electrode layer and the back electrode layer, thereby generating a solid oxide fuel cell.

7. The method of claim 4 , further comprising injecting a second gel into the backside flow channels of the support substrate.

8. The method of claim 7 , further comprising drying the second gel so as to provide additional strength to the electrolyte membrane.

9. The method of claim 7 , further comprising drying the second gel so as to prevent the electrolyte membrane from delaminating from the gel injected into the flow channels of the upper substrate.

10. The method of claim 1 , wherein the upper substrate has further etched therein a return pathway, and further comprising the act of etching the flow channels and the supply and return pathways in the upper substrate.

11. The method of claim 8 , further comprising:
establishing supply and return pathways in a third substrate; and
bonding the third substrate to the support substrate.

12. The method of claim 11 , further comprising:
injecting a third gel through the supply pathway into the flow channels of the third substrate.

13. The method of claim 12 , further including the act of drying the third gel.

14. The method of claim 1 , wherein the act of injecting the gel comprises injecting the gel so as to fill the flow channels of the upper substrate, and wherein the gas-permeable structure fills said flow channels.

15. The method of claim 1 , wherein the gas-permeable structure is rigid.

16. The method of claim 1 , wherein the gas-permeable structure is porous so as to allow gas flow through the electrolyte membrane.

17. The method of claim 1 , wherein the gel comprises at least one of:
carbon aerosol; and a conductive material.

18. The method of claim 1 , wherein the support substrate and the upper substrate comprise at least one of:
silicon; a semiconductor other than silicon; a metal; and glass.

19. The method of claim 1 , wherein the electrolyte membrane comprises at least one of:
yttria-doped zirconia; yttria-doped ceria; yttria-dope hafnia; bismuth oxide; lanthanum gallate; ceria; and Y-doped barium cerate.

20. A method comprising:
providing reinforcing support for a solid oxide electrolyte membrane in a solid oxide fuel cell, comprising the acts of:
depositing the solid oxide electrolyte membrane onto a support substrate;
depositing an electrode layer over the solid oxide electrolyte membrane;
bonding an upper substrate over the electrolyte membrane and the electrode layer on the support substrate, wherein the upper substrate includes a set of flow channels, a supply pathway, and a return pathway etched therein;
injecting a gel through the supply pathways and into the flow channels of the upper substrate; and
drying the gel to form a gas-permeable structure that fills the flow channels so as to mechanically stabilize the electrolyte membrane before the electrolyte membrane is released.

Assignees

• Ramanathan Shriram
• Johnson Alexander C
• Harvard College

Inventors

• Ramanathan Shriram
• Johnson Alexander C

Classifications

• H01M8/124 Primary

  characterised by the process of manufacturing or by the material of the electrolyte · CPC title

• Y02P70/56

  Cross-Sectional Technologies · mapped topic

• H01M8/126

  the electrolyte containing cerium oxide · CPC title

• Y02E60/525

  Cross-Sectional Technologies · mapped topic

• H01M8/1253

  the electrolyte containing zirconium oxide · CPC title