Bi- and tri- layer interfacial layers in perovskite material devices

Patent metadata

Field	Value
Publication number	US-9617431-B2
Application number	US-201514949080-A
Country	US
Kind code	B2
Filing date	Nov 23, 2015
Priority date	Nov 26, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

Photovoltaic devices such as solar cells, hybrid solar cell-batteries, and other such devices may include an active layer disposed between two electrodes. The active layer may have perovskite material and other material such as mesoporous material, interfacial layers, thin-coat interfacial layers, and combinations thereof. The perovskite material may be photoactive. The perovskite material may be disposed between two or more other materials in the photovoltaic device. Inclusion of these materials in various arrangements within an active layer of a photovoltaic device may improve device performance. Other materials may be included to further improve device performance, such as, for example: additional perovskites, and additional interfacial layers.

First claim

What is claimed is:

1. A method comprising the steps of:
preparing a lead halide precursor ink, wherein preparing a lead halide precursor ink comprises the steps of:
introducing a lead halide into a vessel;
introducing a first solvent into the vessel;
contacting the lead halide with the first solvent to dissolve the lead halide; and
introducing an additive comprising an amino acid or an amino acid hydrohalide into the vessel;

depositing the lead halide precursor ink onto a substrate;
drying the lead halide precursor ink to form a thin film; and
depositing a second solvent and a salt onto the thin film.

2. The method of claim 1 , wherein the lead halide is selected from the group consisting of lead (II) iodide, lead (II) bromide, lead (II) chloride, lead (II) fluoride, and combinations thereof.

3. The method of claim 1 , wherein lead halide comprises a mixture of lead (II) chloride and lead (II) iodide mixed in a ratio of 10 mol of lead (II) chloride to 90 mol of lead (II) iodide.

4. The method of claim 1 , wherein contacting the lead halide with the first solvent to dissolve the lead halide occurs between about 20° C. to about 150° C.

5. The method of claim 1 , further comprising heating the thin film and salt to between about 20° C. to about 300° C.

6. The method of claim 1 , wherein the lead halide precursor ink has a concentration of the lead halide between about 0.1 M and about 5 M.

7. The method of claim 1 , further comprising annealing the thin film, wherein annealing the thin film occurs for up to 24 hours at a temperature between about 20° C. to about 300° C.

8. The method of claim 1 , wherein the lead halide precursor ink is deposited in an atmosphere having greater than or equal to 0 grams H 2 O per m3 air and less than or equal to 20 grams H 2 O per m3 air.

9. The method of claim 1 , wherein the salt is selected from the group consisting of methylammonium iodide, formamidinium iodide, guanidinium iodide, 1,2,2-triaminovinylammonium iodide, and 5-aminovaleric acid hydroiodide.

10. The method of claim 1 , wherein the salt is dissolved in the second solvent in a concentration of between about 0.1 M and about 5 M.

11. The method of claim 1 , wherein the salt comprises formamidinium iodide.

12. The method of claim 1 , wherein the amino acid is selected from the group consisting of glycine, cysteine, proline, glutamic acid, arginine, serine, histindine, 5-ammoniumvaleric acid, including alpha, beta, gamma, and greater derivatives thereof, and combinations thereof.

13. The method of claim 1 , wherein the amino acid hydrohalide is selected from the group consisting of hydrohalides of glycine, cysteine, proline, glutamic acid, arginine, serine, histindine, 5-ammoniumvaleric acid, including alpha, beta, gamma, and greater derivatives thereof, and combinations thereof.

14. The method of claim 1 , wherein the additive further comprises formamidinium halide.

15. The method of claim 1 , wherein the additive further comprises formamidinium chloride.

16. The method of claim 1 , wherein the amino acid hydrohalide comprises 5-amino valeric acid hydrochloride.

17. The method of claim 1 , wherein the lead halide ink has a concentration of the additive between about 1 μM to about 1 mM.

18. The method of claim 1 , wherein:
the amino acid hydrohalide comprises 5-amino valeric acid hydrochloride;
the additive further comprises formamidinium halide; and
the lead halide ink has a concentration of the additive between about 1 μM to about 1 mM.

Assignees

• Hunt Energy Entpr Llc

Inventors

• Irwin Michael D
• Chute Jerred A
• Dhas Vivek V

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H01G9/204

  comprising zinc oxides, e.g. ZnO (H01G9/2036 takes precedence) · CPC title

• C09D11/02

  Printing inks (C09D11/30 takes precedence) · CPC title

• C09D7/001

  Chemistry & Metallurgy · mapped topic

• H01G9/2036

  comprising mixed oxides, e.g. ZnO covered TiO2 particles · CPC title