Base metal catalyst

Patent metadata

Field	Value
Publication number	US-9616384-B2
Application number	US-201514604026-A
Country	US
Kind code	B2
Filing date	Jan 23, 2015
Priority date	Jun 11, 2014
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

Described are base metal catalysts that comprise a base metal material in an amount effective to generate an exotherm over a temperature range of 300° C. to 650° C. and to oxidize soot collected by a downstream particulate filter. The base metal catalysts are substantially free of platinum group metals. Emission treatment systems and methods of remediating nitrogen oxides (NO x ), particulate matter, and gaseous hydrocarbons using base metal catalyst are also described.

First claim

What is claimed is:

1. A base metal catalyst for abatement of exhaust gas emissions from a lean burn engine comprising:
a base metal material in an amount effective to generate an exotherm upon the introduction of combustible matter to actively and periodically regenerate a downstream particulate filter containing accumulated soot collected by the downstream particulate filter, the exotherm generating heat to provide a temperature range of 300° C. to 650° C. in front of the downstream particulate filter, wherein the base metal catalyst is substantially free of platinum group metals.

2. The base metal catalyst of claim 1 , wherein the exhaust gas emissions comprise sulfur and the combustible matter comprises diesel fuel.

3. The base metal catalyst of claim 1 , wherein the base metal material is selected from V, W, Ti, Cu, Fe, Co, Ni, Cr, Mn, Nd, Ba, Ce, La, Pr, Mg, Ca, Zn, Nb, Zr, Mo, Sn, Ta, Ce, and Sr, and combinations thereof.

4. The base metal catalyst of claim 3 , wherein the base metal material comprises one or more of V, W, Fe, Ce, Cu, and Ti.

5. The base metal catalyst of claim 1 , further comprising a molecular sieve material.

6. The base metal catalyst of claim 5 , wherein the molecular sieve material has a framework of silicon, aluminum, and/or phosphorus atoms.

7. The base metal catalyst of claim 5 , wherein the molecular sieve material comprises ring sizes of no larger than 12.

8. The base metal catalyst of claim 7 , wherein the molecular sieve material comprises a d6r unit.

9. The base metal catalyst of claim 8 , wherein the molecular sieve material is selected from AEI, AFT, AFX, CHA, EAB, EMT, ERI, FAU, GME, JSR, KFI, LEV, LTL, LTN, MOZ, MSO, MWW, OFF, SAS, SAT, SAV, SBS, SBT, SFW, SSF, SZR, TSC, WEN, and combinations thereof.

10. The base metal catalyst of claim 9 , wherein the molecular sieve material is selected from AEI, CHA, AFX, ERI, KFI, LEV, and combinations thereof.

11. The base metal catalyst of claim 10 , wherein the molecular sieve material is selected from AEI, CHA, and AFX.

12. The base metal catalyst of claim 5 , wherein the molecular sieve material comprises a d6r unit, and the base metal material is selected from Cu, Fe, and combinations thereof.

13. The base metal catalyst of claim 11 , wherein the molecular sieve material comprises CHA and the base metal material is selected from Cu, Fe, and combinations thereof.

14. The base metal catalyst of claim 1 , wherein the base metal catalyst is dispersed on a refractory metal oxide support.

15. The base metal catalyst of claim 14 , wherein the base metal catalyst is in a configuration selected from uniform, zoned, or layered.

16. A system for treatment of a lean burn engine exhaust gas stream including hydrocarbons, carbon monoxide, and other exhaust components, the system comprising
an exhaust conduit in fluid communication with the lean burn engine via an exhaust manifold;
the base metal catalyst of claim 1 disposed on a carrier substrate; and
a particulate filter and a first SCR catalyst located downstream from the base metal catalyst.

17. The system of claim 16 , wherein a second SCR catalyst is coated onto the particulate filter located downstream from the base metal catalyst.

18. The system of claim 16 , further comprising a platinum group metal (PGM) oxidation catalyst downstream from the base metal catalyst and upstream from the particulate filter.

19. The system of claim 18 , wherein the base metal catalyst and the platinum group metal (PGM) oxidation catalyst are located on a single substrate.

20. The system of claim 18 , wherein the base metal catalyst and the platinum group metal (PGM) oxidation catalyst are located on separate substrates.

21. The system of claim 19 , wherein the base metal catalyst and the platinum group metal are layered on the substrate.

22. The system of claim 19 , wherein the base metal catalyst and the platinum group metal are axially zoned on the substrate.

23. The system of claim 20 , wherein the platinum group metal (PGM) oxidation catalyst comprises an ammonia oxidation catalyst, and wherein the system further comprises a reductant injector downstream of the engine and upstream of the base metal catalyst.

24. The system of claim 17 , further comprising a reductant injector downstream of the particulate filter.

25. The system of claim 16 , wherein fuel is injected upstream from the base metal catalyst and the fuel comprises sulfur.

26. The system of claim 25 , wherein the fuel comprises less than 10 ppm of sulfur.

27. The system of claim 25 , wherein the fuel comprises greater than 10 ppm sulfur.

28. The system of claim 16 , wherein there is no platinum group metal oxidation catalyst upstream from the base metal catalyst or upstream from the SCR catalyst.

29. The system of claim 16 , further comprising an ammonia oxidation catalyst downstream from the particulate filter and the first SCR catalyst.

30. A method of treating an exhaust stream from a diesel engine comprising NO x , particulate matter, and combustible matter, the method comprising:
flowing the exhaust stream through a base metal catalyst comprising a base metal material, thereby combusting at least some of the combustible matter, generating an exotherm of 300° C. to 650° C. in front of a downstream particulate filter containing accumulated soot and actively and periodically regenerating the downstream particulate filter,
wherein the base metal catalyst is substantially free of platinum group metals.

31. The method of claim 30 , wherein the combustible matter comprises an unburned gaseous hydrocarbon, a non-volatile hydrocarbon, carbon monoxide, or any combination thereof, and wherein combusting at least some of the combustible matter forms carbon dioxide and water.

32. The method of claim 31 , further comprising flowing the exhaust stream through the downstream particulate filter and a first SCR catalyst downstream from the base metal catalyst,
wherein flowing the exhaust stream through the first SCR catalyst reduces NO and/or NO 2 to N 2 .

Assignees

• Basf Se

Inventors

• Kalwei Martin
• Huennekes Edgar V

Classifications

• B01D2255/1021

  Platinum · CPC title

• B01D2255/65

  Catalysts not containing noble metals · CPC title

• B01D2255/50

  Zeolites · CPC title

• B01D2255/20776

  Tungsten · CPC title

• B01D2255/20723

  Vanadium · CPC title