Piezoelectric device with piezoelectric ceramic layer having AG segregated in voids in sintered body of perovskite composition
US-9406866-B2 · Aug 2, 2016 · US
US9614142B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9614142-B2 |
| Application number | US-201514973671-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 17, 2015 |
| Priority date | Dec 20, 2011 |
| Publication date | Apr 4, 2017 |
| Grant date | Apr 4, 2017 |
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A piezoelectric ceramic composition contains a perovskite composition which is represented by (Pba·Rex){Zr b ·Ti c , ·(Ni 1/3 Nb 2/3 ) d ·(Zn 1/3 Nb 2/3 ) e }O 3 (wherein Re represents La and/or Nd, and a-e and x satisfy the following conditions 0.95≦a≦1.05, 0≦x≦0.05, 0.35≦b≦0.45, 0.35≦c≦0.45, 0<d≦0.10, 0.07≦e≦0.20 and b+c+d+e=1) and 0.05-0.3% by mass of an Ag component in terms of oxides relative to the perovskite composition.
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What is claimed is: 1. A piezoelectric ceramic composition obtained by sintering a zirconate-titanate type perovskite composition expressed by Formula (1) below, as well as an Ag component, wherein the Ag component is contained by 0.05 to 0.3 parts by mass per 100 parts by mass of the zirconate-titanate type perovskite composition in terms of oxides: (Pb a ·Re x )(Zr b ·Ti c ·(Ni 1/3 Nb 2/3 ) d ·(Zn 1/3 Nb 2/3 ) e )O 3 (1) wherein Re represents at least one of La and Nd, and a to e and x meet the respective requirements below: 0.95≦a≦1.05 0≦x≦0.05 0.35≦b≦0.45 0.3≦c≦0.45 0<d≦0.10 0.07≦e≦0.20 b+c+d+= 1, wherein metal Ag is segregated in voids present in the sintered body of the perovskite composition. 2. A piezoelectric ceramic composition according to claim 1 , wherein a maximum grain size of the Ag component is 3 μm or less. 3. A piezoelectric ceramic composition according to claim 1 , wherein a grain size of metal Ag segregated in the voids present in the sintered body of the perovskite composition is 0.1 to 3 μm in d80 diameter.
Micrometer sized grains, i.e. from 1 to 100 micron · CPC title
Lanthanum oxide or oxide-forming salts thereof · CPC title
Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof · CPC title
Lithium oxide or oxide-forming salts thereof · CPC title
Electricity · mapped topic
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