Flexible solid state conductors including polymer mixed with protein

Patent metadata

Field	Value
Publication number	US-9614250-B2
Application number	US-201414223017-A
Country	US
Kind code	B2
Filing date	Mar 24, 2014
Priority date	May 9, 2011
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

Various embodiments of solid-state conductors containing solid polymer electrolytes, electronic devices incorporating the solid-sate conductors, and associated methods of manufacturing are described herein. In one embodiment, a solid-state conductor includes poly(ethylene oxide) having molecules with a molecular weight of about 200 to about 8×10 6 gram/mol, and a soy protein product mixed with the poly(ethylene oxide), the soy protein product containing glycinin and β-conglycinin and having a fine-stranded network structure. Individual molecules of the poly(ethylene oxide) are entangled in the fine-stranded network structure of the soy protein product, and the poly(ethylene oxide) is at least 50 % amorphous.

First claim

What is claimed is:

1. An electronic device comprising:
a first electrode;
a second electrode spaced apart from the first electrode; and
a solid polymer electrolyte disposed between the first electrode and the second electrode, the solid polymer electrolyte comprising:
at least one salt;
a plurality of polymer molecules;
at least one denatured protein mixed with the polymer molecules, wherein individual molecules of the plurality of polymer molecules are entangled in the denatured protein, wherein the protein is derived from plants or plant products; and
wherein the solid polymer electrolyte comprises about 1 wt % to about 45 wt % of the at least one salt, and has conductivity that allows ions to flow between the first electrode and the second electrode.

2. The electronic device of claim 1 , wherein the solid polymer electrolyte comprises about 10 wt % to about 25 wt % of the at least one salt, about 33 wt % to about 40 wt % of the plurality of polymer molecules, and about 41 wt % to about 49 wt % of the at least one denatured protein.

3. The electronic device of claim 1 wherein the plurality of polymer molecules comprises poly(ethylene oxide).

4. The electronic device of claim 1 , wherein the protein comprises a soy protein.

5. The electronic device of claim 1 , wherein the at least one salt comprises at least one of LiPF 6 , LiTFSI, LiBF 4 , LiClO 4 , LiN(CF 3 SO 2 ) 2 , LiAsF 6 , LiCF 3 SO 3 , LiI, LiBC 4 O 8 , Li[PF 3 (C 2 F 5 ) 3 ], LiTf, Lilm, LiBr, LiCl, LiSCN, LiTFSM, NaI, LiCF 3 CO 2 , NaBr, NaSCN, KSCN, MgCl 2 , and Mg(ClO 4 ).

6. The electronic device of claim 1 , wherein an oxygen polar group of one of the plurality of polymer molecules is bound to an ammonium group of one of strands of the denatured protein.

7. The electronic device of claim 1 , wherein the solid polymer electrolyte has an ionic conductivity that allows ions of the at least one salt to migrate between the first electrode and the second electrode.

8. The electronic device of claim 1 , wherein individual carbonyl groups of one of strands of the denatured protein are bound to a cation of the at least one salt to effect repulsion from adjacent strands of the denatured protein.

9. The electronic device of claim 1 , wherein:
at least one strand of the denatured protein has a carbonyl group;
at least one of the plurality of polymer molecules has a first oxygen polar group and a second oxygen polar group;
a cation of the at least one salt is bound to the first oxygen polar group of the one of the plurality of polymer molecules and to the carbonyl group of the at least one strand of the denatured protein; and
the second oxygen polar group of the at least one of the plurality of polymer molecules is bound to an ammonium group of the at least one strand of the denatured protein.

10. A solid polymer electrolyte comprising:
at least one denatured protein,
wherein the at least one denatured protein is derived from plants or plant products;
at least one polymer comprising at least one polar functional group, wherein individual molecules of the at least one polymer are entangled in the at least one denatured protein; and
about 10 wt% to about 45 wt% of at least one salt.

11. The solid polymer electrolyte of claim 10 , comprising about 33 wt % to about 40 wt % of the at least one polymer, about 41 wt % to about 49 wt % of the at least one denatured protein, and about 10 wt % to about 25 wt % of the at least one salt.

12. The solid polymer electrolyte of claim 10 , wherein:
a ratio of the at least one denatured protein to the at least one polymer is about 55:45 by weight;
the at least one polymer molecules are about 100% amorphous; and
the solid polymer electrolyte is deformable by about 50% to about 700% from an original configuration without damage to the solid polymer electrolyte.

