Method of fabricating a liquid crystal polymer film

Patent metadata

Field	Value
Publication number	US-9617205-B2
Application number	US-201514810589-A
Country	US
Kind code	B2
Filing date	Jul 28, 2015
Priority date	Mar 11, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A method of fabricating a liquid crystal polymer film includes providing a support substrate having a surface having a shape arranged to define a form of a liquid crystal polymer film to be fabricated; applying a layer of a photoaligning material over the surface of the support substrate, the photoaligning material having an absorption band; exposing the layer of photoaligning material to a light having a linear polarization and the light comprising a wavelength within the absorption band to convert the layer of photoaligning material into a layer of photoaligned material; applying a layer of a polymerizable liquid crystal over the layer of photoaligned material; performing photopolymerization of the layer of polymerizable liquid crystal to form a liquid crystal polymer film; applying a solvent to the layer of photoaligned material, the solvent formulated to dissolve the photoaligned material to thereby release the liquid crystal polymer film from the support substrate; and removing the liquid crystal polymer film from the support substrate.

First claim

The invention claimed is:

1. A method of fabricating a liquid crystal polymer film, the method comprising:
(a) providing a support substrate having a surface having a shape arranged to define a form of a liquid crystal polymer film to be fabricated;
(b) applying a layer of a photoaligning material consisting of an azobenzene, a stilbene, an azoxy, an azomethine, a fulgide or a diarylethene photoresponsive compound in combination with a coating solvent over said surface of said support substrate, said photoaligning material having an absorption band;
(c) exposing said layer of photoaligning material to a light having a linear polarization and said light comprising a wavelength within said absorption band to convert said layer of photoaligning material into a layer of photoaligned material adapted for aligning molecules of a liquid crystal polymer layer in a predetermined direction;
(d) applying a layer of a polymerizable liquid crystal over said layer of photoaligned material;
(e) performing photopolymerization of said layer of polymerizable liquid crystal to form a liquid crystal polymer film of about 1 μm (micrometer) in thickness;
(f) applying a dissolution solvent to said layer of photoaligned material, said dissolution solvent formulated to dissolve said photoaligned material to thereby release said liquid crystal polymer film from said support substrate; and
(g) removing said liquid crystal polymer film from said support substrate, said liquid crystal polymer film having a thickness of about 1 μm.

2. A method as claimed in claim 1 , wherein said photoresponsive compound has a molecular structure comprising at least one functional group for solubility in a polar solvent.

3. A method as claimed in claim 2 , wherein said at least one functional group is a sulfo group.

4. A method as claimed in claim 1 , wherein the method comprises, before exposing said layer of photoaligning material to said light, spatially modulating said linear polarization of said light.

5. A method as claimed in claim 4 , wherein said linear polarization of said light is spatially modulated with one of a one-dimensional polarization pattern and a two-dimensional polarization pattern.

6. A method as claimed in claim 4 , wherein said linear polarization of said light is spatially modulated by transmitting said light through one of a cycloidal diffractive waveplate, a vector vortex waveplate, and an array of vector vortex waveplates.

7. A method as claimed in claim 1 , wherein said dissolution solvent is a polar solvent.

8. A method as claimed in claim 1 , wherein said dissolution solvent is one of water, Dimethylformamide, and a low molecular weight alcohol.

9. A method as claimed in claim 1 , wherein after step (e) the method comprises attaching said liquid crystal polymer film to a carrier substrate, and where step (g) comprises removing said liquid crystal polymer film on said carrier substrate from said support substrate.

10. A method as claimed in claim 9 , wherein said liquid crystal polymer film is attached to said carrier substrate by applying a layer of an adhesive onto said liquid crystal polymer film and performing photopolymerization of said layer of said adhesive to form said carrier substrate.

11. A method as claimed in claim 9 , wherein said carrier substrate is a polymer film which is thicker and stronger than said liquid crystal polymer film.

12. A method as claimed in claim 9 , wherein said liquid crystal polymer film is attached to said carrier substrate by:
a. applying a layer of an adhesive onto said carrier substrate;
b. bringing said support substrate and said carrier substrate together to bring said adhesive into contact with said liquid crystal polymer film; and
c. curing said adhesive.

13. A method as claimed in claim 1 , wherein after step (e) the method comprises adhering the liquid crystal polymer film to a second support substrate and the method further comprises, after step (g):
d. providing a third support substrate carrying a second layer of a photoaligned material and having a second liquid crystal polymer film, different to the first liquid crystal polymer film, provided over said second layer of a photoaligned material; and
e. applying a second dissolution solvent to said second layer of a photoaligned material, said second dissolution solvent formulated to dissolve said photoaligned material to thereby release said second liquid crystal polymer film from said third support substrate.

14. A method as claimed in claim 13 , wherein said first liquid crystal polymer film has a first alignment pattern and said second liquid crystal polymer film has a second alignment pattern, said second alignment pattern being one of a different pattern to said first alignment pattern and a different orientation to said first alignment pattern.

15. A method as claimed in claim 1 , wherein said support substrate is a first mold segment and step (a) further comprises providing a second mold segment having a surface having a shape arranged to cooperate with said surface of said first mold segment, said surfaces of said first and second mold segments together defining a cavity defining said shape of said liquid crystal polymer film and wherein step (d) comprises arranging said first and second mold segments together to form said cavity and filling said cavity with said polymerizable liquid crystal.

16. A method as claimed in claim 15 , wherein step (b) further comprises applying a layer of said photoaligning material over said surface of said second mold segment and step (c) comprises exposing both said layers of photoaligning material to a light having a linear polarization and said light comprising a wavelength within said absorption band to convert each said layer of photoaligning material into a layer of photoaligned material.

17. A method as claimed in claim 15 , wherein step (b) further comprises applying a layer of said photoaligning material over said surface of said second mold segment and step (c) comprises exposing said layer of photoaligning material on said first mold segment to a first linearly polarized light having a first polarization spatial modulation and exposing said layer of photoaligning material on said second mold segment to a second linearly polarized light having a second polarization spatial modulation, different to said first polarization spatial modulation, each said linearly polarized light comprising a wavelength within said absorption band to convert each said layer of photoaligning material into a respective layer of photoaligned material.

18. A method as claimed in claim 1 , wherein said polymerizable liquid crystal comprises functional groups, copolymers and additives to control its optical, electro-optical, mechanical, thermodynamic, and chemical properties.

Assignees

• Us Army
• Beam Eng For Advanced Measurements Co

Inventors

• Tabirian Nelson V
• Nersisyan Sarik R
• Kimball Brian R
• Steeves Diane M
• Vergara Rafael O

Classifications

• C09B33/044

  the coupling component being a bis-phenol · CPC title

• C09K19/56

  Aligning agents · CPC title

• G02F1/133788

  by light irradiation, e.g. linearly polarised light photo-polymerisation · CPC title

• C09K2219/03

  in the form of films, e.g. films after polymerisation of LC precursor · CPC title

• C07C245/08 Primary

  with the two nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings, e.g. azobenzene · CPC title