Metal complex and supported metal complex having disiloxane as ligand, method for production therefor, and supported metal catalyst prepared by using the same

Patent metadata

Field	Value
Publication number	US-9616418-B2
Application number	US-201414774481-A
Country	US
Kind code	B2
Filing date	Mar 13, 2014
Priority date	Mar 14, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A metal complex represented by the following Formula (1):

(wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 0 to 2 showing the number of the ligand; and each of R 1 to R 4 represents an organic group). The metal complex described above can be fixed on an inorganic oxide while maintaining a skeletal structure thereof to obtain a supported metal complex, which makes it possible to allow the supported metal complex to maintain the same catalytic activity as that of the original metal complex. Also, calcining the supported metal complex obtained in the manner described above makes it possible to obtain a supported metal catalyst improved in catalytic activity to a greater extent than conventional supported metal catalysts.

First claim

The invention claimed is:

1. A supported metal complex having a structure represented by the following Formula (2), in which the metal complex is fixed on an inorganic oxide:

wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; and n represents an integer of 1 to 2 showing the number of the ligand.

2. The supported metal complex according to claim 1 , wherein the inorganic oxide is silica.

3. The supported metal complex according to claim 1 , wherein the inorganic oxide is mesoporous silica MCM-41.

4. A method for producing the supported metal complex as defined in claim 1 , comprising contacting an organic solvent solution of a metal complex represented by the following Formula (3) with an inorganic oxide, to support the metal complex on the inorganic oxide:

wherein M represents palladium or platinum; L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound and an isocyanide compound; n represents an integer of 1 to 2 showing the number of the ligand; and each of R 1′ to R 4′ represents an alkoxy group having 1 to 4 carbon atoms.

5. A catalyst for hydrosilylation reaction of olefins, comprising the supported metal complex as defined in claim 1 .

Assignees

• Nat Inst Advanced Ind Science & Tech

Inventors

• Choi Jun-Chul
• Fukaya Norihisa
• Yasuda Hiroyuki

Classifications

• C07F15/0093

  without a metal-carbon linkage · CPC title

• C07F15/0066

  without a metal-carbon linkage · CPC title

• C07C2531/22

  Organic complexes · CPC title

• C07C5/03

  of non-aromatic carbon-to-carbon double bonds · CPC title

• B01J2531/828

  Platinum · CPC title