13. The solid polymer electrolyte of claim 10 , wherein the at least one salt comprises at least one of LiPF 6 , LiTFSI, LiBF 4 , LiClO 4 , LiN(CF 3 SO 2 ) 2 , LiAsF 6 , LiCF 3 SO 3 , LiI, LiBC 4 O 8 , Li[PF 3 (C 2 F 5 ) 3 ], LiTf, Lilm, LiBr, LiCl, LiSCN, LiTFSM, NaI, LiCF 3 CO 2 , NaBr, NaSCN, KSCN, MgCl 2 , and Mg(ClO 4 ).

14. The solid polymer electrolyte of claim 10 , wherein the at least one denatured protein comprises a soy protein.

15. The solid polymer electrolyte of claim 14 , wherein the soy protein comprises glycinin, β-conglycinin, or a combination thereof.

16. The solid polymer electrolyte of claim 10 , wherein the at least one polymer has a molecular weight of about 200 gram/mol to about 8×10 6 gram/mol.

17. The solid polymer electrolyte of claim 16 , wherein the at least one polymer comprises poly(ethylene oxide).

18. The solid polymer electrolyte of claim 10 , further comprising a plurality of cations noncovalently bound with the at least one polymer, the at least one denatured protein, or both.

19. The solid polymer electrolyte of claim 18 , wherein the cations comprise Li + , K + , Na + , Ca 2+ , Mg 2+ , Cd 2+ , Al 3+ , Zn 2+ , Fe 2+ , Fe 3+ , Pb 2+ , Cu 2+ , Ag + , or a combination thereof.

20. A method to prepare a solid polymer electrolyte, the method comprising:
dissolving at least one salt in a solvent to form a salt solution;
mixing a protein with the salt solution to form a protein dispersion,
wherein the protein is derived from plants or plant products;
denaturing the protein in the protein dispersion to form a denatured protein dispersion;
mixing a polymer with the denatured protein to form a polymer-protein mixture; and
evaporating the solvent from the polymer-protein mixture to form the solid polymer electrolyte,
wherein the solid polymer electrolyte comprises about 10 wt% to about 45 wt% of the at least one salt.

21. The method according to claim 20 , wherein the solid polymer electrolyte comprises about 10 wt% to about 25 wt% of the at least one salt, about 33 wt% to about 40 wt% of the polymer, and about 41 wt% to about 49 wt% of the denatured protein.

22. The method according to claim 20 , wherein mixing the protein with the at least one salt comprising mixing a soy protein.

23. The method according to claim 20 , wherein mixing with the polymer comprises mixing poly(ethylene oxide).

24. The method according to claim 20 , wherein mixing the protein with the at least one salt comprises mixing with at least one of LiPF 6 , LiTFSI, LiBF 4 , LiClO 4 , LiN(CF 3 SO 2 ) 2 , LiAsF 6 , LiCF 3 SO 3 , LiI, LiBC 4 O 8 , Li[PF 3 (C 2 F 5 ) 3 ], LiTf, Lilm, LiBr, LiCl, LiSCN, LiTFSM, NaI, LiCF 3 CO 2 , NaBr, NaSCN, KSCN, MgCl 2 , and Mg(ClO 4 ).

25. The method according to claim 20 , wherein dissolving the at least one salt comprising dissolving in water.

26. The method according to claim 20 ,
wherein the solvent has a pH, and the method further comprises:
heating the protein dispersion at a treatment temperature for a treatment period prior to mixing with the polymer; and
adjusting at least one of the pH of the solvent, the treatment temperature, or the treatment period based on at least one of a target electrical conductivity or a targeted mechanical flexibility of the solid polymer electrolyte.

27. The method according to claim 20 , further comprising adjusting at least one of a ratio between the polymer and the protein, or the polymer and a composition of the protein, based on at least one of a target electrical conductivity or a target mechanical flexibility of the solid p

Assignees

• Univ Washington State
• Empire Technology Dev Llc

Inventors

• Zhong wei-hong
• Ji Jianying
• Li Bin

Classifications

• H01M8/1069

  characterised by the manufacturing processes · CPC title

• Y02P70/56

  Cross-Sectional Technologies · mapped topic

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M8/1041

  Polymer electrolyte composites, mixtures or blends · CPC title