Low shear process for polycarbonate purification

Patent metadata

Field	Value
Publication number	US-9617381-B2
Application number	US-201414907349-A
Country	US
Kind code	B2
Filing date	Jul 25, 2014
Priority date	Jul 25, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

In another embodiment, a process of purifying an interfacially polymerized polycarbonate from a feed comprising an aqueous phase and an organic phase comprising an organic solvent, the interfacially polymerized polycarbonate, a catalyst, and ions, can comprise: separating the aqueous phase and the organic phase from the feed, wherein during the separating the feed is subjected to at least one of: energy of less than or equal to 0.5 kJ/kg of feed, a shear rate of less than 150,000 S −1 , and centrifugal forces of 100 to 2,000 g-force; to form a purified aqueous phase and a purified organic phase comprising a purified polycarbonate.

First claim

We claim:

1. A process of purifying a polycarbonate from a feed comprising an interfacial polymerization product mixture, wherein the product mixture comprises an aqueous phase and an organic phase comprising an organic solvent, the polycarbonate, a catalyst, and ions, the process comprising:
separating the aqueous phase and the organic phase while subjecting the product mixture to a shear rate of less than 150,000 S −1 to form a separated organic phase and a separated aqueous phase;
extracting the catalyst from the separated organic phase with an acid stream while subjecting the separated organic phase and the acid stream to a shear rate of less than 150,000 S −1 ; and
extracting the ions from the separated organic phase with a water stream while subjecting the separated organic phase and the water stream to a shear rate of less than 150,000 S −1 ;
to form a purified organic phase comprising a purified polycarbonate.

2. A process of making a purified polycarbonate, comprising:
interfacially polymerizing a polycarbonate to form a product mixture; wherein the product mixture comprises an aqueous phase and an organic phase comprising an organic solvent, the polycarbonate, a catalyst, and ions;
separating the aqueous phase and the organic phase while subjecting the product mixture to a shear rate of less than 150,000 S −1 to form a separated organic phase and a separated aqueous phase;
extracting the catalyst from the separated organic phase with an acid stream while subjecting the separated organic phase and the acid stream to a shear rate of less than 150,000 S −1 ; and
extracting the ions from the separated organic phase with a water stream while subjecting the separated organic phase and the water stream to a shear rate of less than 150,000 S −1 ;
forming a purified organic phase comprising the purified polycarbonate.

3. The process of claim 1 , wherein one or more of the separating, the extracting of the catalyst, and the extracting of the ions, is at a shear rate of 0.5 to less than 100,000 S −1 .

4. A process of purifying an interfacially polymerized polycarbonate from a feed comprising an aqueous phase and an organic phase comprising an organic solvent, the interfacially polymerized polycarbonate, a catalyst, and ions, the process comprising:
separating the aqueous phase and the organic phase from the feed, wherein during the separating the feed is subjected to at least one of:
energy of less than or equal to 0.5 kJ/kg of feed,
a shear rate of less than 150,000 S −1 , and
centrifugal forces of 100 to 2,000 g-force,
to form a purified aqueous phase and a purified organic phase comprising a purified polycarbonate.

5. The process of claim 4 , further comprising
interfacially polymerizing the interfacially polymerized polycarbonate.

6. The process of claim 4 , wherein the feed comprises an organic wash stream and wherein the process further comprises extracting the organic wash stream with an extracting aqueous stream prior to the separating.

7. The process of claim 4 , wherein the feed is subjected to the energy of 0.001 to 0.5 kJ/kg of feed.

8. The process of claim 4 , wherein the feed is subjected to the shear rate of 0.5 to less than 100,000 S −1 .

9. The process of claim 1 , wherein the separating is at a shear rate of 0.5 to less than 100,000 S −1 .

10. The process of claim 1 , further comprising increasing a size of an aqueous droplet in the organic phase in a low shear rate coalescer to form a coalesced mixture.

11. The process of claim 1 , wherein the separated aqueous stream comprises less than or equal to 10 vol % of the organic phase.

12. The process of claim 1 , wherein the separated organic phase has a viscosity of less than or equal to 100 centipoise.

13. The process of claim 1 , wherein the separating comprises separating with a low shear centrifuge, wherein the low shear centrifuge is free of a rotating disc and a rotating screw, wherein the process further comprises introducing the feed to an annular mixing zone in the low shear centrifuge.

14. The process of claim 1 , further comprising determining that the product mixture emulsifies at shear rate of greater than or equal to 150,000 S −1 prior to the separating.

15. The process of claim 1 , further comprising determining that one or both of the separated aqueous phase and the separated organic phase emulsifies at shear rate greater than or equal to 150,000 S −1 .

16. The process of claim 2 , wherein one or more of the separating, the extracting of the catalyst, and the extracting of the ions, is at a shear rate of 0.5 to less than 100,000 S −1 .

17. The process of claim 4 , further comprising increasing a size of an aqueous droplet in the organic phase in a low shear rate coalescer to form a coalesced mixture.

18. The process of claim 4 , wherein the separated aqueous stream comprises less than or equal to 10 vol % of the organic phase.

19. The process of claim 4 , wherein the separated organic phase has a viscosity of less than or equal to 100 centipoise.

20. The process of claim 4 , further comprising determining that the product mixture emulsifies at shear rate of greater than or equal to 150,000 S −1 prior to the separating.

Assignees

• Sabic Global Technologies Bv

Inventors

• Gautam Pankaj Singh
• Kuzeljevic Zeljko
• Hollar Jr William E
• Khadilkar Mohan

Classifications

• C08G64/24

  and phenols · CPC title

• C08G64/406 Primary

  Purifying; Drying · CPC title