Multilayer pipe for transporting water or gas

Patent metadata

Field	Value
Publication number	US-9616642-B2
Application number	US-44559806-A
Country	US
Kind code	B2
Filing date	Jun 2, 2006
Priority date	Jun 2, 2005
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

The invention relates to a multilayer pipe which comprises (in the following order, from the inside of the pipe outwards):
optionally, a layer C 1 of a fluoropolymer; a layer C 2 of a fluoropolymer onto which at least one unsaturated monomer has been radiation-grafted, optionally blended with a fluoropolymer; optionally, an adhesion tie layer C 3 , this layer C 3 being directly attached to the layer C 2 containing the radiation-grafted fluoropolymer; a layer C 4 of a polyolefin optionally blended with a functionalized polyolefin, directly attached to the optional layer C 3 or else to the layer C 2 ; optionally, a barrier layer C 5 ; and optionally, a layer C 6 of a polyolefin.

First claim

What is claimed is:

1. A coextruded multilayer pipe consisting (in the following order, from the inside of the pipe outwards):
a layer C 1 of a vinylidene fluoride homopolymer or copolymer having at least 75% by weight of vinylidene fluoride (VDF);
layer C 2 a radiation grafted vinylidene fluoride homopolymer or copolymer onto which maleic anhydride has been radiation-grafted by melt-blending said vinylidene fluoride homopolymer or copolymer and said maleic anhydride, forming granules of said blend, followed by irradiation grafting of said granules in the solid state—said grafting taking place when the polymer is not in the melt state, wherein said grafting occurs throughout the mass and not just on the surface of a powder, and wherein the level of grafting is from 0.9 to 5%;
an adhesion tie layer C 3 , this layer C 3 being directly attached to the layer C 2 containing the radiation-grafted fluoropolymer;
a layer C 4 selected from the group consisting of a polyethylene and a polyolefin blended with a functionalized polyolefin, directly attached to the layer C 3 ;
a polymer barrier layer C 5 to prevent diffusion of chemical compounds; and
a polyethylene layer C 6 .

2. The multilayer pipe according to claim 1 , in which the layers adhere to one another in their respective contact regions.

3. The multilayer pipe according to claim 1 , in which the fluoropolymer of the layer C 1 and/or of the layer C 2 is a polymer having, in its chain, at least one monomer chosen from compounds containing a vinyl group capable of opening, in order to be polymerized, and containing, directly attached to this vinyl group, at least one fluorine atom, one fluoroalkyl group or one fluoroalkoxy group.

4. The multilayer pipe according to claim 1 , in which the adhesion tie layer is a functionalized polyolefin optionally blended with a polyolefin.

5. The multilayer pipe according to claim 4 , in which the functionalized polyolefin possesses functional groups capable of reacting with the functional groups grafted onto the fluoropolymer.

6. The multilayer pipe according to claim 1 , in which the polyolefin layer C 4 is an cross-linked polyethylene (XPE).

7. The multilayer pipe according to claim 4 , in which the functionalized polyolefin possesses epoxide or hydroxy functional groups.

8. The multilayer pipe according to claim 4 , in which the functionalized polyolefin is a copolymer of ethylene, and an unsaturated epoxide.

9. The multilayer pipe of claim 1 comprising a fluid transport system for transporting water, hot water, chemicals or a gas.

10. The multilayer pipe of claim 9 comprising a fluid transport system for conveying hot water in an under-floor radiant heating system or for conveying hot water to a radiator.

11. The multilayer pipe of claim 9 comprising a fluid transport system in radiant heating systems.

12. The multiplayer pipe of claim 9 comprising a fluid transport system wherein the gas is a gaseous hydrocarbon, nitrogen, helium, hydrogen, oxygen, a corrosive gas or a gas capable of degrading polyethylene or polypropylene, or a cryogen.

13. The multilayer pipe according to claim 1 , in which the vinylidene fluoride copolymer of the layer C 1 and/or of the layer C 2 is a VDF copolymer containing at least 75% VDF by weight.

14. The multilayer pipe according to claim 8 , in which the functionalized polyolefin is a copolymer of ethylene, an unsaturated epoxide, and an alkyl acrylate.

15. The multilayer pipe of claim 1 , wherein said barrier layer comprises polydimethylketene.

Assignees

• Bonnet Anthony
• Werth Michael
• Arkema France

Inventors

• Bonnet Anthony
• Werth Michael

Classifications

• B32B27/28 Primary

  comprising synthetic resins not wholly covered by any one of the sub-groups {B32B27/30 - B32B27/42} · CPC title

• F16L9/121

  with three layers · CPC title

• Y10T428/1393

  Multilayer [continuous layer] · CPC title

• F16L2011/047

  with a diffusion barrier layer · CPC title

• B32B27/327

  comprising polyolefins obtained by a metallocene or single-site catalyst · CPC title