Polycarbonate blend and method of producing the same

Patent metadata

Field	Value
Publication number	US-9617415-B2
Application number	US-201314387880-A
Country	US
Kind code	B2
Filing date	Mar 5, 2013
Priority date	Apr 10, 2012
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A blend comprising from 50 to 95 percent by weight polycarbonate; and from 5 to 50 percent by weight modified methyl methacrylate polymer, wherein the modified methyl methacrylate polymer is selected from the group consisting of modified methyl methacrylate homopolymer, modified methyl methacrylate copolymers, and combinations thereof; wherein the modified methyl methacrylate polymer has one or more end groups provided by reaction with one or more chain transfer agents selected from the group consisting of mercapto esters, cycloalkyl and substituted cycloalkyl thiols, hydroxyl thiols, aryl and substituted aryl thiols, and aminoalkyl thiols, wherein the modified methyl methacrylate polymer has a Mw from 5,000 to 100,000 g/mole; and wherein the blend exhibits a pencil hardness equal to or greater than F measured according to ASTM D3363-05 is provided. A method for preparing a polycarbonate/modified methyl methacrylate blend is also provided.

First claim

We claim:

1. A blend consisting essentially of:
from 50 to 95 percent by weight polycarbonate; and
from 5 to 50 percent by weight modified methyl methacrylate polymer,
wherein the modified methyl methacrylate polymer is prepared by solution polymerization, and wherein the modified methyl methacrylate polymer is selected from the group consisting of (a) modified methyl methacrylate homopolymers, (b) modified methyl methacrylate copolymers consisting essentially of from 77.7 to 78.4 percent by weight units derived from methyl methacrylate, from 2 to 2.9 percent by weight of butyl mercaptopropionate, and from 19.4 to 19.6 percent by weight of cyclohexyl methacrylate, and (c) combinations thereof;
wherein the modified methyl methacrylate polymer has one or more mercapto ester end groups provided by reaction with the butyl mercaptopropionate chain transfer agent, and aminoalkyl thiols; and
wherein the modified methyl methacrylate polymer has an Mw from 9,300 to 13,200 g/mole; and
wherein the blend exhibits a pencil hardness equal to or greater than F measured according to ASTM D3363-05, and wherein the blend has a haze of equal to or less than 5%, measured according to ASTM D1003.

2. The blend according to claim 1 , wherein the modified methyl methacrylate polymer has a refractive index less than 1.52.

3. A method for improving the scratch resistance of polycarbonate comprising:
forming a blend by melt blending, the blend consisting essentially of from 50 to 95 weight percent polycarbonate and from 5 to 50 weight percent modified methyl methacrylate polymer;
wherein the modified methyl methacrylate polymer is prepared by solution polymerization, and wherein the modified methyl methacrylate polymer is (a) a modified methyl methacrylate homopolymer, (b) a modified methyl methacrylate copolymer consisting essentially of from 77.7 to 78.4 percent by weight units derived from methyl methacrylate, from 2 to 2.9 percent by weight of butyl mercaptopropionate, and from 19.4 to 19.6 percent by weight of cyclohexyl methacrylate, or (c) combination thereof, having one or more end groups provided by reaction with one or more chain transfer agents selected from the group consisting of mercapto esters, cycloalkyl and substituted cycloalkyl thiols, hydroxyl thiols, aryl and substituted aryl thiols, and aminoalkyl thiols; and
wherein the modified methyl methacrylate polymer has a Mw equal from 9,300 to 13,200 g/mole; and
wherein the blend exhibits a pencil hardness equal to or greater than F measured according to ASTM D3363-05, and wherein the blend has a haze of equal to or less than 5%, measured according to ASTM D1003.

4. The method according to claim 3 , wherein the blend has a refractive index of less than 1.52.

Assignees

• Rohm & Haas
• Rohm & Haas

Inventors

• Nelliappan Veera G
• Lundquist Eric G
• Saint-Gerard Yannick

Classifications

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08F2220/1841

  Chemistry & Metallurgy · mapped topic