Display screen and its manufacturing process

Patent metadata

Field	Value
Publication number	US-9606378-B2
Application number	US-201314377993-A
Country	US
Kind code	B2
Filing date	Feb 14, 2013
Priority date	Feb 16, 2012
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

The invention relates to a display screen and its manufacturing process. The display screen of the invention comprises: a substrate made of a plastic; at least one transparent heating element; and at least one thermochromic compound, and is characterized in that the at least one transparent heating element comprises at least one optionally functionalized metal nanowire. The invention in particular has applications in the electronics industry.

First claim

The invention claimed is:

1. A display screen, comprising:
a substrate made of a plastic material;
at least one transparent heating element; and
at least one thermochromic compound,
wherein said at least one transparent heating element comprises at least one metal nanowire which is functionalized and comprises, at an external surface, a self-assembled monomolecular layer formed from one or more precursor of molecule of formula I,
R 1 —Z n —R 2    Formula I

in which:
Z represents a sulfur or selenium atom,
n=I or 2,
R 1 and R 2 each represent, independently of one another, a hydrogen atom or a saturated or unsaturated and linear, branched or cyclic hydrocarbon group which is optionally perfluorinated or partially fluorinated, which comprises from 1 to 100 carbon atoms and which optionally comprises one or more heteroatoms and/or one or more chemical functional groups comprising at least one heteroatom and/or one or more aromatic or heteroaromatic groups, or a chemical functional group comprising at least one heteroatom or one aromatic or heteroaromatic group which is substituted or unsubstituted.

2. The display screen according to claim 1 , wherein the self-assembled monomolecular layer completely covers an external surface of the at least one metal nanowire.

3. A method for the manufacture of a display screen, said method comprising:
depositing, over all or part of a surface of a substrate made of a plastic material, of at least one heating element comprising at least one metal nanowire, the nanowire being functionalized by formation of a self-assembled monomolecular layer from at least one molecule of formula I,
R 1 —Z n —R 2    Formula I

in which:
Z represents a sulfur or selenium atom,
n=1 or 2,
R 1 and R 2 each represent, independently of one another, a hydrogen atom or a saturated or unsaturated and linear, branched or cyclic hydrocarbon group which is optionally perfluorinated or partially fluorinated, which comprises from 1 to 100 carbon atoms and which optionally comprises one or more heteroatoms and/or one or more chemical functional groups comprising at least one heteroatom and/or one or more aromatic or heteroaromatic groups, or a chemical functional group comprising at least one heteroatom or one aromatic or heteroaromatic group which is substituted or unsubstituted.

4. The display screen according to claim 1 , wherein the at least one functionalized metal nanowire comprises a metal chosen from silver, gold, copper, platinum, palladium, nickel, cobalt, rhodium, iridium, ruthenium, and iron.

5. The display screen according to claim 1 , wherein in formula I, R 1 is H, Z is S, and R 2 is a saturated C 3 to C 18 alkyl chain or a substituted or unsubstituted C 4 to C 10 aromatic group.

6. The display screen according to claim 1 , wherein formula I is one or more selected from 1-propanethiol, 1-decanethiol, 1-octadecanethiol, benzenethiol, 4-methoxybenzenethiol, and 4-trifluoromethylbenzenethiol.

7. The display screen according to claim 1 , wherein at least one thermochromic compound is chosen from crystal violet lactone, vanadium dioxide, and mixtures thereof.

8. The display screen according to claim 1 , wherein the substrate made of a plastic material is chosen from polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polymethyl methacrylate (PMMA), and a silicone.

9. The display screen according to claim 1 , wherein the substrate has a thickness of from 2 μm and 500 μm.

10. The display screen according to claim 1 , further comprising an encapsulation layer, said layer comprising a material chosen from an ethylene/vinyl acetate (EVA) polymer, a vinyl butyral polymer (PVB), and a urethane polymer.

11. The display screen according to claim 1 , wherein the substrate is coated with an insulation layer.

12. The method according to claim 3 , wherein the self-assembled monomolecular layer completely covers an external surface of the at least one metal nanowire.

13. The method according to claim 3 , wherein the at least one nanowire comprises a metal chosen from silver, gold, copper, platinum, palladium, nickel, cobalt, rhodium, iridium, ruthenium, and iron.

14. The method according to claim 3 , wherein in formula I, R 1 is H, Z is S, and R 2 is a saturated C 3 to C 8 alkyl chain or a substituted or unsubstituted C 4 to C 10 aromatic group.

15. The method according to claim 3 , wherein formula I is chosen from 1-propanethiol, 1-decanethiol, 1-octadecanethiol, benzenethiol, 4-methoxybenzenethiol, or 4-trifluoromethylbenzenethiol.

16. The method according to claim 3 , wherein the depositing further comprises deposition of at least one thermochromic compound chosen from crystal violet lactone, vanadium dioxide, and mixtures thereof.

17. The method according to claim 3 , wherein the plastic material is chosen from polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polymethyl methacrylate (PMMA), and a silicone.

18. The method according to claim 3 , wherein the substrate has a thickness of from 2 μm to 500 μm.

19. The method according to claim 3 , further comprising the deposition of a layer for encapsulation of the substrate, said encapsulation comprising a polymer material chosen from an ethylene/vinyl acetate (EVA) polymer, a vinyl butyral polymer (PVB), and a urethane polymer.

20. The method according to claim 16 , further comprising the deposition of an insulation layer on the surface of the substrate on which the deposition of the at least one metal nanowire and of the thermochromic compound is carried out.

21. The method according to claim 16 , wherein the deposition of the at least one metal nanowire is carried out before the deposition of the thermochromic compound.

22. The method according to claim 16 , wherein the deposition of the metal nanowire is carried out after the deposition of the thermochromic compound.

23. The method according to claim 3 , wherein the deposition of the at least one metal nanowire is carried out by projection under pressure, the use of an inkjet machine or a spin coater, by flexography, by photogravure, or by use of a scraper.

Assignees

• Commissariat A L'Energie Atomique Et Aux Ene Alt
• Commissariat Energie Atomique

Inventors

• Simonato Jean-Pierre
• Carella Alexandre
• Celle Caroline

Classifications

• B82Y15/00

  Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors · CPC title

• G02F1/0147 Primary

  based on thermo-optic effects (G02F1/132 takes precedence) · CPC title

• G02F1/009

  Thermal properties · CPC title

• G02F2201/12

  electrode · CPC title

• Y10S977/762

  Nanowire or quantum wire, i.e. axially elongated structure having two dimensions of 100 nm or less · CPC title