Energy efficient polyolefin process

Patent metadata

Field	Value
Publication number	US-9610558-B2
Application number	US-201514975423-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Aug 27, 2004
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

A manufacturing system for producing polyolefin includes a polymerization reactor, a flash chamber, and a purge column. In certain embodiments, the purge column may receive a solids stream directly from the flash chamber. Further, the purge column may function as a feed tank for an extruder within an extrusion/loadout system. According to certain embodiments, the manufacturing system may be configured to consume less than 445 kilowatt-hours of energy per metric ton of polyolefin produced based on consumption of electricity, steam, and fuel gas.

First claim

What is claimed is:

1. A system, comprising:
a polymerization reactor configured to produce a slurry comprising polyolefin particles and a diluent;
a coolant system configured to provide a coolant to a reactor jacket disposed along a portion of the polymerization reactor, wherein an outlet temperature of the coolant exiting the reactor jacket is about 15° F. or more greater than an inlet temperature of the coolant entering the reactor jacket; and
one or more automation controllers configured to:
receive an input indicative of the outlet temperature of the coolant exiting the reactor jacket; and
activate an output to actuate the coolant system to provide the coolant to the reactor jacket based at least in part on the input to maintain the outlet temperature about 15° F. or more greater than the inlet temperature of the coolant entering the reactor jacket.

2. The system of claim 1 , wherein the coolant system is configured to provide the coolant to the reactor jacket such that the outlet temperature of the coolant exiting the reactor jacket is between about 15° F. and about 30° F. greater than the inlet temperature of the coolant entering the reactor jacket.

3. The system of claim 1 , wherein the coolant system is configured to provide the coolant to the reactor jacket such that the outlet temperature of the coolant exiting the reactor jacket is between about 15° F. and about 50° F. greater than the inlet temperature of the coolant entering the reactor jacket.

4. The system of claim 1 , wherein the coolant system comprises a coolant pump configured to circulate the coolant through the reactor jacket.

5. The system of claim 4 , wherein a capacity of a motor coupled to the coolant pump is less than about 600 horsepower, and wherein the coolant pump is configured to provide between about 50 pounds per square inch (psi) and about 60 psi delivered head at between about 3 million pounds per hour and about 12 million pounds per hour of coolant.

6. The system of claim 4 , wherein the coolant system is capable of operating such that the outlet temperature of the coolant exiting the reactor jacket is within 15° F. of the inlet temperature of the coolant entering the reactor jacket, and wherein the one or more automation controllers permit the coolant system to maintain the flow rate of the coolant through the reactor jacket such that the outlet temperature is about 15° F. or more greater than the inlet temperature of the coolant entering the reactor jacket to thereby reduce an amount of power input into the coolant system.

7. The system of claim 1 , comprising:
a diluent/monomer recovery system configured to separate a majority of the diluent from the slurry discharged from the polymerization reactor and to recycle a first portion of the separated diluent to a feed system for the polymerization reactor without fractionating the first portion; and
a fractionation system configured to fractionate a second portion of the separated diluent to provide recovered diluent to the polymerization reactor substantially free of monomer.

8. The system of claim 1 , comprising:
a separation vessel configured to receive the slurry to produce a lights stream comprising light components and a solids stream comprising the polyolefin particles and residual diluent; and
an additional polymerization reactor configured to receive the solids stream and produce additional polyolefin particles, wherein the additional polymerization reactor comprises a loop slurry polymerization reactor.

9. The system of claim 1 , wherein the coolant system comprises:
a coolant flow element configured to provide a flow input indicative of an actual flow rate of the coolant to the one or more automation controllers; and
a coolant control valve communicatively coupled to the one or more automation controllers and configured to adjust the actual flow rate of the coolant, and wherein the one or more automation controllers are configured to:
receive the flow input from the coolant flow element; and
activate the coolant control valve to provide the coolant to the reactor jacket based at least in part on the flow input and the input indicative of the outlet temperature to maintain the outlet temperature approximately 15° F. or more greater than the inlet temperature of the coolant entering the reactor jacket.

10. The system of claim 1 , wherein the polymerization reactor comprises an inner pipe disposed within an outer pipe of the reactor jacket, and wherein the coolant system is configured to flow the coolant through the reactor jacket.

11. The system of claim 10 , wherein the coolant system is configured to flow the coolant through the reactor jacket in a counter-current direction relative to the slurry flowing through the polymerization reactor.

12. The system of claim 1 , wherein the coolant system comprises a coolant cooler configured to cool the coolant before returning the coolant to the first polymerization reactor.

13. A system, comprising:
a polymerization reactor configured to produce a slurry comprising polyolefin particles and a diluent;
a coolant system configured to provide a coolant to a reactor jacket disposed along a portion of the polymerization reactor; and
one or more automation controllers configured to:
receive a temperature input indicative of an outlet temperature of the coolant exiting the reactor jacket;

receive a flow input indicative of an actual coolant flow rate through the reactor jacket from a coolant flow element; and
activate a coolant control valve to adjust the actual coolant flow rate based at least in part on the temperature input indicative of the outlet temperature and the flow input to maintain the outlet temperature approximately 15° F. or more greater than the inlet temperature of the coolant entering the reactor jacket.

14. The system of claim 13 , wherein the one or more automation controllers are configured to maintain the outlet temperature between approximately 15° F. to approximately 30° F. greater than the inlet temperature of the coolant entering the reactor jacket.

15. The system of claim 13 , wherein the one or more automation controllers are configured to maintain the outlet temperature between approximately 15° F. to approximately 50° F. greater than the inlet temperature of the coolant entering the reactor jacket.

16. The system of claim 13 , wherein the coolant system comprises a coolant temperature element configured to provide the temperature input indicative of the outlet temperature of the coolant exiting the reactor jacket to the one or more automation controllers.

17. The system of claim 13 , comprising:
a separation vessel configured to receive the slurry to produce a lights stream comprising light components and a solids stream comprising the polyolefin particles and residual diluent; and
an additional polymerization reactor configured to receive the solids stream and produce additional polyolefin particles, wherein the additional polymerization reactor comprises a loop slurry polymerization reactor.

18. The system of claim 13 , wherein the polymerization reactor comprises an inner pipe disposed within an outer pipe of the reactor jacket, and wherein the coolant system is configured to flow the coolant through the reactor jacket.

19. The system of claim 18 , wherein the coolant system is configured to flow the coolant through the reactor jacket in a counter-current direction relative to the slurry flowing through the polymerization reactor.

20. The system of claim 13 , wherein the co

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Mcelvain Robert R
• Hottovy John D
• Romig Ralph W
• Verser Donald W
• Burns David H
• Tait John H
• Peacock Richard
• Hein James E
• Kufeld Scott E
• Fenderson Carl W
• Gupta Anurag
• Zellers Dale A

Classifications

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F110/02

  Ethene · CPC title

• C08F6/003

  from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom · CPC title

• B01J2208/00212

  Plates; Jackets; Cylinders · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title