Mixed metal oxidic nano sheets coated monolithic catalysts useful for the decomposition of toxic N2O and a process for the preparation thereof

Patent metadata

Field	Value
Publication number	US-9616412-B2
Application number	US-201314646333-A
Country	US
Kind code	B2
Filing date	Nov 25, 2013
Priority date	Nov 23, 2012
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A process for the preparation of nano-oxide coated catalysts useful for the treatment of toxic gases by coating of composite materials containing LDHs over ceramic monolithic substrates. The process combines reacting oxides and salts of metals so as to prepare LDHs or mixed metal layered hydroxides possessing positive layer charge, from which a stable gel is prepared by adding swellable clay having a negative charge in different LDH:clay ratio in an aqueous medium and homogenizing the same in a high intensity ultrasonic processor. The gel is then dip-coated over cordierite/mulite honey-comb monolithic supports at various dipping and withdrawal rates. The dip-coated monoliths are then dried and calcined at different temperatures to develop the alumino-silicate supported nano-oxide coats over honey-comb ceramic substrates for carrying out decomposition of N20 gas in a He flow in various flow rates at 400 to 600° C. temperature in a cylindrical quartz tube.

First claim

We claim:

1. Mixed metal oxidic nano-sheet coated monolithic catalyst comprising a composite gel wherein the gel comprises layered double hydroxide and clay in ratio ranging between 0.2:1 to 1:0.2% w/v of the gel coated over ceramic honeycomb monoliths of 250 to 450 cells per square inch.

2. The mixed metal oxidic nano-sheet coated monolithic catalyst as claimed in claim 1 , wherein metals in layered double hydroxides are selected from the group consisting of Zinc, Magnesium, Chromium, Aluminium and Nickel.

3. The mixed metal oxidic nano-sheet coated monolithic catalyst as claimed in claim 1 , wherein clay is selected from the group consisting of montmorillonite, laponite, hectorite.

4. The mixed metal oxidic nano-sheet coated monolithic catalyst as claimed in claim 1 ,
wherein ceramic monolith used is cordierite/mulite honey-comb monolith having 250 to 400 Channels Per Square Inch.

5. A process for the preparation of mixed metal oxidic nano-sheet coated monolithic catalyst as claimed in claim 1 , wherein the said process comprising the steps of;
a. providing layered double hydroxides:clay composite in ratio of 0.2:1 to 1:0.2% w/v of the gel;
b. homogenising layered double hydroxides:clay composite as obtained in step (a) with a homogeniser at 8000-14000 RPM for 5 to 15 minutes further dispersing under ultrasonication by using 0.5 or 1 inch titanium horn in a high intensity ultrasonic processor at above 15 kHz frequency of 20 to 40% amplitude for 3-10 minutes with 1.5-4.5 second pulser on and 1.0-2.0 second pulser off mode and 1 inch (25 mm) solid titanium horn with a total spell of sonication for 0.5 to 3.5 hours over a period of 4 to 10 days with 5 to 24 hours gap between each spell; dip-coating the prepared gels over cordierite/mulite honey-comb monolithic supports of 250 to 400 Channels Per Square Inch at dipping rates of 5 to 20 cm/min and withdrawal rates of 1 to 20 cm/min followed by drying the dip-coated monoliths at 80-160° C. and calcining the dried coated monoliths at 350 to 650° C. to obtain mixed metal oxidic nano-sheet coated monolithic catalyst.

6. The process for decomposition of N 2 O gas using layered double hydroxides-clay composite coated on a ceramic monolith as claimed in claim 1 , wherein the said process comprises flowing N 2 O gas premixed with He over mixed layered double hydroxides-clay composite coated on a ceramic monolith in reactor at a flow rate ranging between 5 to 50 ml/minute at temperature ranging between 300 to 550° C. for a period ranging between 30 to 120 minutes to obtain Nitrogen and Oxygen.

7. The process for decomposition of N 2 O gas as claimed in claim 6 , wherein reactor used is a cylindrical quartz reactor with a reaction area of 20-80 cm 3 , length 10-60 cm and diameter 2-3 cm.

8. The process for decomposition of N 2 O gas as claimed in claim 6 , wherein Specific Decomposition Efficiencies of the reaction is in the range of 20,000 to 40,000%/gram.

9. The process for decomposition of N 2 O gas as claimed in claim 6 , wherein N 2 O conversion is in the range of 90 to 98%.

Assignees

• Council Scient Ind Res

Inventors

• Goswamee Rajib Lochan
• Mishra Mridusmita
• Baruah Anil Kumar Sarma

Classifications

• B01J35/57

  Honeycombs · CPC title

• B01D2255/20753

  Nickel · CPC title

• B01J37/0215

  Coating · CPC title

• B01D53/8628

  Processes characterised by a specific catalyst · CPC title

• B01J21/16

  Clays or other mineral silicates · CPC title