Power storage device, electrode thereof, and method for manufacturing power storage device

Patent metadata

Field	Value
Publication number	US-9620769-B2
Application number	US-201213491647-A
Country	US
Kind code	B2
Filing date	Jun 8, 2012
Priority date	Jun 24, 2011
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

To provide a power storage device having excellent charge/discharge cycle characteristics and a high charge/discharge capacity. The following electrode is used as an electrode of a power storage device: an electrode including a current collector and an active material layer provided over the current collector. The active material layer includes a plurality of whisker-like active material bodies. Each of the plurality of whisker-like active material bodies includes at least a core and an outer shell provided to cover the core. The outer shell is amorphous, and a portion between the current collector and the core of the active material bodies is amorphous. Note that a metal layer may be provided instead of the current collector, the active material bodies do not necessarily have to include the core, and a mixed layer may be provided between the current collector and the active material layer.

First claim

What is claimed is:

1. An electrode of a power storage device, comprising:
a current collector; and
an active material layer including a first region and a second region over the current collector,
wherein the first region covers an entire surface of the current collector,
wherein the second region includes a plurality of whisker-like active material bodies, the plurality of whisker-like active material bodies being amorphous and extended from the first region,
wherein at least one of the plurality of whisker-like active material bodies includes at least a core and an outer shell covering the core,
wherein the outer shell is amorphous,
wherein the core is in contact with the current collector through the first region, and
wherein an interface between the first region and the second region is a surface which is parallel to the surface of the current collector and overlaps with a bottom of a deepest valley of valleys between the plurality of whisker-like active material bodies.

2. The electrode of a power storage device, according to claim 1 ,
wherein a material of the active material layer is silicon.

3. The electrode of a power storage device, according to claim 1 ,
wherein the current collector is a metal layer over a substrate.

4. The electrode of a power storage device, according to claim 1 ,
wherein a material of the current collector is titanium.

5. The electrode of a power storage device, according to claim 1 ,
wherein each of the plurality of whisker-like active material bodies partly includes crystalline silicon.

6. The electrode of a power storage device, according to claim 1 ,
wherein 90% or more in volume of each of the plurality of whisker-like active material bodies is amorphous.

7. A power storage device comprising the electrode, according to claim 1 .

8. An electrode of a power storage device, comprising:
a current collector; and
an active material layer including a first region and a second region over the current collector,
wherein the first region covers an entire surface of the current collector,
wherein the second region includes a plurality of whisker-like active material bodies, the plurality of whisker-like active material bodies being extended from the first region,
wherein each of the plurality of whisker-like active material bodies includes at least a core and an outer shell covering the core,
wherein the outer shell is amorphous,
wherein a portion of the first region is amorphous,
wherein the core is in contact with the current collector through the first region, and
wherein an interface between the first region and the second region is a surface which is parallel to the surface of the current collector and overlaps with a bottom of a deepest valley of valleys between the plurality of whisker-like active material bodies.

9. The electrode of a power storage device, according to claim 8 , wherein a width of a cross section of the core of each of the plurality of whisker-like active material bodies is greater than or equal to 50 nm and less than or equal to 10000 nm.

10. The electrode of a power storage device, according to claim 8 , wherein a material of the active material layer is silicon.

11. The electrode of a power storage device, according to claim 8 , wherein the current collector is a metal layer over a substrate.

12. The electrode of a power storage device, according to claim 8 , wherein a material of the current collector is titanium.

13. The electrode of a power storage device, according to claim 8 , wherein the core of each of the plurality of whisker-like active material bodies is crystalline silicon.

14. The electrode of a power storage device, according to claim 8 , wherein 90% or more in volume of each of the plurality of whisker-like active material bodies is amorphous.

15. A power storage device comprising the electrode, according to claim 8 .

16. An electrode of a power storage device, comprising:
a current collector;
an active material layer including a first region and a second region over the current collector, the active material layer including silicon; and
a silicide layer of the current collector being between the current collector and the first region,
wherein the silicide layer covers an entire surface of the current collector,
wherein the first region covers an entire surface of the silicide layer,
wherein the second region includes a plurality of whisker-like active material bodies, the plurality of whisker-like active material bodies being amorphous and extended from the first region,
wherein a thickness of the silicide layer is 50 nm or less,
wherein at least one of the plurality of whisker-like active material bodies includes at least a core and an outer shell covering the core,
wherein the outer shell is amorphous,
wherein the core is in contact with the current collector through the first region, and
wherein an interface between the first region and the second region is a surface which is parallel to the surface of the current collector and overlaps with a bottom of a deepest valley of valleys between the plurality of whisker-like active material bodies.

17. The electrode of a power storage device, according to claim 16 , wherein the current collector is a metal layer over a substrate.

18. The electrode of a power storage device, according to claim 16 , wherein a material of the current collector is titanium.

19. The electrode of a power storage device, according to claim 16 , wherein each of the plurality of whisker-like active material bodies partly includes crystalline silicon.

20. The electrode of a power storage device, according to claim 16 ,
wherein 90% or more in volume of each of the plurality of whisker-like active material bodies is amorphous.

21. A power storage device comprising the electrode, according to claim 16 .

Assignees

• Takeuchi Toshihiko
• Oguni Teppei
• Osada Takeshi
• Semiconductor Energy Lab

Inventors

• Takeuchi Toshihiko
• Oguni Teppei
• Osada Takeshi

Classifications

• Y02P70/54

  Cross-Sectional Technologies · mapped topic

• H01M4/0428 Primary

  Chemical vapour deposition · CPC title

• H01M4/134 Primary

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/661

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title

• H01M4/667

  in the form of layers, e.g. coatings · CPC title