High energy density redox flow device

Patent metadata

Field	Value
Publication number	US-9614231-B2
Application number	US-201114002304-A
Country	US
Kind code	B2
Filing date	Dec 16, 2011
Priority date	Jun 12, 2008
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

First claim

What is claimed is:

1. An electrochemical cell comprising:
an anode;
a cathode; and
an ion-permeable membrane disposed between the anode and the cathode;
wherein at least one of the anode and the cathode includes an electrode composition comprising ion storage compound particles capable of taking up or releasing ions, and 0.5% to 10% by volume of electronically conductive particles disposed in a liquid electrolyte, the ion storage compound particles having a polydisperse size distribution and a particle packing fraction of at least 50 vol %.

2. The electrochemical cell of claim 1 , wherein the electronically conductive particles form a percolating network in the electrode composition.

3. The electrochemical cell of claim 1 , wherein the electrode composition is a semi-solid composition.

4. The electrochemical cell of claim 1 , wherein the liquid electrolyte is a non-aqueous liquid electrolyte.

5. The electrochemical cell of claim 1 , wherein the particle packing fraction is at least 70 vol %.

6. The electrochemical cell of claim 1 , wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

7. The electrochemical cell of claim 1 , wherein the electronically conductive particles comprise a conductive inorganic compound selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.

8. The electrochemical cell of claim 1 , wherein the volume percentage of the ion storage compound is between 5% and 70%.

9. The electrochemical cell of claim 1 , wherein the electrode composition comprises 0.5% to 5% by volume of the electronically conductive particles.

10. An electrochemical cell comprising:
an anode;
a cathode; and
an ion-permeable membrane disposed between the anode and the cathode;
wherein at least one of the anode and the cathode includes a semi-solid electrode composition comprising ion storage compound particles capable of taking up or releasing ions, and 0.5% to 10% by volume of electronically conductive particles disposed in a liquid electrolyte, the ion storage compound particles having a polydisperse size distribution and a particle packing fraction of at least 50 vol %.

11. The electrochemical cell of claim 10 , wherein the particle packing fraction is at least 70 vol %.

12. The electrochemical cell of claim 10 , wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

13. The electrochemical cell of claim 10 , wherein the volume percentage of the ion storage compound is between 5% and 70%.

14. The electrochemical cell of claim 10 , wherein the electronically conductive particles form a percolating network in the electrode composition.

15. The electrochemical cell of claim 10 , wherein the electronically conductive particles comprise a conductive inorganic compound selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.

16. An electrochemical cell comprising:
an anode;
a cathode; and
an ion-permeable membrane disposed between the anode and the cathode;
wherein at least one of the anode and the cathode includes an electrode composition comprising a suspension of ion storage compound particles capable of taking up or releasing ions, and 0.5% to 10% by volume of electronically conductive particles disposed in a liquid electrolyte, the ion storage compound particles having a polydisperse size distribution and a particle packing fraction of at least 50 vol %.

17. The electrochemical cell of claim 16 , wherein the ion storage compound particles have a particle packing fraction of at least 70 vol %.

18. The electrochemical cell of claim 16 , wherein the electrode composition comprises a semi-solid composition.

19. The electrochemical cell of claim 16 , wherein the liquid electrolyte is a non-aqueous liquid electrolyte.

20. The electrochemical cell of claim 16 , wherein the electronically conductive particles form a percolating network in the electrode composition.

21. The electrochemical cell of claim 16 , wherein the electronically conductive particles comprise a conductive inorganic compound selected from the group consisting of metals, metal carbides, metal nitrides, metal oxides, and allotropes of carbon including carbon black, graphitic carbon, carbon fibers, carbon microfibers, vapor-grown carbon fibers (VGCF), fullerenic carbons including “buckyballs”, carbon nanotubes (CNTs), multiwall carbon nanotubes (MWNTs), single wall carbon nanotubes (SWNTs), graphene sheets or aggregates of graphene sheets, and materials comprising fullerenic fragments and mixtures thereof.

22. The electrochemical cell of claim 16 , wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

Assignees

• Carter W Craig
• Chiang Yet-Ming
• Duduta Mihai
• Limthongkul Pimpa
• 24M Technologies Inc

Inventors

• Carter W Craig
• Chiang Yet-Ming
• Duduta Mihai
• Limthongkul Pimpa

Classifications

• H01M8/0215

  Glass; Ceramic materials · CPC title

• H01M8/0221

  Organic resins; Organic polymers · CPC title

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• B60L50/64 Primary

  Constructional details of batteries specially adapted for electric vehicles · CPC title

• H01M8/0228

  in the form of layered or coated products · CPC title