Graphene-containing platelets and electronic devices, and method of exfoliating graphene

Patent metadata

Field	Value
Publication number	US-9620727-B2
Application number	US-201013203481-A
Country	US
Kind code	B2
Filing date	Feb 25, 2010
Priority date	Feb 26, 2009
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

This document describes graphene-containing platelets and methods of exfoliating graphene from a surface. The method comprises facilitating exfoliation by treatment with proteins. In an embodiment, the proteins adhere to the surface of graphene and then the produced platelets may contain a graphene layer and a protein layer on the surface of the graphene layer. Electronic devices containing such platelets are also described.

First claim

The invention claimed is:

1. A method of producing graphene-containing platelets by exfoliating a graphene layer from a surface, the method comprising facilitating exfoliation by adhering proteins to the surface and applying a force to the proteins such that the proteins deliver the force to the surface, thereby separating the graphene layer from the surface.

2. The method of claim 1 , wherein the proteins include amphiphilic proteins.

3. The method of claim 1 , wherein the proteins include hydrophobins.

4. The method of claim 1 , wherein the proteins include fusion proteins comprising at least two functional parts such that at least one of the functional parts is formed by a hydrophobin.

5. The method of claim 3 , wherein the hydrophobins are class II hydrophobins.

6. The method of claim 3 , wherein the hydrophobins are from Trichoderma reesei.

7. The method of claim 3 , wherein the proteins include at least one of:
an HFBI and a fusion protein NCysHFBI.

8. The method of claim 1 , wherein the proteins form a layer on the surface.

9. The method of claim 1 , wherein said treatment comprises immersing the surface in a solution containing the proteins.

10. The method of claim 1 , wherein said treatment comprises:
forming a layer of said proteins,
touching the formed layer of proteins with the surface in order to adhere the layer of proteins on the surface, and
pressing the layer of proteins on the surface against a substrate in order to stamp the graphene on the substrate.

11. The method of claim 1 , comprising exposing the surface to ultrasonic waves in order to facilitate exfoliation.

12. The method of claim 1 , wherein the surface is a surface of a highly oriented graphite body.

13. The method of claim 1 , wherein the surface contains patterned features in order to produce platelets with predetermined shape.

14. The method of claim 1 , wherein the proteins include a plurality of proteins each having a hydrophobic part that is capable of adhering to graphene.

15. The method of claim 1 , wherein the proteins include a plurality of proteins capable of adhering to each other in order to form a network of proteins.

16. A method of producing graphene-containing platelets by exfoliating a graphene layer from a surface, the method comprising facilitating exfoliation by adhering proteins to the surface and applying a force to the proteins such that the proteins deliver the force to the surface, thereby separating the graphene layer from the surface, said proteins including hydrophobins.

17. A method of producing graphene-containing platelets by exfoliating a graphene layer from a surface of a highly oriented graphite body, the method comprising facilitating exfoliation by adhering proteins to the surface and applying a force to the proteins such that the proteins deliver the force to the surface, thereby separating the graphene layer from the surface.

18. The method of claim 17 , wherein said proteins include hydrophobins.

19. The method of claim 18 , wherein the hydrophobins are class II hydrophobins.

20. The method of claim 18 , wherein the hydrophobins are from Trichoderma reesei.

21. The method of claim 17 , wherein the proteins form a layer on the surface of the graphene layer.

22. The method of claim 1 , wherein the exfoliation occurs at a temperature less than 100 ° C.

23. The method of claim 1 , wherein the force is induced by acoustic energy, mechanical energy, or a combination thereof.

Assignees

• Laaksonen Päivi
• Ahopelto Jouni
• Linder Markus
• Teknologian Tutkimuskeskus Vtt Oy

Inventors

• Laaksonen Päivi
• Ahopelto Jouni
• Linder Markus

Classifications

• C01B31/0484

  Chemistry & Metallurgy · mapped topic

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C01B2204/32

  Size or surface area · CPC title

• B82Y10/00 Primary

  Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic · CPC title

• Y10T428/31938

  Polymer of monoethylenically unsaturated hydrocarbon · CPC title