Installing monoliths in a reactor for conducting heterogeneously catalyzed gas phase reactions

Patent metadata

Field	Value
Publication number	US-9616406-B2
Application number	US-201414180455-A
Country	US
Kind code	B2
Filing date	Feb 14, 2014
Priority date	Feb 14, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A method is proposed for installing monoliths ( 2 ) each formed of a ceramic block having a multiplicity of mutually parallel channels wherethrough the reaction gas mixture of a heterogeneously catalyzed gas phase reaction can flow in a reactor ( 1 ) for conducting heterogeneously catalyzed gas phase reactions, wherein said monoliths ( 2 ) are stacked side by side and on top of each other in the reactor interior, wherein the monoliths are sealed off from each other and from the inner wall of said reactor ( 1 ) by mats ( 3 ) each comprising an intumescent mat which before installation in said reactor ( 1 ) were completely enveloped in a polymeric film, wherein the interior enclosed by the polymeric film and containing said mat ( 3 ) is evacuated and wherein the interior enclosed by the polymeric film and containing said mat ( 3 ) is devacuated after installation in said reactor ( 1 ).

First claim

We claim:

1. A method of installing a multiplicity of monoliths comprising;
stacking the multiplicity of monoliths side by side and on top of each other in a heterogeneously catalyzed, gas phase dehydrogenation reactor, wherein each monolith is formed of a ceramic block having multiple parallel channels, and with the parallel channels of one monolith mutually aligned with the parallel channels of an adjacent monolith through which a reaction gas mixture can flow through the reactor for conducting heterogeneously catalyzed, gas phase dehydrogenation reactions, and the multiplicity of monoliths are separated from each other and from an inner wall of the reactor by an arrangement of mats each mat comprising an intumescent mat, wherein the mats are enclosed and sealed within a polymeric film under reduced pressure, and
unsealing the polymeric film enclosure of the arranged mats in the reactor to seal the monoliths from each other and from the inner wall of the reactor.

2. The method according to claim 1 wherein said mat is an intumescent mat.

3. The method according to claim 1 wherein the polymeric film comprises one or more polyamides or mixtures of one or more polyamides with polyethylene and/or polypropylene.

4. The method according to claim 1 wherein the unsealing of the enclosure includes puncturing and/or burning off the polymeric film.

5. The method according to claim 1 wherein the multiplicity of monoliths are installed in the dehydrogenation reactor in one or more horizontal layers side by side across a reactor cross section and forming vertically disposed channels in said reactor, and wherein spacers are provided between successive layers to vacate cavities where a measuring element can be introduced.

6. The method according to claim 5 wherein the measuring element measures temperature.

7. The method according to claim 1 wherein said mat is a composite mat including an intumescent mat and a fibrous mat of oxidic fibers, wherein the intumescent mat and the fibrous mat are each sheet bodies which are joined at their major surfaces.

8. The method according to claim 7 wherein the composite mat comprises a plurality of successive layers each consisting of one intumescent mat and one fibrous mat.

9. The method according to claim 1 wherein the multiplicity of monoliths are arranged side by side and on top of each other, and are enclosed at the outer periphery thereof, in the longitudinal direction of the channels, by a metal enclosure to form a monolith module, and wherein said monolith module is installed in said reactor with horizontally disposed channels.

10. The method according to claim 9 , wherein both ends of the metal enclosure extends beyond the monoliths, which allows the enclosure to function as spacer between adjacent monolith modules.

11. The method according to claim 9 wherein two or more monolith modules are stacked on top of each other to form monolith module stacks.

12. The method according to claim 11 wherein two or more monolith module stacks are installed in said reactor one behind the other.

Assignees

• Basf Se

Inventors

• Olbert Gerhard
• Gauer Jochen
• Kühling Arnold
• Tellaeche Herranz Carlos

Classifications

• B01J2219/2438

  Ceramics · CPC title

• Y10T29/49826

  Assembling or joining · CPC title

• B01J19/2485 Primary

  Monolithic reactors · CPC title

• B01J2219/2443

  Assembling means of monolith modules · CPC title