Complex polyester composition, lubricant composition, lubricant, and production method for complex polyester composition

Patent metadata

Field	Value
Publication number	US-9617492-B2
Application number	US-201615010731-A
Country	US
Kind code	B2
Filing date	Jan 29, 2016
Priority date	Jul 31, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

An object of the present invention is to provide a lubricant which has excellent lubrication performance and is able to exhibit excellent lubrication performance even when under extreme pressure conditions. The present invention relates to a complex polyester composition containing polyester obtained by condensing polyhydric alcohol having at least two hydroxyl groups, a dicarboxylic acid having 44 carbon atoms, and monohydric alcohol. Further, the present invention relates to a lubricant composition containing the complex polyester composition, and a lubricant and a production method for a complex polyester composition.

First claim

What is claimed is:

1. A complex polyester composition containing polyester obtained by condensing
polyhydric alcohol having at least two hydroxyl groups,
a dicarboxylic acid having 44 carbon atoms, and
monohydric alcohol.

2. The complex polyester composition according to claim 1 , wherein the dicarboxylic acid having 44 carbon atoms is an erucic acid dimer.

3. The complex polyester composition according to claim 1 , wherein the polyhydric alcohol has three or more hydroxyl groups.

4. The complex polyester composition according to claim 1 , wherein the polyhydric alcohol is selected from pentaerythritol, trimethylol propane, glycerin, and dipentaerythritol.

5. The complex polyester composition according to claim 1 , wherein the monohydric alcohol is denoted by General Formula (1) described below, and
R a O(CX a1 X a2 ) na1 na2 OH  General Formula (1)

in General Formula (1), R a represents an alkyl group which may have a substituent group, a cycloalkyl group which may have a substituent group, an alkenyl group which may have a substituent group, an aryl group which may have a substituent group, or a heteroaryl group which may have a substituent group, X a1 and X a2 each independently represent a hydrogen atom, a halogen atom, or an alkyl group, nal represents an integer of 2 to 4, and na2 represents an integer of 1 to 12.

6. The complex polyester composition according to claim 1 , wherein the complex polyester composition contains polyester obtained by further condensing a dimer acid in addition to the polyhydric alcohol, the dicarboxylic acid having 44 carbon atoms, and the monohydric alcohol.

7. The complex polyester composition according to claim 1 , wherein the complex polyester composition contains polyester obtained by further condensing a trimer acid in addition to the polyhydric alcohol, the dicarboxylic acid having 44 carbon atoms, and the monohydric alcohol.

8. The complex polyester composition according to claim 1 , wherein at least one type of polyester is denoted by General Formula (2) described below, and
R OCOR 1 COOR 2 ) n   General Formula (2)

in General Formula (2), R represents a n-valent atomic group, R 1 represents a residue of a dicarboxylic acid having 44carbon atoms, R 2 represents an alkyl group which may have a substituent group, a cycloalkyl group which may have a substituent group, an alkenyl group which may have a substituent group, an aryl group which may have a substituent group, or a heteroaryl group which may have a substituent group, and n represents an integer of 2 to 6.

9. The complex polyester composition according to claim 8 , wherein in General Formula (2) described above, n represents an integer of 3 to 6.

10. The complex polyester composition according to claim 8 , wherein in General Formula (2) described above, R represents an atomic group formed of saturated aliphatic hydrocarbon which may have a substituent group.

11. The complex polyester composition according to claim 8 , wherein in General Formula (2) described above, the number of carbon atoms of R 2 is greater than or equal to 4.

12. The complex polyester composition according to claim 8 , wherein in General Formula (2) described above, R 2 represents a group having an oxyalkylene structure.

13. The complex polyester composition according to claim 1 , wherein viscosity at 40° C. is 50 mPa·s to 1650 mPa·s.

14. A lubricant composition containing the complex polyester composition according to claim 1 , and at least one type of additive selected from an abrasion preventing agent, a viscosity index improver, an antioxidant, a cleaning agent, a dispersant, a fluidizing agent, a curing agent, a corrosion preventing agent, a seal compatible agent, a defoaming agent, a rust preventing agent, a friction adjuster, and a thickener.

15. A lubricant composition containing at least the complex polyester composition according to claim 1 , and at least one type of medium selected from mineral oil, a fatty oil compound, polyolefin oil, silicone oil, perfluoropolyether oil, diphenyl ether oil, aromatic ester oil, aliphatic monoester oil, aliphatic diester oil, and polyol ester lubricating oil.

16. A lubricant containing the complex polyester composition according to claim 1 .

17. The lubricant according to claim 16 , wherein the lubricant is used as lubricating oil for grease, a releasing agent, engine oil for an internal combustion engine, oil for metal working (machining), oil for a bearing, fuel for a combustion engine, vehicle engine oil, gear oil, operating oil for an automobile, lubricating oil for a vessel and an aircraft, machine oil, turbine oil, hydraulic operating oil, compressor and vacuum pump oil, freezer oil, lubricating oil for metal working, a lubricant for magnetic recording medium, a lubricant for a micro machine, a lubricant for an artificial bone, shock absorber oil, or rolling oil.

18. A production method for a complex polyester composition, comprising:
obtaining a mixture by mixing polyhydric alcohol having at least two hydroxyl groups, a dicarboxylic acid having 44 carbon atoms, and monohydric alcohol; and
performing dehydration condensation with respect to the mixture.

19. The production method for a complex polyester composition according to claim 18 , wherein the afore-mentioned obtaining the mixture is mixing the polyhydric alcohol, the dicarboxylic acid having 44 carbon atoms, and the monohydric alcohol such that an equivalence ratio of mixing the dicarboxylic acid having 44 carbon atoms with respect to the polyhydric alcohol is 1 to 3, and an equivalence ratio of mixing the monohydric alcohol with respect to the polyhydric alcohol is 0.5 to 3.

20. The production method for a complex polyester composition according to claim 18 , wherein the afore-mentioned performing the dehydration condensation includes adding a hydrocarbon-based solvent having a boiling point of 110° C. to 160° C. in the amount of 1 mass % to 25 mass % with respect to the mixture, and of performing the dehydration condensation while setting water in an azeotropic state.

21. The production method for a complex polyester composition according to claim 18 , wherein the afore-mentioned performing the dehydration condensation is performing condensation in the absence of a solvent.

22. The complex polyester composition according to claim 1 , wherein said dicarboxylic acid having 44 carbon atoms is used as a sole dicarboxylic acid for condensation to produce the polyester.

Assignees

• Fujifilm Corp

Inventors

• Suzuki Hiroyuki
• Terada Yuji

Classifications

• C10N2040/02

  Bearings · CPC title

• C10N2050/14

  Composite materials or sliding materials in which lubricants are integrally molded · CPC title

• C10N2050/10

  semi-solid; greasy · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2040/24

  without essential removal of material {, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding}; Punching metal · CPC title