Method for manufacturing a part made of CMC

Patent metadata

Field	Value
Publication number	US-9611180-B2
Application number	US-201314431413-A
Country	US
Kind code	B2
Filing date	Sep 13, 2013
Priority date	Sep 27, 2012
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

A composite material part having a matrix made of ceramic, at least for the most part, is fabricated by a method including making a fiber preform from silicon carbide fibers containing less than 1 at % oxygen; depositing a boron nitride interphase on the fibers of the preform, deposition being performed by chemical vapor infiltration at a deposition rate of less than 0.3 μm/h; performing heat treatment to stabilize the boron nitride of the interphase, after the interphase has been deposited, without prior exposure of the interphase to an oxidizing atmosphere and before depositing matrix layer on the interphase, the heat treatment being performed at a temperature higher than 1300° C. and not less than the maximum temperature to be encountered subsequently until the densification of the preform with the matrix has been completed; and thereafter, densifying the perform with a matrix that is made of ceramic, at least for the most part.

First claim

The invention claimed is:

1. A method of fabricating a composite material part having a matrix, the majority of said matrix being made of ceramic, the method comprising:
making a fiber preform from silicon carbide fibers containing less than 1 at % oxygen;
depositing a boron nitride interphase on the fibers of the preform, deposition being performed by chemical vapor infiltration at a deposition rate of less than 0.3 μm/h so as to obtain coated fibers;
performing heat treatment of the thus obtained coated fibers, only after the end of the deposition of the boron nitride interphase, without prior exposure of the interphase to an oxidizing atmosphere and before depositing matrix layer on the interphase, the heat treatment allowing to stabilize the boron nitride of the interphase, the heat treatment being performed on the coated fibers which comprise the fibers and the boron nitride interphase and which are deprived of any matrix layer deposited on the boron nitride interphase, the heat treatment being performed at a temperature higher than 1300° C. and not less than a maximum temperature to be encountered subsequently until a densification of the preform with the matrix has been completed; and
thereafter, densifying the preform with the matrix.

2. A method according to claim 1 , wherein the boron nitride interphase is deposited at a deposition rate of less than 0.1 μm/h.

3. A method according to claim 1 , wherein the boron nitride interphase is deposited from a reaction gas mixture containing boron chloride BCl 3 , ammonia NH 3 , and gaseous hydrogen H 2 , at a temperature of less than 800° C. and at a pressure of less than 5 kPa.

4. A method according to claim 1 , wherein the boron nitride interphase is deposited from a reaction gas mixture containing boron trifluoride BF 3 , ammonia NH 3 , and gaseous hydrogen H 2 , at a temperature lower than 1050° C., and at a pressure less than 20 kPa.

5. A method according to claim 1 , wherein the duration of the heat treatment lies in the range 0.25 h to 4 h.

6. A method according to claim 1 , wherein the duration of the heat treatment lies in the range 0.5 h to 2 h.

7. A method according to claim 1 , wherein the boron nitride interphase is formed with the preform being held in shaping tooling, and after heat treatment, depositing at least one layer of ceramic on the interphase by chemical vapor infiltration in order to consolidate the preform held in the tooling, densification of the preform subsequently being continued after the consolidated preform has been extracted from the tooling.

8. A method according to claim 1 , wherein the preform is densified at least in part by chemical vapor infiltration.

9. A method according to claim 1 , wherein the preform is densified at least in part by impregnating the preform with at least one ceramic precursor polymer and by pyrolysis.

10. A method according to claim 1 , wherein the preform is densified at least in part by introducing carbon and/or ceramic powder into the preform and by infiltrating silicon-based metal in the molten state.

Assignees

• Herakles

Inventors

• GOUJARD STéPHANE
• Bouillon Eric
• Delcamp Adrien
• BERTRAND SéBASTIEN

Classifications

• C04B2235/5244

  Silicon carbide · CPC title

• C04B2235/428

  Silicon · CPC title

• C04B2235/723

  Oxygen content · CPC title

• C04B2235/483

  Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes · CPC title

• C04B35/62884

  by gas phase techniques · CPC title