Integration of N-C4/N-C4=/BD separation system for on-purpose butadiene synthesis

Patent metadata

Field	Value
Publication number	US-9611192-B2
Application number	US-201514749059-A
Country	US
Kind code	B2
Filing date	Jun 24, 2015
Priority date	Jun 30, 2014
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

A process for the production of butadiene is presented. The process combines the separation of butenes and butadienes extracted from a non-oxidated dehydrogenation process with the separation of butenes and butadienes from an oxidative dehydrogenation process to increase the butadiene yields and reduce the equipment for the recovery of a butadiene product.

First claim

What is claimed is:

1. A process for the recovery of butadiene, comprising:
passing a first feedstream comprising n-butane to a dehydrogenation unit to generate a first butene process stream comprising n-butene;
passing the first n-butene process stream to a butane extraction column to generate a butane overhead stream and a first n-butene stream, wherein the butane extraction column is operated to recover the n-butenes in the first butene stream;
passing the first n-butene process stream to a butene extraction column to generate an overhead stream comprising n-butene, and a bottoms stream comprising butadiene
passing the overhead stream to an oxydehydrogenation unit to generate a second process stream comprising n-butene and butadiene;
passing the second process stream to a butene extraction column to generate an overhead stream comprising n-butene, and a bottoms stream comprising butadiene; and
passing the bottoms stream to a butadiene recovery unit to generate a butadiene stream.

2. The process of claim 1 further comprising passing a second feedstream comprising n-butene to an oxydehydrogenation unit to generate a second process stream comprising n-butene and butadiene; and
passing the second process stream to the butene extraction column.

3. The process of claim 1 further comprising:
passing the first butene process stream to a light gas separation unit to generate a vapor phase stream comprising hydrogen, and a liquid phase stream comprising n-butane and n-butene; and
passing the liquid phase stream to a butane extraction column to generate a butane overhead stream and the first n-butene process stream.

4. The process of claim 3 further comprising passing the butane overhead stream to the dehydrogenation unit.

5. The process of claim 3 further comprising passing a portion of the vapor phase stream to the dehydrogenation unit.

6. The process of claim 3 wherein the light gas separation unit is a cold-box separation unit to condense the butane and butenes, while separating hydrogen and other light gases from the first process stream.

7. The process of claim 3 further comprising passing a solvent to the butane extraction column.

8. The process of claim 7 wherein the solvent is selected from the group consisting of n-methyl-2-pyrrolidone (NMP), dimethylformamide (DMF), acetonitrile (ACN), and mixtures thereof.

9. The process of claim 1 wherein the oxydehydrogenation unit generates an intermediate stream, further comprising:
passing the intermediate stream to a second light gas separation unit to generate a second light gas stream and a second intermediate stream comprising butadiene and n-butene; and
passing the second intermediate stream to the butene extraction column.

10. The process of claim 1 further comprising passing a solvent to the butene extraction column.

11. The process of claim 1 further comprising passing steam and air to the oxydehydrogenation unit.

12. The process of claim 1 wherein passing the bottoms stream to the butadiene recovery unit comprises:
passing the bottoms stream to a rectifying column to generate an overhead stream, an intermediate stream comprising butadiene, and a rectifying bottoms stream;
passing the rectifying bottoms stream to a degassing column to generate a degassing column overhead stream an a solvent recovery bottoms stream;
passing the degassing column overhead stream to the rectifying column;
passing the intermediate stream to a butadiene extraction column to generate a butadiene extraction column bottoms comprising solvent and n-butene, and the butadiene stream.

13. The process of claim 12 further comprising passing a solvent to the butadiene extraction column.

14. A process for the recovery of butadiene, comprising:
passing a first stream comprising n-butane to a dehydrogenation reactor to generate a second stream comprising n-butane and n-butene;
passing the second stream to a light gas separation unit to generate a vapor phase comprising hydrogen, and a third stream comprising liquid n-butane and n-butene;
passing the third stream to a butane extraction column to generate a fourth stream comprising n-butane and a fifth stream comprising n-butene;
passing the fifth stream to a butene extraction column;
passing a sixth stream comprising n-butene to an oxydehydrogenation reactor to generate a seventh stream comprising butadiene and n-butene;
passing the seventh stream to a second light gas separation unit to generate a second vapor phase comprising light gases, and an eighth stream comprising butadiene and n-butene; and
passing the eighth stream to the butene extraction column to generate a ninth stream comprising n-butene, and a tenth stream comprising butadiene.

15. The process of claim 14 wherein the fifth stream and the eighth stream are passed to the butene extraction column at different stages.

16. The process of claim 14 further comprising:
passing the tenth stream to a rectifying column to generate an overhead stream an intermediate stream comprising butadiene and a bottoms stream comprising solvent; and
passing the intermediate stream to a butadiene extraction column to generate a butadiene product stream and a bottoms stream.

17. The process of claim 16 further comprising passing the butadiene extraction column bottoms stream to the rectifying column.

18. The process of claim 16 further comprising:
passing the rectifying column bottoms stream to a degassing column to generate a degassing column overhead and a recovered solvent bottoms stream; and
passing the degassing column overhead stream to the rectifying column.

19. The process of claim 14 further comprising passing steam and air to the oxydehydrogenation reactor.

20. The process of claim 14 wherein the extraction columns comprise passing a solvent to the extraction column.

Assignees

• Uop Llc

Inventors

• Digiulio Christopher D

Classifications

• C07C7/10

  by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids · CPC title

• C07C5/327

  Formation of non-aromatic carbon-to-carbon double bonds only · CPC title

• C07C5/48 Primary

  with oxygen as an acceptor · CPC title

• C07C11/167

  1, 3-Butadiene · CPC title

• C07C11/08

  with four carbon atoms · CPC title