Porous structure provided with a pattern that is composed of conductive polymer and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-9617649-B2
Application number	US-201113637494-A
Country	US
Kind code	B2
Filing date	Mar 25, 2011
Priority date	Mar 26, 2010
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A porous structure ( 1 ) provided with a pattern that is composed of a conductive polymer, which comprises a porous body ( 2 ) and a pattern ( 3 ) that is composed of a conductive polymer and arranged on the porous body ( 2 ). The porous body ( 2 ) is preferably a gel, and a dopant may be added to the pattern ( 3 ) that is composed of a conductive polymer. If an agarose gel is used as the gel ( 2 ) and a PEDOT electrode ( 3 A) is used as the pattern ( 3 ) that is composed of a conductive polymer in the porous structure ( 1 ) which is provided with the pattern ( 3 ) that is composed of a conductive polymer, the porous structure ( 1 ) can be used as an electrode for cell stimulation. The porous structure ( 1 ) provided with the pattern ( 3 ) that is composed of a conductive polymer can be produced by an electropolymerization method.

First claim

What is claimed is:

1. An electrode, comprising:
a porous body made of gel; and
a pattern that is composed of conductive polymer provided only on the porous body, wherein the gel is composed of hydrogel, and
wherein the pattern that is composed of conductive polymer is contacted to cells or tissue.

2. The electrode according to claim 1 , wherein the hydrogel includes water at a water content percentage of 70 to 99%.

3. The electrode according to claim 1 , wherein the hydrogel is any of agarose gel, collagen, glucomannan, polyacrylamide, polyvinyl alcohol, polyhydroxyethyl methacrylate, or polyvinylpyrrolidone.

4. The electrode according to claim 1 , wherein the conductive polymer is any of PEDOT, polypyrrole, or polyacetylene.

5. The electrode according to claim 1 , wherein the conductive polymer is added with a dopant.

6. The electrode according to claim 1 , wherein the conductive polymer has a conductivity of 10 S/cm or more.

7. A method of manufacturing the electrode according to claim 1 , comprising:
a step of forming an electrode pattern functioning as a working electrode;
a step of inserting the working electrode pattern to electrolyte liquid including raw material of conductive polymer;
a step of placing a porous body on the working electrode pattern;
a step of performing electropolymerization for a predetermined time to deposit a pattern that is composed of conductive polymer between the porous body and the electrode pattern; and
a step of peeling the porous body from the electrode pattern to thereby obtain a porous structure provided with a pattern that is composed of conductive polymer.

8. The method of manufacturing the electrode according to claim 7 , wherein the raw material of conductive polymer is monomer of the conductive polymer.

9. The method of manufacturing the electrode according to claim 7 , wherein the electropolymerization is followed by at least one or more applications of negative and positive voltages to the working electrode in an alternate manner.

10. The method of manufacturing the electrode according to claim 7 , wherein the electrolyte liquid further includes a dopant.

11. The method of manufacturing the electrode according to claim 10 , wherein KNO 3 is used as the dopant.

12. The method of manufacturing the electrode according to claim 7 , wherein the pattern that is composed of conductive polymer has the minimum line width that is wider than the minimum line width of the electrode pattern functioning as a working electrode by 1 μm to 10 μm.

13. The method of manufacturing the electrode according to claim 7 , wherein the hydrogel is any of agarose gel, collagen, glucomannan, polyacrylamide, polyvinyl alcohol, polyhydroxyethyl methacrylate, or polyvinylpyrrolidone.

Assignees

• Nishizawa Matsuhiko
• Sekine Soichiro
• Ido Yuichiro
• Univ Tohoku

Inventors

• Nishizawa Matsuhiko
• Sekine Soichiro
• Ido Yuichiro

Classifications

• C09D5/4476

  comprising polymerisation in situ · CPC title

• H05K1/03

  Use of materials for the substrate · CPC title

• H05K1/0353

  consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement · CPC title

• A61N1/0496 Primary

  characterised by using specific chemical compositions, e.g. hydrogel compositions, adhesives · CPC title

• H05K1/0313

  Organic insulating material · CPC title